2-methyl-1H-isoindole-1,3(2H)-dithione | 35373-10-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 异吲哚及其衍生物
• 英文名称: 2-methyl-1H-isoindole-1,3(2H)-dithione
• 英文别名: N-methyl(dithiophthalimide)；N-methyldithiophthalimide；N-Methyldithiophthalimid；N-methyldithiophtalimide；1H-Isoindole-1,3(2H)-dithione, 2-methyl-；2-methylisoindole-1,3-dithione
• CAS: 35373-10-5
• 化学式: C₉H₇NS₂
• 分子量: 193.293
• InChiKey: DORVZFVQNUHJNY-UHFFFAOYSA-N

物化性质

• 沸点：
  307.6±25.0 °C(Predicted)
• 密度：
  1.40±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.5
• 重原子数：
  12
• 可旋转键数：
  0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.11
• 拓扑面积：
  67.4
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  2-methyl-1H-isoindole-1,3(2H)-dithione 以 苯 为溶剂， 反应 8.0h， 生成 3-Isopropylidene-2-methyl-2,3-dihydro-isoindole-1-thione
  参考文献：
  名称：

  Photochemistry of the nitrogen-thiocarbonyl systems. 2. Photochemistry of the thioimide systems: imide-thietanes

  摘要：

  DOI：

  10.1021/jo00210a023
• 作为产物：
  描述：

  N-甲基邻苯二甲酰亚胺 在 bis(1,5-cyclooctadiylboryl)sulfide 作用下， 以 甲苯 为溶剂， 反应 4.0h， 以89%的产率得到2-methyl-1H-isoindole-1,3(2H)-dithione
  参考文献：
  名称：

  Koester, Roland; Kucznierz, Ralf, Liebigs Annalen der Chemie, 1992, # 10, p. 1081 - 1086

  摘要：

  DOI：

文献信息

• FUNGICIDAL MIXTURES
  申请人：Gregory Vann

  公开号：US20100240619A1

  公开（公告）日：2010-09-23

  Disclosed is a fungicidal composition comprising (a) at least one compound selected from the compounds of Formula 1 N-oxides, and salts thereof, wherein R 1 , R 2 , A, G, W, Z 1 , X, J, and n are as defined in the disclosure, and (b) at least one additional fungicidal compound. Also disclosed is a method for controlling plant diseases caused by fungal plant pathogens comprising applying to the plant or portion thereof, or to the plant seed, a fungicidally effective amount of the aforesaid composition. Also disclosed is a composition comprising component (a) of aforesaid composition and at least one insecticide. Also disclosed are compounds of Formula 1A, 1B and 1C, wherein R 1 , R 2 , A, G, W, Z 1 , X, J, n, Z 3 , M and J 1 are as defined in the disclosure.

  公开了一种含真菌化合物，包括：(a)至少一种选自公式1 N-氧化物的化合物，以及它们的盐类，其中R1，R2，A，G，W，Z1，X，J和n如公开所述定义，以及（b）至少一种额外的含真菌化合物。还公开了一种控制由真菌植物病原体引起的植物病害的方法，包括将有效量的前述组合物施用于植物或其部分，或施用于植物种子。还公开了一种组合物，包括前述组合物的组分(a)和至少一种杀虫剂。还公开了公式1A，1B和1C的化合物，其中R1，R2，A，G，W，Z1，X，J，n，Z3，M和J1如公开所述定义。
• POLYMERIZABLE COMPOUND AND OPTICAL ISOMER
  申请人：DIC Corporation

  公开号：US20180022716A1

  公开（公告）日：2018-01-25

  The present invention provides a polymerizable compound having high storage stability without causing crystal precipitation when added to a polymerizable composition. The present invention also provides a polymerizable composition containing the compound. When the filmy polymer produced through polymerization of the polymerizable composition is irradiated with UV light, it hardly discolors or peels from substrate. Further, the present invention provides a polymer produced through polymerization of the polymerizable composition and an optically anisotropic body using the polymer.

  本发明提供了一种聚合物化合物，具有高储存稳定性，添加到聚合物化合物时不会导致结晶沉淀。本发明还提供了含有该化合物的聚合物化合物。当通过聚合物化合物的聚合产生薄膜状聚合物时，若用紫外光照射，它几乎不会变色或脱落。此外，本发明提供了通过聚合物化合物的聚合产生的聚合物，以及使用该聚合物的光学各向异性体。
• [EN] POLYMERIZABLE COMPOUND AND OPTICALLY ANISOTROPIC BODY<br/>[FR] COMPOSÉ POLYMÉRISABLE ET CORPS OPTIQUEMENT ANISOTROPE
  申请人：DAINIPPON INK & CHEMICALS

  公开号：WO2017079867A1

  公开（公告）日：2017-05-18

  There is provided a polymerizable composition, by which discoloration or alignment defects are less likely to occur when a filmy polymer, which is obtained by adding a polymerizable compound to the polymerizable composition and polymerizing this composition, is irradiated with ultraviolet light. There are also provided a polymer obtained by polymerizing the polymerizable composition, and an optically anisotropic body using the polymer. The present invention provides a polymerizable low-wavelength dispersive or polymerizable reverse-wavelength dispersive compound having a partial structure represented by Formula (Z-0). Further, the present invention provides a composition containing the compound; a polymer obtained by polymerizing the composition; and an optically anisotropic body obtained by using the polymer.

  提供一种可聚合的组合物，通过该组合物得到的薄膜聚合物在紫外光照射时，不太容易发生变色或排列缺陷。还提供了通过聚合该聚合物组合物得到的聚合物，以及使用该聚合物的光学各向异性体。本发明提供了一种具有由式（Z-0）表示的部分结构的可聚合低波长色散或可聚合反波长色散化合物。此外，本发明提供了一种含有该化合物的组合物；通过聚合该组合物得到的聚合物；以及通过使用该聚合物得到的光学各向异性体。
• Investigation of the Thionation Reaction of Cyclic Imides
  作者：A. Orzeszko、J. K. Maurin、D. Melon-Ksyta

  DOI：10.1515/znb-2001-1012

  日期：2001.10.1

  A series of monothioimides and dithioimides were synthesised using Lawesson’s reagent. It has been found that two main effects affect thionation reaction. The high polarity of carbonyl groups leads to good yields of mono- and dithioimides. On the other hand, steric hindrance in the vicinity of the carbonyl group strongly inhibits the replacement of the oxygen atom by sulfur.

  使用Lawesson试剂合成了一系列单硫代亚胺和二硫代亚胺。发现两个主要因素影响了硫化反应。羰基团的高极性导致了单硫代亚胺和二硫代亚胺的高产率。另一方面，在羰基团附近的立体位阻强烈抑制了氧原子被硫取代。
• FUNGICIDAL HETEROCYCLIC COMPOUNDS
  申请人：Pasteris Robert James

  公开号：US20110224258A1

  公开（公告）日：2011-09-15

  Disclosed are compounds of Formula 1, including all geometric and stereoisomers, tautomers, N-oxides, and salts thereof, wherein R 1 , R 2 , R 3 , R 4 , R 5 , A, W, X, G, Z, J and n are as defined in the disclosure. Also disclosed are compositions containing the compounds of Formula 1 and methods for controlling plant disease caused by a fungal pathogen comprising applying an effective amount of a compound or a composition of the invention.

  本发明涉及一种公式1的化合物，包括其所有的几何和立体异构体、互变异构体、N-氧化物和盐，其中R1、R2、R3、R4、R5、A、W、X、G、Z、J和n的定义如本文所述。本发明还涉及包含公式1化合物的组合物，以及控制由真菌病原体引起的植物病害的方法，包括施用本发明中化合物或组合物的有效量。