1,1,4-三氯丁烷 | 66250-03-1

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 有机氯化物
• 中文名称: 1,1,4-三氯丁烷
• 英文名称: 1,1,4-trichloro-butane
• 英文别名: 1,1,4-Trichlor-butan；4-chlorobutylyl chloride；1,1,4-Trichlorobutane
• CAS: 66250-03-1
• 化学式: C₄H₇Cl₃
• mdl: MFCD19232287
• 分子量: 161.459
• InChiKey: RDCXWDUHESIPFX-UHFFFAOYSA-N

物化性质

• 熔点：
  -6°C (estimate)
• 沸点：
  151.13°C (estimate)
• 密度：
  1.2667 (estimate)

计算性质

• 辛醇/水分配系数(LogP)：
  2.9
• 重原子数：
  7
• 可旋转键数：
  3
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

安全信息

• 海关编码：
  2903199000

反应信息

• 作为反应物：
  描述：

  (+/-)-7,8-dihydro-6,6-dimethyl-7-hydroxy-8-amino-6H-pyrano[2,3-f]benz-2,1-3-oxadiazole 、 1,1,4-三氯丁烷 在 sodium hydroxide 作用下， 以 二氯甲烷 、 水 为溶剂， 以37%的产率得到7,8-dihydro-6,6-dimethyl-7-hydroxy-8-(n-(1-oxo-4-chloro) butyl)amino-6H-pyrano [2,3-f] benzo-2,1,3-oxadiazole
  参考文献：
  名称：

  Pyranobenzoxadiazole derivatives, preparation, use and compositions comprising them

  摘要：

  公开号：

  EP0327127B1
• 作为产物：
  描述：

  1,4-二氯丁烷 在 氯 作用下， 以 gas 为溶剂， 生成 1,2,4-三氯丁烷 、 1,1,4-三氯丁烷
  参考文献：
  名称：

  Potter, Alan; Tedder, John M., Journal of the Chemical Society. Perkin transactions II, 1982, p. 1689 - 1692

  摘要：

  DOI：

文献信息

• METHOD FOR PRODUCING CYCLIC CARBONATE
  申请人：NATIONAL INSTITUTE OF ADVANCED INDUSTRIAL SCIENCE AND TECHNOLOGY

  公开号：US20160145234A1

  公开（公告）日：2016-05-26

  Provided is a method for producing a cyclic carbonate obtained by reacting epoxide and carbon dioxide, the method being capable of efficiently producing a cyclic carbonate at a high conversion rate and a high yield, in which degradation of the catalyst over time is suppressed and catalytic activity hardly decreases. A method for producing a cyclic carbonate by reacting epoxide and carbon dioxide in the presence of a quaternary onium salt selected from the group consisting of a quaternary ammonium salt having a halogenated anion as a counter ion and a quaternary phosphonium salt having a halogenated anion as a counter ion, or in the presence of a solid catalyst obtained by immobilizing the quaternary onium salt onto a carrier, wherein an organohalogen compound containing at least one halogen atom in one molecule is added to the reaction system.

  提供了一种生产环状碳酸酯的方法，该方法通过反应环氧化物和二氧化碳获得，能够高效地以高转化率和高产率生产环状碳酸酯，同时抑制催化剂随时间降解并且催化活性几乎不会下降。在存在从属于具有卤素阴离子作为对离子的季铵盐和具有卤素阴离子作为对离子的季膦盐中选择的季铵盐，或者存在通过将季铵盐固定在载体上而获得的固体催化剂的情况下，通过在反应体系中添加含有至少一个卤素原子的有机卤素化合物来生产环状碳酸酯的方法。
• COMPOSITIONS BASED ON 1,1,3,3-TETRACHLOROPROPENE
  申请人：ARKEMA FRANCE

  公开号：US20180148394A1

  公开（公告）日：2018-05-31

  The present invention relates to compositions based on F-1230za (1,1,3,3-tetrachloropropene), or on a mixture consisting of F-1230za and F-1230zd (1,3,3,3-tetrachloropropene), the manufacture thereof, and also the use thereof in particular for the production of F-1233zdE (trans-1-chloro-3,3,3-trifluoropropene), F-1234zeE (trans-1,3,3,3-tetrafluoropropene), and/or F-245fa (1,1,1,3,3-pentafluoropropane).

  本发明涉及基于F-1230za（1,1,3,3-四氯丙烯）或由F-1230za和F-1230zd（1,3,3,3-四氯丙烯）组成的混合物的组合物，其制造方法以及特别适用于生产F-1233zdE（反-1-氯-3,3,3-三氟丙烯）、F-1234zeE（反-1,3,3,3-四氟丙烯）和/或F-245fa（1,1,1,3,3-五氟丙烷）的用途。
• METHOD FOR PRODUCING TETRAFLUOROMETHANE
  申请人：SHOWA DENKO K.K.

  公开号：US20210061733A1

  公开（公告）日：2021-03-04

  Fluorine gas is introduced to a raw material liquid containing a reaction inducer and a fluorinated hydrocarbon represented by C p H q Cl r F s (in the formula, p is an integer of 3 to 18, q is an integer of 0 to 3, r is an integer of 0 to 9, and s is an integer of 5 to 30) and having no carbon-carbon unsaturated bond to give tetrafluoromethane. The reaction inducer is a halogen-containing carbon compound liquid at room temperature and pressure and is reacted with fluorine gas to induce a reaction of forming tetrafluoromethane from the fluorinated hydrocarbon and the fluorine gas. The reaction inducer is contained at a content of more than 0% by mass and not more than 10% by mass when the total content of the fluorinated hydrocarbon and the reaction inducer contained in the raw material liquid is 100% by mass.

  氟气被引入到一种原料液中，该液体包含反应诱导剂和表示为CpHqClrFs的氟化碳氢化合物（其中，p为3至18的整数，q为0至3的整数，r为0至9的整数，s为5至30的整数），并且不具有碳-碳不饱和键，以产生四氟甲烷。反应诱导剂是一种在室温和压力下含有卤素的碳化合物液体，与氟气反应以诱导氟化碳氢化合物和氟气形成四氟甲烷的反应。当原料液中所含的氟化碳氢化合物和反应诱导剂的总含量为100%时，反应诱导剂的含量为质量含量大于0%且不大于10%。
• Process for the preparation of substituted norbornene derivatives and norbornene derivatives
  申请人：The B.F. GOODRICH Company

  公开号：EP0005527A2

  公开（公告）日：1979-11-28

  Preparation of substituted norbornene derivatives by the reaction in the liquid phase of cyclopentadiene or dicyclopentadiene with an olefin or cycloolefin; temperature: 100-300°C; pressure: 3,4-170 atm.; solvent: chlorinated or brominated hydrocarbon. Tricyclic norbornene derivatives: e.g. tricyclo (12.2.1.02,13) heptadeca-5,9,15-triene; tetracyclo (8.2.1.09.207.3) tridecene-11.

  通过环戊二烯或双环戊二烯与烯烃或环烯烃在液相中的反应制备取代的降冰片烯衍生物；温度：100-300°C；压力：3,4-170 atm；溶剂：氯化或溴化碳氢化合物。 三环降冰片烯衍生物：如三环(12.2.1.02,13)十七碳-5,9,15-三烯；四环(8.2.1.09.207.3)十三烯-11。
• Titanium trichloride catalyst and process for production of alpha-olefin polymers
  申请人：SUMITOMO CHEMICAL COMPANY, LIMITED

  公开号：EP0034935A1

  公开（公告）日：1981-09-02

  A component of a catalyst (for polymerizing olefins) is prepared by reacting a mixture of (1) a titanium trichloride hydrocarbon aluminum halide dialkyl ether composition, (2) a halogen, interhalogen compound or halgenated hydrocarbon and (3) a dialkyl ether, as in known from U.K. Patent No. 1,559,447; to increase activity of the catalyst and stereoregu- lanty of the polymer, the mixture also includes (4) an electron donor, namely an organic compound containing a N, O, Si, S and /or P atom, e.g. an amine, imine, nitrile, ether, ketone, ester, sulfide, silane, siloxane, phosphine, phosphite or phosphate, in an amount of 10-6 to 0.02 mols per gram of titanium trichloride composition (1). The reaction may be in an inert hydrocarbon solvent at 0° to 150°C for 5 minutes to 6 hours, after which the solid is isolated and washed. The catalyst also includes a known hydrocarbon aluminum halide or hydride as activator and may include a further stereoregularity improving agent. Olefins having 2 to 10 carbon atoms are homo- or copolymerized at0°to 100°C to form stereoregular polyolefin using the catalyst in a small amount, e.g. 50 mg per 1.4 Kg of propylene.

  一种催化剂（用于聚合烯烃）的组分是通过以下物质的混合物反应制备的：(1)三氯化 钛烃卤化铝二烷基醚组合物；(2)卤素、卤间化合物或卤代烃；(3)二烷基醚，如英国专利 No.为了提高催化剂的活性和聚合物的立体性，混合物中还包括 (4) 电子供体，即含有 N、O、Si、S 和/或 P 原子的有机化合物，如胺、亚胺、腈、醚、酮、酯、硫化物、硅烷、硅氧烷、磷化氢、亚磷酸盐或磷酸盐，其用量为每克三氯化钛组合物 (1) 10-6 至 0.02 摩尔。 反应可在 0° 至 150°C 的惰性烃类溶剂中进行 5 分钟至 6 小时，然后分离和洗涤固体。 催化剂还包括作为活化剂的已知烃类卤化铝或氢化物，并可包括另一种立体规整度改进剂。 具有 2 至 10 个碳原子的烯烃在 0° 至 100°C 的温度下进行均聚或共聚，形成立体规整的聚烯烃，催化剂的用量很小，例如每 1.4 千克丙烯用 50 毫克。