2-[[2-(Difluoromethylidene)-4,5,5-trifluoro-1,3-dioxolan-4-yl]-difluoromethoxy]-1,1,2,2-tetrafluoroethanesulfonyl fluoride | 521322-82-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二氧戊环
• 英文名称: 2-[[2-(Difluoromethylidene)-4,5,5-trifluoro-1,3-dioxolan-4-yl]-difluoromethoxy]-1,1,2,2-tetrafluoroethanesulfonyl fluoride
• CAS: 521322-82-7
• 化学式: C₇F₁₂O₅S
• 分子量: 424.121
• InChiKey: VVJHVEWKESTEFR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4
• 重原子数：
  25
• 可旋转键数：
  5
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.71
• 拓扑面积：
  70.2
• 氢给体数：
  0
• 氢受体数：
  17

反应信息

• 作为产物：
  描述：

  4-[Difluoro-(1,1,2,2-tetrafluoro-2-fluorosulfonylethoxy)methyl]-4,5,5-trifluoro-2-(trifluoromethyl)-1,3-dioxolane-2-carbonyl fluoride 以52%的产率得到2-[[2-(Difluoromethylidene)-4,5,5-trifluoro-1,3-dioxolan-4-yl]-difluoromethoxy]-1,1,2,2-tetrafluoroethanesulfonyl fluoride
  参考文献：
  名称：

  FLUOROSULFONYL COMPOUNDS AND PROCESS FOR PRODUCTION OF COMPOUNDS DERIVED THEREFROM

  摘要：

  公开号：

  EP1440971B1

文献信息

• PROCESSES FOR PRODUCING A FLUOROSULFONYL GROUP-CONTAINING COMPOUND AND A COMPOUND LED FROM THE FLUOROSULFONYL GROUP-CONTAINING COMPOUND
  申请人：OKAZOE Takashi

  公开号：US20080287694A1

  公开（公告）日：2008-11-20

  A fluorosulfonyl group-containing compound having a high polymerization reactivity, a process for its production, a sulfonyl group-containing polymerizable monomer led from the sulfonyl group-containing compound, and a polymer obtainable by polymerizing the sulfonyl group-containing polymerizable monomer, are provided. A compound (3) is fluorinated to form a compound (4), and then, the compound (4) is subjected to a decomposition reaction to produce a compound (5). A preferred compound (5-1) of the compound (5) is thermally decomposed to produce a compound (7-1) having a high polymerization reactivity. wherein R A is a bivalent organic group such as a fluoroalkylene group, R AF is a group having R A fluorinated, or the same group as R A , each of R B to R D which are independent of one another, is a hydrogen atom, etc., each of R BF to R DF is a fluorine atom, etc., R E is a monovalent organic group, R EF is a group having R E fluorinated, or the same group as R E , E is a bivalent connecting group, E F is the same group as E, or a group having E fluorinated, E F1 is a group formed by scission of E F , each of X 1 to X 3 is a hydrogen atom, etc., and each of X 1F to X 3F is a fluorine atom, etc.

  提供了一种含有氟磺酰基团的高聚合反应性化合物、其制备方法、由含有磺酰基团的聚合单体引导的磺酰基团含量的聚合物以及通过聚合磺酰基团含量的聚合单体获得的聚合物。化合物（3）被氟化形成化合物（4），然后，化合物（4）经历分解反应产生化合物（5）。化合物（5）的优选化合物（5-1）被热分解产生具有高聚合反应性的化合物（7-1）。 其中，RA是双价有机基团，例如氟烷基团，RAF是RA氟化的基团，或者与RA相同的基团，RB到RD中的每一个都是独立的，是氢原子等，RBF到RDF中的每一个都是氟原子等，RE是单价有机基团，REF是RE氟化的基团，或者与RE相同的基团，E是双价连接基团，EF是与E相同的基团，或者是E氟化的基团，EF1是通过EF断裂形成的基团，X1到X3中的每一个都是氢原子等，X1F到X3F中的每一个都是氟原子等。
• METHOD FOR PRODUCING ORGANIC COMPOUND HAVING SULFO GROUP, METHOD FOR PRODUCING LIQUID COMPOSITION, AND METHOD FOR HYDROLYTICALLY TREATING ORGANIC COMPOUND HAVING FLUOROSULFONYL GROUP
  申请人：Asahi Glass Company, Limited

  公开号：EP2752431A1

  公开（公告）日：2014-07-09

  To provide a method for producing an organic compound having a sulfo group by efficiently hydrolyzing an organic compound having a fluorosulfonyl group with a small number of steps with a small quantity of waste liquid. A method for producing an organic compound having a sulfo group, which comprises bringing an organic compound having a fluorosulfonyl group into contact with subcritical water at from 200 to 320°C to convert the fluorosulfonyl group into a sulfo group.

  提供一种生产具有磺基的有机化合物的方法，该方法通过少量步骤和少量废液有效地水解具有氟磺酰基的有机化合物。 一种生产具有磺基的有机化合物的方法，包括使具有氟磺酰基的有机化合物与 200 至 320°C 的亚临界水接触，将氟磺酰基转化为磺基。
• METHOD FOR PRODUCING FLUORINATED ION EXCHANGE RESIN SOLUTION
  申请人：Asahi Glass Company, Limited

  公开号：EP2810715A1

  公开（公告）日：2014-12-10

  To provide a process for forming a polymer electrolyte membrane having good durability and few wrinkles, a polymer electrolyte membrane capable of forming a catalyst layer, or a catalyst layer; a process for producing a fluorinated ion exchange resin fluid, or a paste for forming a catalyst layer, which can be used for such a forming process; and a process for producing a membrane/electrode assembly for a polymer electrolyte fuel cell having good durability and power generation properties. A fluorinated ion exchange resin fluid obtained by subjecting a powder or pellets of a fluorinated ion exchange resin having cation exchange groups to hydrogen peroxide treatment, followed by mixing with a solvent, is used.

  提供一种用于形成耐久性好、褶皱少的聚合物电解质膜、能够形成催化剂层的聚合物电解质膜或催化剂层的工艺；一种用于生产氟离子交换树脂液或用于形成催化剂层的浆料的工艺，该浆料可用于上述形成工艺；以及一种用于生产耐久性好、发电性能高的聚合物电解质燃料电池膜/电极组件的工艺。使用的氟化离子交换树脂液是通过将具有阳离子交换基团的氟化离子交换树脂粉末或颗粒进行过氧化氢处理，然后与溶剂混合而得到的。
• ELECTROLYTE MATERIAL, LIQUID COMPOSITION, MEMBRANE ELECTRODE ASSEMBLY FOR SOLID POLYMER FUEL CELL, AND FLUORINE-CONTAINING BRANCHED POLYMER
  申请人：Asahi Glass Company, Limited

  公开号：EP3165546A1

  公开（公告）日：2017-05-10

  To provide: an electrolyte material having high oxygen permeability as compared with conventional ones; a membrane electrode assembly for a polymer electrolyte fuel cell excellent in power generation characteristics as compared with conventional ones; a liquid composition suitable for forming a catalyst layer for the membrane electrode assembly; and a fluorinated branched polymer useful as e.g. a raw material of the electrolyte material. The electrolyte material comprises a fluoropolymer (H)1 having a structural unit (u1) that has an ionic group and a structural unit (u2) that has an alicyclic structure, wherein the fluoropolymer (H)1 is composed of a branched molecular chain, and has a segment (A)3 comprising a molecular chain having the structural unit (u1) and a segment (B)2 composed of a molecular chain having the structural unit (u2), and the ion exchange capacity of the segment (B)2 is smaller than the ion exchange capacity of the segment (A)3.

  提供：一种与传统材料相比具有高氧气渗透性的电解质材料；一种与传统材料相比发电特性优异的聚合物电解质燃料电池膜电极组件；一种适用于形成膜电极组件催化剂层的液体组合物；以及一种可用作电解质材料原料等的含氟支化聚合物。电解质材料包括含氟聚合物 (H)1，其结构单元 (u1) 具有离子基团，结构单元 (u2) 具有脂环结构，其中含氟聚合物 (H)1 由支化分子链组成、具有由具有结构单元（u1）的分子链和具有结构单元（u2）的分子链组成的区段（B）2 的区段（A）3，且区段（B）2 的离子交换容量小于区段（A）3 的离子交换容量。
• METHOD FOR MANUFACTURING FLUORINE-CONTAINING POLYMER PARTICLES
  申请人：Asahi Glass Company, Limited

  公开号：EP3239215A1

  公开（公告）日：2017-11-01

  To provide a method capable of producing fluorinated polymer particles in which formation of fine particles or formation of large aggregates is sufficiently suppressed even in the case of a fluorinated polymer having high solubility in a solvent. The method comprises the following steps (i) and (ii), being a method for producing particles of a fluorinated polymer (A) which has either one or both of structural units (u1) derived from tetrafluoroethylene and structural units (u2) having no sulfonic acid type functional group and having a cyclic structure and fluorine atoms, and which has structural units (u3) having a sulfonic acid type functional group, wherein the proportion of the structural units (u1) is from 0 to 82 mol% in all structural units (100 mol%) in the fluorinated polymer (A): (i) a step of preparing solution or dispersion of the fluorinated polymer (A) having the above fluorinated polymer (A) dissolved or dispersed in a solvent (B), wherein the following conditions (i-1) and (i-2) are satisfied: (i-1) the solvent (B) contains a good solvent (B2) wherein the solubility of the fluorinated polymer (A) is at least 30%, (i-2) even when the above solution or dispersion of the fluorinated polymer (A) is passed through a filter of 200 mesh made of stainless steel, no residue remains on the filter, (ii) a step of mixing the above solution or dispersion of the fluorinated polymer (A) and a solvent (C) to aggregate the fluorinated polymer (A) to form particles of the fluorinated polymer (A), wherein the following conditions (ii-1) to (ii-3) are satisfied: (ii-1) the solvent (C) contains a poor solvent (C1) whereby the degree of swelling of the fluorinated polymer (A) is at most 100%, (ii-2) the degree of swelling of the fluorinated polymer (A) by a mixed solvent (BC) of the solvent (B) and the solvent (C) is from 70 to 250%, (ii-3) the ratio of the mass (Wc) of the solvent (C) to the mass (WB) of the solvent (B) is from 1 to 5.

  提供一种生产含氟聚合物颗粒的方法，在该方法中，即使含氟聚合物在溶剂中的溶解度很 高，也能充分抑制细小颗粒的形成或大型聚集体的形成。 该方法包括以下步骤(i)和(ii)，即生产含氟聚合物 (A) 颗粒的方法，该含氟聚合物 (A) 具有衍生自四氟乙烯的结构单元 (u1) 和不含磺酸型官能团且具有环状结构和氟原子的结构单元 (u2) 中的一个或两个、和具有磺酸型官能团的结构单元（u3），其中结构单元（u1）在含氟聚合物（A）的所有结构单元（100 摩尔%）中的比例为 0 至 82 摩尔%： (i) 制备氟化聚合物（A）溶液或分散液的步骤，上述氟化聚合物（A）溶解或分散于 溶剂（B）中，其中满足以下条件（i-1）和（i-2）： (i-1) 溶剂（B）含有良好溶剂（B2），其中含氟聚合物（A）的溶解度至少为 30%、 (i-2) 即使上述含氟聚合物（A）溶液或分散液通过 200 目不锈钢过滤器，过滤器上也没有残留物、 (ii) 将上述含氟聚合物(A)溶液或分散液与溶剂(C)混合以聚合含氟聚合物(A)形成含氟聚合物(A)颗粒的步骤，其中满足以下条件(ii-1)至(ii-3)： (ii-1) 溶剂（C）含有贫溶剂（C1），氟化聚合物（A）的溶胀度最多为 100%、 (ii-2) 溶剂(B)和溶剂(C)的混合溶剂(BC)对含氟聚合物(A)的溶胀度为 70%至 250%、 (ii-3) 溶剂（C）的质量（Wc）与溶剂（B）的质量（WB）之比为 1 至 5。