propyl 2-methoxybenzoate | 81763-23-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: propyl 2-methoxybenzoate
• 英文别名: 2-methoxy-benzoic acid propyl ester；2-Methoxy-benzoesaeure-propylester
• CAS: 81763-23-7
• 化学式: C₁₁H₁₄O₃
• mdl: MFCD12178054
• 分子量: 194.23
• InChiKey: RKNMLBOVBRNMFX-UHFFFAOYSA-N

物化性质

• 沸点：
  114.8-115.5 °C(Press: 1.5 Torr)
• 密度：
  1.085 g/cm3
• 保留指数：
  1514

计算性质

• 辛醇/水分配系数(LogP)：
  2.9
• 重原子数：
  14
• 可旋转键数：
  5
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.363
• 拓扑面积：
  35.5
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  丙醇 、 邻甲氧基苯甲酸 在 silphos 作用下， 反应 0.17h， 以91%的产率得到propyl 2-methoxybenzoate
  参考文献：
  名称：

  在作为多相膦试剂的 Silphos [PCl3-n(SiO2)n] 存在下羧酸和醇的无溶剂酯化

  摘要：

  摘要 报道了一种使用多相膦试剂 silphos [PCl3-n(SiO2)n] 从各种芳香族和脂肪酸与伯醇、仲醇和叔醇制备酯的有效无溶剂方法，收率良好。图形概要

  DOI：

  10.1080/00397911.2011.555903

文献信息

• Zinc-Catalyzed Esterification of <i>N</i> -β-Hydroxyethylamides: Removal of Directing Groups under Mild Conditions
  作者：Yuji Nishii、Takahiro Hirai、Sarah Fernandez、Paul Knochel、Kazushi Mashima

  DOI：10.1002/ejoc.201700748

  日期：2017.9.15

  Amide transformations involving C-N bond cleavage are recognized as difficult reactions owing to the inert nature of amides resulting from resonance. Accordingly, a strong inductive effect and geometrical distortion reasonably decrease the resonance stabilization to attenuate the C-N linkage. Although the conversion of such activated amides has been studied intensively, reaction systems for unactivated

  由于由共振引起的酰胺的惰性性质，涉及 CN 键断裂的酰胺转化被认为是困难的反应。因此，强感应效应和几何失真合理地降低了共振稳定性以衰减 CN 链接。尽管已经对此类活化酰胺的转化进行了深入研究，但未活化酰胺的反应体系尚未开发。我们在此报告了三氟甲磺酸锌 (II) [Zn(OTf)(2)] 催化剂在分子内酰基重排的帮助下实现了多种未活化的叔酰胺的酯化。该反应用于在温和的反应条件下一锅脱除各种酰胺基导向基团，以高产率得到相应的酯。
• COMPOUND AND COLORED RESIN COMPOSITION
  申请人：SUMITOMO CHEMICAL COMPANY, LIMITED

  公开号：US20210002487A1

  公开（公告）日：2021-01-07

  An object of the present invention is to provide a novel squarylium dye that can achieve an equivalent chromaticity value of even a colored resin composition having a low content of the squarylium dye as compared with a colored resin composition comprising a conventional squarylium dye. The present invention provides a compound represented by the formula (I) wherein R 4 to R 4 each independently represent a hydrogen atom or the like; R 5 to R 8 each independently represent a hydrogen atom or the like; R 9 and R 10 each independently represent a monovalent saturated hydrocarbon group having 1 to 20 carbon atoms or the like; R 11 and R 12 each independently represent a halogen atom or an alkyl halide group having 1 to 6 carbon atoms; and m1 and m2 each independently represent an integer of 1 to 5.

  本发明的一个目的是提供一种新型的方苯基染料，即使与含有传统方苯基染料的着色树脂组合相比，也可以实现具有低含量方苯基染料的着色树脂组合的等效色度值。本发明提供了一个由式（I）表示的化合物，其中R4到R4各自独立地表示氢原子或类似物；R5到R8各自独立地表示氢原子或类似物；R9和R10各自独立地表示具有1到20个碳原子的一价饱和碳氢基团或类似物；R11和R12各自独立地表示卤素原子或具有1到6个碳原子的烷基卤素基团；m1和m2各自独立地表示1到5的整数。
• Synthesis of Hydroxybenzoic Acids and Their Esters by Reaction of Phenols with Carbon Tetrachloride and Alcohols in the Presence of Iron Catalysts
  作者：A. R. Bayguzina、L. I. Tarisova、R. I. Khusnutdinov

  DOI：10.1134/s1070363218020056

  日期：2018.2

  Alkyl esters of hydroxy-, methoxy-, and ethoxybenzoic and cresotic acids have been synthesized by reaction of phenols, anisole, phenetole, and cresols with carbon tetrachloride and alcohols in the presence of iron catalysts.

  在铁催化剂的存在下，通过苯酚，苯甲醚，苯酚和甲酚与四氯化碳和醇的反应，合成了羟基，甲氧基和乙氧基苯甲酸和酚醛酸的烷基酯。
• A catalyst component for olefin polymerization and a catalyst comprising the same
  申请人：China Petroleum & Chemical Corporation

  公开号：EP2287208A1

  公开（公告）日：2011-02-23

  The present invention relates to a solid catalyst component for olefin polymerization comprising an α-cyanosuccinate compound as an internal electron donor, a catalyst comprising the catalyst component, and use of the catalyst in olefin polymerization. When used in propylene polymerization, the catalyst exhibits a higher catalytic activity and good hydrogen response, and the resulting polymer has a high isotacticity and a broad molecular weight distribution.

  本发明涉及一种用于烯烃聚合的固体催化剂组分，该组分包括一种作为内部电子供体的α-氰基琥珀酸酯化合物、一种由该催化剂组分组成的催化剂以及该催化剂在烯烃聚合中的用途。当用于丙烯聚合时，催化剂表现出更高的催化活性和良好的氢响应，所产生的聚合物具有高同构度和宽分子量分布。
• CATALYST COMPONENT FOR OLEFIN POLYMERIZATION AND PREPARATION METHOD THEREOF
  申请人：China Petroleum & Chemical Corporation

  公开号：EP2492290A1

  公开（公告）日：2012-08-29

  A catalyst component for olefin polymerization is disclosed, which comprises at least one diol ester type electron donor compound (a) and at least one diether type electron donor compound (b) among others, wherein the molar ratio of a to b is 0.55-50. A preparation method of the catalyst component, a catalyst comprising the catalyst component, and an olefin polymerization method using the catalyst which can especially be used for preparation of polypropylenes of low ash contents are also disclosed.

  本发明公开了一种用于烯烃聚合的催化剂组分，它包括至少一种二醇酯类电子供体化合物（a）和至少一种二醚类电子供体化合物（b），其中a与b的摩尔比为0.55-50。此外，还公开了催化剂组分的制备方法、包含催化剂组分的催化剂以及使用该催化剂的烯烃聚合方法，该催化剂尤其可用于制备低灰分含量的聚丙烯。