bis-heptafluoropropyl-pentafluoroethyl-amine | 338-82-9

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: bis-heptafluoropropyl-pentafluoroethyl-amine
• 英文别名: Bis-heptafluorpropyl-pentafluoraethyl-amin；Bis-(heptafluoropropyl)-pentafluoroethyl-amine；1,1,2,2,3,3,3-heptafluoro-N-(1,1,2,2,3,3,3-heptafluoropropyl)-N-(1,1,2,2,2-pentafluoroethyl)propan-1-amine
• CAS: 338-82-9
• 化学式: C₈F₁₉N
• 分子量: 471.064
• InChiKey: JCZIZRITTQLVOG-UHFFFAOYSA-N

物化性质

• 沸点：
  111.2±35.0 °C(Predicted)
• 密度：
  1.733±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  7.2
• 重原子数：
  28
• 可旋转键数：
  5
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  3.2
• 氢给体数：
  0
• 氢受体数：
  20

反应信息

• 作为产物：
  描述：

  N-乙基二丙胺 在 氢氟酸 作用下， 生成 bis-heptafluoropropyl-pentafluoroethyl-amine
  参考文献：
  名称：

  Fluorocarbon tertiary amines

  摘要：

  公开号：

  US02616927A1

文献信息

• Electrochemical fluorination of aminoalkyl ethers
  作者：G.G.I. Moore、J.C. Hansen、T.M. Barrett、J.E. Waddell、K.M. Jewell、T.A. Kestner、R.M. Payfer

  DOI：10.1016/s0022-1139(00)80506-0

  日期：1986.6

  trialkylamines in liquid HF takes place readily in good yields, whereas dialkyl ethers give low yields. The latter fluorinated ethers are of interest for their low temperature properties. Our goal in this work was to prepare fluorinated aminoalkyl ether fluids which might combine the favorable yields of amines and properties of ethers. Several dialkylamine and alkylene units were combined in a variety of diamino

  已知在液体HF中三烷基胺的电化学氟化容易以良好的产率发生，而二烷基醚的产率很低。后者的氟化醚因其低温性能而受到关注。我们在这项工作中的目标是制备氟化的氨基烷基醚流体，该流体可以结合胺的良好收率和醚的性能。将几种二烷基胺和亚烷基单元结合在各种二氨基单醚，二氨基二醚和单氨基单醚中。在第一类材料中，电化学氟化产率高达50％。描述了这些新流体的结构-屈服关系和性质。
• The electrochemical fluorination of nitrogen-containing carboxylic acids. Fluorination of methyl esters of 3-dialkylamino propionic acids
  作者：Takashi Abe、Eiji Hayashi、Haruhiko Fukaya、Yoshio Hayakawa、Hajime Baba、Shigeki Ishikawa、Kinya Asahino

  DOI：10.1016/s0022-1139(00)82821-3

  日期：1992.4

  Six methyl esters of 3-dialkylamino-substituted propionic acids were subjected to electrochemical fluorination to give the corresponding perfluoroacid fluorides. The following dialkylamino substituents were investigated: diethylamino, di-n-propyl-amino, di-n-butylamino, pyrrolidino, morpholino and piperidino groups. These perfluoroacid fluorides, which were obtained in fair yields, are considered to

  将3-二烷基氨基取代的丙酸的六种甲酯进行电化学氟化，得到相应的全氟代氟化物。研究了以下二烷基氨基取代基：二乙基氨基，二正丙基氨基，二正丁基氨基，吡咯烷基，吗啉代和哌啶子基。这些以合理收率获得的全氟酸氟化物被认为是制备软质（可降解）含氟化合物的潜在关键前体。这些盐在水溶液中显示出明显降低的表面张力。报告了所获得的所有全氟酸氟化物的物理性质，以及它们的光谱数据（19 F NMR，质谱和IR光谱）。
• PROCESS FOR PREPARING TERTIARY PERFLUOROAMINES
  申请人：MINNESOTA MINING AND MANUFACTURING COMPANY

  公开号：EP0548155A1

  公开（公告）日：1993-06-30
• US5108556A
  申请人：——

  公开号：US5108556A

  公开（公告）日：1992-04-28
• [EN] PROCESS FOR PREPARING TERTIARY PERFLUOROAMINES
  申请人：MINNESOTA MINING AND MANUFACTURING COMPANY

  公开号：WO1992005142A1

  公开（公告）日：1992-04-02

  (EN) A process for preparing tertiary perfluoroamines is provided. The process comprises electrochemically fluorinating a tertiary thioamide precursor, said thioamide precursor having at least one thioamide moiety, see formula (I), and terminal portions which can be alkyl or cycloalkyl having 1 to 12 carbon atoms, aryl having 6 to 12 carbon atoms, or combinations thereof, with the proviso that when more than one thioamide moiety is present, the thioamide moieties are bonded together by alkylene, cycloalkylene or arylene groups. Also provided are tertiary thioamides and tertiary perfluoroamines.(FR) Procédé de préparation de perfluoroamines tertiaires. Le procédé consiste à fluorurer électrochimiquement un précurseur de thioamide tertiaire, ledit précurseur de thioamide ayant au moins une fraction thioamide, cf formule (I), ainsi que des parties terminales pouvant être alkyles ou cycloalkyles contenant 1 à 2 atomes de carbone, aryle contenant 6 à 12 atomes de carbone ou des combinaisons de ceux-ci, à condition que lorsque plus d'une fraction thioamide est présente, les fractions thioamide soient liées ensemble par des groupes alkylène, cycloalkylène ou arylène. L'invention concerne également des thioamides tertiaires ainsi que des perfluoroamines tertiaires.