2-羟基-N,N-二(2-羟乙基)-N-甲基乙铵硫酸甲酯盐 | 29463-06-7

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机硫酸及其衍生物
• 中文名称: 2-羟基-N,N-二(2-羟乙基)-N-甲基乙铵硫酸甲酯盐
• 英文名称: tris-(2-hydroxyethyl)methylammonium methyl sulfate
• 英文别名: tris(2-hydroxyethyl)methylammonium methyl sulfate；tris(2-hydroxyethyl)methylammonium methylsulfate；[MTEOA][MeOSO3]；tris-(2-hydroxyethyl)methylammonium methylsulfate；Tris(2-hydroxyethyl)methylammonium methyl sulphate；methyl sulfate;tris(2-hydroxyethyl)-methylazanium
• CAS: 29463-06-7
• 化学式: CH₃O₄S*C₇H₁₈NO₃
• 分子量: 275.323
• InChiKey: WLTHPEHYBIKNHR-UHFFFAOYSA-M

物化性质

• 密度：
  1.347[at 20℃]
• 闪点：
  >100 °C

计算性质

• 辛醇/水分配系数(LogP)：
  -2.5
• 重原子数：
  17
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  136
• 氢给体数：
  3
• 氢受体数：
  7

安全信息

• WGK Germany：
  1
• 储存条件：
  保存在2-8℃的环境中，需要密封、干燥并充气。

SDS

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Section 1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE
Product identifiers
Product name : Tris(2-hydroxyethyl)methylammonium methylsulfate
CAS-No. : 29463-06-7
Relevant identified uses of the substance or mixture and uses advised against
Identified uses : Laboratory chemicals, Manufacture of substances

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Section 2. HAZARDS IDENTIFICATION
Classification of the substance or mixture
Not a hazardous substance or mixture according to Regulation (EC) No. 1272/2008.
Not a hazardous substance or mixture according to EC-directives 67/548/EEC or 1999/45/EC.
Label elements
The product does not need to be labelled in accordance with EC directives or respective national laws.
Other hazards - none

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Section 3. COMPOSITION/INFORMATION ON INGREDIENTS
Substances
Synonyms : BASIONIC® FS 01
MTEOA MeOSO3
Formula : C8H21NO7S
Molecular Weight : 275,32 g/mol

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Section 4. FIRST AID MEASURES
Description of first aid measures
If inhaled
If breathed in, move person into fresh air. If not breathing, give artificial respiration.
In case of skin contact
Wash off with soap and plenty of water.
In case of eye contact
Flush eyes with water as a precaution.
If swallowed
Never give anything by mouth to an unconscious person. Rinse mouth with water.
Most important symptoms and effects, both acute and delayed
Indication of any immediate medical attention and special treatment needed
no data available

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Section 5. FIREFIGHTING MEASURES
Extinguishing media
Suitable extinguishing media
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Special hazards arising from the substance or mixture
Carbon oxides, nitrogen oxides (NOx), Sulphur oxides
Advice for firefighters
Wear self contained breathing apparatus for fire fighting if necessary.
Further information
no data available

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Section 6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Avoid breathing vapors, mist or gas.
Environmental precautions
Do not let product enter drains.
Methods and materials for containment and cleaning up
Keep in suitable, closed containers for disposal.
Reference to other sections
For disposal see section 13.

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Section 7. HANDLING AND STORAGE
Precautions for safe handling
no data available
Conditions for safe storage, including any incompatibilities
Store in cool place. Keep container tightly closed in a dry and well-ventilated place.
Store under inert gas. Moisture sensitive.
Specific end uses
no data available

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Section 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Control parameters
Components with workplace control parameters
Exposure controls
Appropriate engineering controls
General industrial hygiene practice.
Personal protective equipment
Eye/face protection
Use equipment for eye protection tested and approved under appropriate government standards
such as NIOSH (US) or EN 166(EU).
Skin protection
Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique
(without touching glove's outer surface) to avoid skin contact with this product. Dispose of
contaminated gloves after use in accordance with applicable laws and good laboratory practices.
Wash and dry hands.
The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and
the standard EN 374 derived from it.
Body Protection
impervious clothing, The type of protective equipment must be selected according to the
concentration and amount of the dangerous substance at the specific workplace.
Respiratory protection
Respiratory protection not required. For nuisance exposures use type OV/AG (US) or type ABEK
(EU EN 14387) respirator cartridges. Use respirators and components tested and approved under
appropriate government standards such as NIOSH (US) or CEN (EU).

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Section 9. PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties
a) Appearance Form: liquid
Colour: yellow
b) Odour no data available
c) Odour Threshold no data available
d) pH 7,0 - 8,0 at 20 g/l at 20 °C
e) Melting point/freezing no data available
point
f) Initial boiling point and > 180 °C at 1.013 hPa
boiling range
g) Flash point > 100,00 °C - closed cup
h) Evaporation rate no data available
i) Flammability (solid, gas) no data available
j) Upper/lower no data available
flammability or
explosive limits
k) Vapour pressure no data available
l) Vapour density no data available
m) Relative density 1,320 g/cm3 at 20 °C
n) Water solubility soluble
o) Partition coefficient: n- no data available
octanol/water
p) Autoignition no data available
temperature
q) Decomposition no data available
temperature
r) Viscosity no data available
s) Explosive properties no data available
t) Oxidizing properties no data available
Other safety information
no data available

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Section 10. STABILITY AND REACTIVITY
Reactivity
no data available
Chemical stability
no data available
Possibility of hazardous reactions
no data available
Conditions to avoid
no data available
Incompatible materials
Strong oxidizing agents
Hazardous decomposition products
Other decomposition products - no data available

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Section 11. TOXICOLOGICAL INFORMATION
Information on toxicological effects
Acute toxicity
LD50 Oral - rat - > 6.400 mg/kg
Skin corrosion/irritation
Skin - rabbit - No skin irritation
Serious eye damage/eye irritation
Eyes - rabbit - No eye irritation
Respiratory or skin sensitization
no data available
Germ cell mutagenicity
no data available
Carcinogenicity
IARC: No component of this product present at levels greater than or equal to 0.1% is identified as
probable, possible or confirmed human carcinogen by IARC.
Reproductive toxicity
no data available
Specific target organ toxicity - single exposure
no data available
Specific target organ toxicity - repeated exposure
no data available
Aspiration hazard
no data available
Potential health effects
Inhalation
May be harmful if inhaled. May cause respiratory tract irritation.
Ingestion May be harmful if swallowed.
Skin May be harmful if absorbed through skin. May cause skin irritation.
Eyes May cause eye irritation.
Additional Information
RTECS: Not available

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Section 12. ECOLOGICAL INFORMATION
Toxicity
Toxicity to fish LC50 - Danio rerio (zebra fish) - > 5.000 mg/l - 96 h
Persistence and degradability
Biodegradability Result: > 70 - 100 % - Readily biodegradable.
Bioaccumulative potential
no data available
Mobility in soil
no data available
Results of PBT and vPvB assessment
no data available
Other adverse effects
no data available

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Section 13. DISPOSAL CONSIDERATIONS
Waste treatment methods
Product
Offer surplus and non-recyclable solutions to a licensed disposal company.
Contaminated packaging
Dispose of as unused product.

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Section 14. TRANSPORT INFORMATION
UN number
ADR/RID: - IMDG: - IATA: -
UN proper shipping name
ADR/RID: Not dangerous goods
IMDG: Not dangerous goods
IATA: Not dangerous goods
Transport hazard class(es)
ADR/RID: - IMDG: - IATA: -
Packaging group
ADR/RID: - IMDG: - IATA: -
Environmental hazards
ADR/RID: no IMDG Marine pollutant: no IATA: no
Special precautions for user
no data available

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SECTION 15 - REGULATORY INFORMATION
N/A

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SECTION 16 - ADDITIONAL INFORMATION
N/A

反应信息

• 作为反应物：
  描述：

  甲基丙烯酸异氰基乙酯 、 2-羟基-N,N-二(2-羟乙基)-N-甲基乙铵硫酸甲酯盐 在 二月桂酸二丁基锡 2,6-二叔丁基-4-甲基苯酚 作用下， 以 二氯甲烷 为溶剂， 反应 39.0h， 生成
  参考文献：
  名称：

  [EN] COMPOSITIONS AND ARTICLES COMPRISING POLYMERIZABLE IONIC LIQUID MIXTURE, AND METHODS OF CURING
  [FR] COMPOSITIONS ET ARTICLES COMPRENANT UN MÉLANGE LIQUIDE IONIQUE POLYMÉRISABLE, ET PROCÉDÉS DE DURCISSEMENT

  摘要：

  公开号：

  WO2011025847A3
• 作为产物：
  描述：

  三乙醇胺 、 硫酸二甲酯 生成 2-羟基-N,N-二(2-羟乙基)-N-甲基乙铵硫酸甲酯盐
  参考文献：
  名称：

  Screening ionic liquids for use in biotransformations with whole microbial cells

  摘要：

  翻译结果：对含有多种阳离子和阴离子的离子液体进行了广泛的毒性筛选，包括可水溶和难水溶的离子液体，利用琼脂扩散试验和液体培养中的生长抑制试验来评估对大肠杆菌K-12的毒性。数据提供了初步规则，以便设计用于生物催化过程中的无毒离子液体。

  DOI：

  10.1039/c0gc00579g

文献信息

• METHOD FOR PREPARING SURFACTANT COMPOSITIONS COMPRISING ALKYL LIDURONAMIDES D-GLUCURONAMIDES AND L-RHAMNOSIDES FROM ULVANS
  申请人：ÉCOLE NATIONALE SUPÉRIEURE DE CHIMIE

  公开号：US20200045962A1

  公开（公告）日：2020-02-13

  The present invention relates to a novel process for preparing surfactant compositions based on alkyl L-iduronamides, alkyl L-rhamnosides and alkyl D-glucuronamides, to the compositions obtained via said process and to the uses thereof.

  本发明涉及一种基于烷基L-异硫酰胺、烷基L-鼠李糖苷和烷基D-葡萄糖苷的表面活性剂组合物的制备新方法，涉及通过该方法获得的组合物以及其用途。
• アミノ酸系農薬用効力増強剤組成物
  申请人：花王株式会社

  公开号：JP2015205869A

  公开（公告）日：2015-11-19

  【課題】生分解性、水生生物毒性（魚毒性）に優れ、アミノ酸系農薬と相溶性に優れ、安定で、アミノ酸系農薬の効力、なかでも耐雨性を効果的に増強できるアミノ酸系農薬用効力増強剤を提供する。【解決手段】エステル基を有する３種の特定の第４級アンモニウム塩を、特定の質量比で含有するアミノ酸系農薬用効力増強剤組成物。【選択図】なし

  这段文本描述了一种提供用于氨基酸类农药的增效剂，具有优越的生物降解性、水生生物毒性（鱼毒性），与氨基酸类农药相容性好，稳定性强，能有效增强氨基酸类农药的功效，特别是增强其耐雨性。解决方案是包含三种具有酯基的特定第四级铵盐，在特定质量比下的氨基酸类农药用增效剂组合物。
• Measuring the effect of ionic liquids on laccase activity using a simple, parallel method
  作者：Lars Rehmann、Ekaterina Ivanova、Jamie L. Ferguson、H. Q. Nimal Gunaratne、Kenneth R. Seddon、Gillian M. Stephens

  DOI：10.1039/c2gc16009a

  日期：——

  Laccase activity was measured in the presence of 63 water-miscible and water-immiscible ionic liquids, including imidazolium, pyridinium, quaternary ammonium and quaternary phosphonium salts. A simple, parallel method was used to determine activity. In general, water-immiscible ionic liquids, especially bis[(trifluoromethyl)sulfonyl]amide salts, supported the highest enzyme activities.

  在63种可溶于水和不溶于水的离子液体存在下测量了漆酶活性，这些离子液体包括咪唑鎓、吡啶鎓、四级铵盐和四级膦盐。采用了一种简单的并行方法来确定活性。通常，不溶于水的离子液体，特别是双[(三氟甲基)磺酰]氨盐，支持了最高的酶活性。
• Zeolite‐Type Metal Oxalate Frameworks
  作者：Fei‐Yan Yi、Huajun Yang、Xiang Zhao、Pingyun Feng、Xianhui Bu

  DOI：10.1002/anie.201900106

  日期：2019.2.25

  known to form zeolite‐type topologies. The construction of zeolite types, especially those with low framework density such as RHO, from linear ligands is generally perceived as less likely, because the 180° metal‐ligand‐metal geometry deviates too much from the established strategy of using ligands with bent coordination geometry (centered around 145°) to mimic the geometry in natural zeolites. We show

  虽然已知许多草酸盐金属盐，但很少能形成沸石型拓扑。人们普遍认为，由线性配体构造沸石类型，尤其是那些低骨架密度的沸石（如RHO）的可能性较小，因为180°金属-配体-金属几何形状与使用具有弯曲配位几何形状的配体的既定策略相差太大（以145°为中心）以模仿天然沸石的几何形状。通过报告具有多种沸石拓扑结构的草酸铟盐家族，包括RHO，GIS和ABW，我们展示了使用线性配体合成沸石类型的一般可行性。特别令人感兴趣的是具有双8环和大α笼的RHO沸石网的合成，这是非常需要的沸石特征。
• [EN] ESLICARBAZEPINE ACETATE AND ITS POLYMORPHS<br/>[FR] ACÉTATE D'ESLICARBAZÉPINE ET SES POLYMORPHES
  申请人：REDDYS LAB LTD DR

  公开号：WO2011091131A2

  公开（公告）日：2011-07-28

  Processes for the preparation of eslicarbazepine acetate and intermediates thereof. Also provided are polymorphic forms of eslicarbazepine acetate and methods for their preparation.

  制备艾司卡巴嗪乙酸酯及其中间体的过程。还提供了艾司卡巴嗪乙酸酯的多态形式及其制备方法。