diethyl-dipropyl-ammonium; iodide

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: diethyl-dipropyl-ammonium; iodide
• 英文别名: Diaethyl-dipropyl-ammonium; Jodid；Diethyl(dipropyl)azanium;iodide；diethyl(dipropyl)azanium;iodide
• 化学式: C₁₀H₂₄N*I
• 分子量: 285.212
• InChiKey: KHOKTPWAHAJKRU-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  -0.33
• 重原子数：
  12
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  diethyl-dipropyl-ammonium; iodide 生成 N-(n-丙基)二乙胺
  参考文献：
  名称：

  v. Auwers; Mauss, Chemische Berichte, 1928, vol. 61, p. 2415,2416, 2417

  摘要：

  DOI：
• 作为产物：
  描述：

  乙基三丙基碘化铵 生成 diethyl-dipropyl-ammonium; iodide
  参考文献：
  名称：

  v. Auwers; Mauss, Chemische Berichte, 1928, vol. 61, p. 2415,2416, 2417

  摘要：

  DOI：

文献信息

• New Ionic Plastic Crystals of NR₄BEt₃Me (R = Me and Et) and NR<i>_x</i>R′₄₋<i>_x</i>BEt₃Me (R = Et, R′ = Me and Pr, <i>x</i> = 1–3) in a New Class of Plastic Crystals
  作者：Tomoyuki Hayasaki、Satoru Hirakawa、Hisashi Honda

  DOI：10.1246/bcsj.20130040

  日期：2013.8.15

  New ionic plastic crystals of NR4BEt3Me (R = Me and Et) and NRxR′4−xBEt3Me (R = Et, R′ = Me and Pr, x = 1–3) were formed in a new region of plastic crystal. In this area, globular cations and anions are assembled by weak interactions. On the basis of our results of 1H and 13C NMR spectra and electrical conductivity measurements, we could conclude that isotropic reorientation and self-diffusion of globular cations and anions were detected in the crystal. X-ray diffraction (XRD) lines observed in RxR′4−xBEt3Me (R = Et, R′ = Me, x = 0–4) revealed a CsCl-type cubic crystal structure. Additionally, DSC spectra revealed that this new class of plastic crystals displays low phase-transition temperatures in the plastic phase and have high melting points. The former tendency is frequently detected in molecular plastic crystals while the latter is often found in ionic plastic crystals.

  新型的NR4BEt3Me (R = Me和Et)和NRxR′4−xBEt3Me (R = Et, R′ = Me和Pr, x = 1–3)离子塑料晶体在新区域的塑料晶体中形成。在这一区域，球状阳离子和阴离子通过弱相互作用组装在一起。根据我们对1H和13C NMR谱图及电导率测量的结果，可以得出结论：在晶体中检测到了球状阳离子和阴离子的各向同性重定向和自扩散。X射线衍射(XRD)线在RxR′4−xBEt3Me (R = Et, R′ = Me, x = 0–4)中揭示了一个CsCl型立方晶体结构。此外，DSC谱图显示这类新型塑料晶体在塑料相中具有较低的相变温度，并且熔点较高。前一种趋势在分子塑料晶体中经常被检测到，而后一种则通常在离子塑料晶体中发现。
• Synthesis Of Chabazite Structure-Containing Molecular Sieves And Their Use In The Conversion Of Oxygenates To Olefins
  申请人：Cao Guang

  公开号：US20090018379A1

  公开（公告）日：2009-01-15

  In a method of synthesizing a silicoaluminophosphate or aluminophosphate molecular sieve comprising a CHA framework-type material, a synthesis mixture is provided comprising a source of aluminum, a source of phosphorus, optionally a source of silicon and at least one organic template of formula (I): [R 1 R 2 R 3 R 4 N] + X − (I) wherein each of R 1 , R 2 , R 3 , and R 4 is independently an acyclic alkyl group having at least one carbon atom, the total number of carbon atoms in said alkyl groups R 1 , R 2 , R 3 , and R 4 is greater than 8 but less than 16, and X − is an anion. The synthesis mixture can then be crystallized to produce the desired molecular sieve.

  在合成硅铝磷酸盐或铝磷酸盐分子筛的方法中，提供了一种包含铝源、磷源、可选的硅源和至少一种有机模板的合成混合物，该有机模板的化学式为（I）：[R1R2R3R4N]+X−（I），其中R1、R2、R3和R4分别独立地表示具有至少一个碳原子的无环烷基基团，这些烷基基团R1、R2、R3和R4中的碳原子总数大于8但小于16，X−是一种阴离子。然后可以结晶化合成混合物以产生所需的分子筛。
• Walden; Ulich; Birr, Zeitschrift für physikalische Chemie, Stöchiometrie und Verwandtschaftslehre, 1927, vol. 130, p. 504
  作者：Walden、Ulich、Birr

  DOI：——

  日期：——