N,N'-dichloro-1,4-benzoquinone diimine | 68456-83-7

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: N,N'-dichloro-1,4-benzoquinone diimine
• 英文别名: N,N'-dichloro-p-benzoquinone diimine；N,N'-dichloro-quinone diimine；p-benzoquinone(1,4)-dichlorimide；parabenzoquinonedichlorimine；N,N′-bis(chlorosulfanyl)-cyclohexa-2,5-diene-1,4-diimine；N,N'-dichloro-cyclohexa-2,5-diene-1,4-diylidenediamine；[1,4]benzoquinone-bis-chlorimin；[1,4]Benzochinon-bis-chlorimin；p-Chinondichlordiimid；Chinondichlordiimid；N,N'-dichloro-2,5-cyclohexadiene-1,4-diimine；N,N'-dichloro-p-benzoquinonediimide；Benzochinon-(1.4)-bis-chlorimid；p-Chinon-bis-chlorimid；2,5-Cyclohexadiene-1,4-diimine, N,N'-dichloro-；1-N,4-N-dichlorocyclohexa-2,5-diene-1,4-diimine
• CAS: 68456-83-7
• 化学式: C₆H₄Cl₂N₂
• 分子量: 175.017
• InChiKey: NHMMHCXTHYEVLE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.5
• 重原子数：
  10
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  24.7
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  N,N'-dichloro-1,4-benzoquinone diimine 在 盐酸 、 tin(ll) chloride 作用下， 生成 2,3,5,6-四氯-1,4-苯二胺
  参考文献：
  名称：

  Krause, Chemische Berichte, 1879, vol. 12, p. 54

  摘要：

  DOI：
• 作为产物：
  描述：

  对苯二胺 在 盐酸 、 calcium chloride 作用下， 生成 N,N'-dichloro-1,4-benzoquinone diimine
  参考文献：
  名称：

  Griebel; Weiss, Zeitschrift fur Lebensmittel-Untersuchung und -Forschung, 1933, vol. 65, p. 419,421

  摘要：

  DOI：

文献信息

• Organometallic CN coupling between N,N′-dichloro-p-benzoquinone diimine and Grignard reagents and its application to synthesis of polyanilines
  作者：Takakazu Yamamoto、Ismayil Nurulla、Asako Ushiro

  DOI：10.1016/s0040-4039(01)01872-x

  日期：2001.12

  A new C–N coupling reaction between N,N′-dichloro-p-benzoquinone diimines and aryl Grignard reagents has been developed. The new method gives N,N′-diaryl-p-benzoquinone diimines in 50–88% isolated yield. The obtained new compounds are regarded as oligomeric model compounds for pernigraniline-type polyaniline, and their chemical behavior has been investigated. New polyaniline-type polymers have been

  N，N'-二氯-对苯醌二亚胺与芳基格氏试剂之间的新型C–N偶联反应得到了发展。新方法以50-88％的分离产率得到N，N'-二芳基-对苯并醌二亚胺。所获得的新化合物被认为是肾上腺素型聚苯胺的低聚模型化合物，并对其化学行为进行了研究。新的聚苯胺型聚合物是通过应用已开发的C–N偶联反应制备的。
• Mechanism of color reaction of aromatic secondary and tertiary amines with quinonedichlorodiimide.
  作者：MASAYASU YAMAMOTO、TOYOZO UNO

  DOI：10.1248/cpb.27.688

  日期：——

  Quinonedichlorodiimide (I) reacts with aromatic secondary and tertiary amines to yield green colored compounds. The chemical structure of these colored compounds is investigated from the spectral data (infrared, ultraviolet, nuclear magnetic resonance, mass) and the chemical reactions. The color of the reaction product of I and N-ethyl-m-toluidine (II) or N, N-diethyl-m-toluidine (III) is changed mutually between green and violet by oxidation and reduction. These results and the spectral data suggest that these reactions are electrophilic displacement reactions in the ortho or para position of the alkylamino group and I reacts with II or III at the rate of 1 : 2.

  醌二氯双亚胺 (I) 与芳香族次级和三级胺反应，生成绿色化合物。这些着色化合物的化学结构通过光谱数据（红外、紫外、核磁共振、质谱）和化学反应进行研究。I 与 N-乙基-m-甲基苯胺 (II) 或 N, N-二乙基-m-甲基苯胺 (III) 的反应产物的颜色在氧化和还原过程中相互变化为绿色和紫色。这些结果和光谱数据表明，这些反应是在烷基氨基团的邻位或对位发生的电亲核取代反应，并且 I 以 1:2 的速率与 II 或 III 反应。
• Jaubert, Chemische Berichte, 1895, vol. 28, p. 273
  作者：Jaubert

  DOI：——

  日期：——
• Molecular Characterization in the VP7, VP4 and NSP4 Genes of Human Rotavirus Serotype 4 (G4) Isolated in Japan and Kenya
  作者：Satoshi Kudo、Yumei Zhou、Xin-Ru Cao、Shigeki Yamanishi、Shuji Nakata、Hiroshi Ushijima

  DOI：10.1111/j.1348-0421.2001.tb01286.x

  日期：2001.2

  AbstractThe VP7, VP4 and NSP4 genes of human rotavirus serotype 4 (G4) were analyzed to investigate intraserotypic variations. The techniques used included reverse transcription polymerase chain reaction with subtype specific primers, restriction fragment length polymorphism analysis and sequence analysis. Twelve isolates (nine from Japan and three from Kenya) and two standard strains (Hochi, Odelia) were G4A P[8] Wa group NSP4. A standard strain (ST3) was G4A P[6] Wa group NSP4 and a strain (VA70) was G4B P[8] Wa group NSP4. These results show G4 rotaviruses can be divided into three combinations at the moment.
• Shand, Charles A.; Thomson, Ronald H.; Greenhalgh, Colin W., Journal of Chemical Research, Miniprint, 1982, # 6, p. 1601 - 1617
  作者：Shand, Charles A.、Thomson, Ronald H.、Greenhalgh, Colin W.

  DOI：——

  日期：——