bis(1,10-phenanthroline-κ2N,N')copper(I) iodide | 25753-91-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 菲咯啉
• 英文名称: bis(1,10-phenanthroline-κ2N,N')copper(I) iodide
• 英文别名: bis(1,10-phenanthroline)copper(I) iodide；Cu(phen)2I；Copper(1+);1,10-phenanthroline;iodide
• CAS: 25753-91-7
• 化学式: C₂₄H₁₆CuN₄*I
• 分子量: 550.868
• InChiKey: BVQASKZVCPRFTK-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  2.57
• 重原子数：
  30
• 可旋转键数：
  0
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  51.6
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为产物：
  描述：

  copper(l) iodide 、 1,10-菲罗啉 在 锌 作用下， 以 四氢呋喃 、 1,2-二溴乙烷 为溶剂， 反应 21.0h， 生成 bis(1,10-phenanthroline-κ2N,N')copper(I) iodide
  参考文献：
  名称：

  一种纳斯特试剂的催化合成方法及其应用

  摘要：

  本发明提供了一种催化合成纳斯特试剂的方法及其应用，所述纳斯特试剂为式(1)所示结构的有机溶液：其催化合成方法为：惰性气体保护下，将如式(II)所示催化剂铜配合物和活性锌粉加到有机溶剂中，在一定温度下滴加二溴甲烷，然后升温反应直至锌粉反应完全，得到的乳白色的悬浊液即为纳斯特试剂。(II)，本发明与现有的技术相比，最大的优点在于：提供了一种纳斯特试剂的催化合成方法，形成的新型铜配合物作为催化剂在纳斯特试剂的合成中效果显著，并在羰基的亚甲基化中得到了应用。

  公开号：

  CN107915754A

文献信息

• Influence of the counterion on the geometry of Cu(I) and Cu(II) complexes with 1,10-phenanthroline
  作者：Alessandra Crispini、Carmen Cretu、Diana Aparaschivei、Adelina A. Andelescu、Viorel Sasca、Valentin Badea、Iolinda Aiello、Elisabeta I. Szerb、Otilia Costisor

  DOI：10.1016/j.ica.2017.05.064

  日期：2018.1

  respectively. The firstly isolated Cu(I) complexes were characterized by IR, 1H NMR and UV-Vis spectroscopies, their proposed structures being confirmed by elemental analysis, atomic absorption spectroscopy (AAS) and thermogravimetric analysis (TGA). The molecular structure of Cu(II) complexes was determined by single crystal X-ray diffraction analysis. While for Cu(I) complexes, the coordinating nature

  摘要研究了抗衡离子对Cu（I）和Cu（II）未取代的phen基（phen = 1,10-菲咯啉）配合物的几何构型的影响。所使用的合成策略提供了具有通式[（phen）2Cu] + Y-（Y- = ClO4-，I-，SCN-和BF4-）的四配位Cu（I）和五配位Cu（II）的合成。和[（phen）2CuX] + Y-（X = Cl-，I-，NCS-和Y- = -，I-，SCN-和 -）。首次分离的Cu（I）配合物通过IR，1H NMR和UV-Vis光谱学进行表征，其提议的结构已通过元素分析，原子吸收光谱法（AAS）和热重分析（TGA）得以确认。通过单晶X射线衍射分析确定了Cu（II）配合物的分子结构。对于Cu（I）络合物，
• NOVEL FLUORAN COMPOUND, INTERMEDIATE, AND CHROMOGENIC RECORDING MATERIAL
  申请人：NIPPON SODA CO., LTD.

  公开号：EP0735105A1

  公开（公告）日：1996-10-02

  By using the fluoran compound represented by the following general formula (I); wherein R1 is alkyl containing 1 to 4 carbon atoms, R3 is alkyl containing 1 to 8 carbon atoms, R4 is hydrogen or alkyl containing 1 to 8 carbon atoms, or R3 and R4 may bond with each other to form a ring together with a N atom, R2 is alkyl containing 1 to 4 carbon atoms, and n denotes 0, 1 or 2, however, the substituents represented by R2 may be different with each other when n is 2, as a color former for color forming recording materials, recording materials which have excellent properties in whiteness of the background of the material under light and in photostability of color-formed images on the materials as well as in sufficient color forming capability of the material even after having exposed them to light, can be provided.

  使用以下通式(I)代表的氟烷化合物； 其中 R1 是含 1 至 4 个碳原子的烷基，R3 是含 1 至 8 个碳原子的烷基，R4 是氢或含 1 至 8 个碳原子的烷基，或 R3 和 R4 可相互键合，与一个 N 原子一起形成一个环，R2 是含 1 至 4 个碳原子的烷基，n 表示 0、1 或 2，但当 n 为 2 时，R2 所代表的取代基可相互不同、作为彩色成形记录材料的显色剂，可提供在光下材料背景的白度和材料上彩色成形图像的光稳定性以及即使在光下曝光后材料仍有足够的彩色成形能力方面性能优异的记录材料。
• Nucleophilic Aryl Fluorination and Aryl Halide Exchange Mediated by a Cu^I/Cu^III Catalytic Cycle
  作者：Alicia Casitas、Mercè Canta、Miquel Solà、Miquel Costas、Xavi Ribas

  DOI：10.1021/ja2058567

  日期：2011.12.7

  Copper-catalyzed halide exchange reactions under very mild reaction conditions are described for the first time using a family of model aryl halide substrates. All combinations of halide exchange (I, Br, Cl, F) are observed using catalytic amounts of Cu-I. Strikingly, quantitative fluorination of aryl X substrates is also achieved catalytically at room temperature, using common F- sources, via the intermediacy of aryl-Cu-III-X species. Experimental and computational data support a redox Cu-I/Cu-III catalytic cycle involving aryl X oxidative addition at the Cu-I center, followed by halide exchange and reductive elimination steps. Additionally, defluorination of the aryl-F model system can be also achieved with Cu-I at room temperature operating under a Cu-I/Cu-III redox pair.
• Two polymorphs of bis(1,10-phenanthroline-κ²<i>N</i>,<i>N</i>′)copper(I) iodide
  作者：Rachael Clarke、Kay Latham、Colin Rix、Jonathan White

  DOI：10.1107/s0108270102020590

  日期：2003.1.15

  The title complex, [Cu(C12H8N2)(2)]I, (I), has been crystallized in two polymorphic forms, both containing four-coordinate copper. Both forms are orthorhombic, with form (Ia) crystallizing in the primitive space group Pban and form (Ib) in the c-centred space group Ccca. In (Ia), the complex cation and the I- anion both have 222 crystallographic symmetry, and in (Ib), the complex cation has approximate 222 symmetry, with the I- counter-ion distributed over three special positions.