cyclopenta-1,3-diene;cyclopenta-2,4-dien-1-ylmethyl(trimethyl)azanium;iron(2+);trifluoromethanesulfonate | 163394-31-8

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 卤代烷
• 英文名称: cyclopenta-1,3-diene;cyclopenta-2,4-dien-1-ylmethyl(trimethyl)azanium;iron(2+);trifluoromethanesulfonate
• CAS: 163394-31-8
• 化学式: CF₃O₃S*C₁₄H₂₀FeN
• 分子量: 407.237
• InChiKey: VJEPBRULQVRPMD-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  cyclopenta-1,3-diene;cyclopenta-2,4-dien-1-ylmethyl(trimethyl)azanium;iron(2+);trifluoromethanesulfonate 以 not given 为溶剂， 生成 ((trimethylammonio)methyl)ferrocenium(2+)
  参考文献：
  名称：

  Structural and spectral characterization of novel charge-transfer salts of polyoxometalates and the cationic ferrocenyl donor

  摘要：

  The first charge-transfer salts containing the cationic ferrocenyl donor cpFecpCH(2)N(+)(CH3)(3) and polyoxometalate accepters of the Lindqvist structural type (M(6)O(19)(2-); M = Mo, W) have been isolated in high yields (87-88%). The X-ray structure of the charge-transfer salt shows the close (interionic) interaction of the hydrogen atoms of the cyclopentadienyl ligand with the surface of the polyoxometalate. Furthermore, the UV-vis diffuse reflectance spectrum in the solid state indicates the presence of a new charge-transfer band at lambda(max) = 550 nm; and laser-flash photolysis spectroscopy establishes cpFe(+)cpCH(2)N(+)(CH3)(3) and M(6)O(19)(3-) as short-lived transients in the direct photoactivation of the charge-transfer salt.

  DOI：

  10.1016/0022-328x(94)00028-b
• 作为产物：
  描述：

  N,N-dimethylaminomethylferrocene 、 三氟甲烷磺酸甲酯 以 四氢呋喃 为溶剂， 以86%的产率得到cyclopenta-1,3-diene;cyclopenta-2,4-dien-1-ylmethyl(trimethyl)azanium;iron(2+);trifluoromethanesulfonate
  参考文献：
  名称：

  Structural and spectral characterization of novel charge-transfer salts of polyoxometalates and the cationic ferrocenyl donor

  摘要：

  The first charge-transfer salts containing the cationic ferrocenyl donor cpFecpCH(2)N(+)(CH3)(3) and polyoxometalate accepters of the Lindqvist structural type (M(6)O(19)(2-); M = Mo, W) have been isolated in high yields (87-88%). The X-ray structure of the charge-transfer salt shows the close (interionic) interaction of the hydrogen atoms of the cyclopentadienyl ligand with the surface of the polyoxometalate. Furthermore, the UV-vis diffuse reflectance spectrum in the solid state indicates the presence of a new charge-transfer band at lambda(max) = 550 nm; and laser-flash photolysis spectroscopy establishes cpFe(+)cpCH(2)N(+)(CH3)(3) and M(6)O(19)(3-) as short-lived transients in the direct photoactivation of the charge-transfer salt.

  DOI：

  10.1016/0022-328x(94)00028-b

文献信息

• Palladium-Catalyzed Stereoselective Difunctionalization of Bicyclic Alkenes with Organoammonium Salts and Organoboronic Compounds
  作者：Yuanyuan Tang、Kuan Liu、Jinjin Zhang、Long Liu、Tianzeng Huang、Chunya Li、Zhi Tang、Tieqiao Chen

  DOI：10.1021/acs.joc.1c01339

  日期：2021.9.3

  A palladium-catalyzed difunctionalization of bicyclic alkenes with organoammonium salts and organoboronic compounds was reported. A wide range of functionalized cyclic products, including those bearing functional groups, were produced stereoselectively in good to excellent yields. The gram-scale experiment, one-pot operation, and synthetic application of β-borylated products further demonstrated the

  报道了钯催化的双环烯烃与有机铵盐和有机硼化合物的双官能化。各种官能化环状产物，包括那些带有官能团的产物，都以良好到极好的收率立体选择性地生产。β-硼酸化产物的克级实验、一锅操作和合成应用进一步证明了这一新反应在有机合成中的合成价值。
• Pullen, Anthony E.; Faulmann, Christophe; Pokhodnya, Konstantin I., Inorganic Chemistry, 1998, vol. 37, # 26, p. 6714 - 6720
  作者：Pullen, Anthony E.、Faulmann, Christophe、Pokhodnya, Konstantin I.、Cassoux, Patrick、Tokumoto, Madoka

  DOI：——

  日期：——