bis(2-[(pyridin-2-yl)methoxy]naphthalen-1-yl)methane

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: bis(2-[(pyridin-2-yl)methoxy]naphthalen-1-yl)methane
• 英文别名: 2-[[1-[[2-(Pyridin-2-ylmethoxy)naphthalen-1-yl]methyl]naphthalen-2-yl]oxymethyl]pyridine；2-[[1-[[2-(pyridin-2-ylmethoxy)naphthalen-1-yl]methyl]naphthalen-2-yl]oxymethyl]pyridine
• 化学式: C₃₃H₂₆N₂O₂
• 分子量: 482.582
• InChiKey: KKWUNFFSWMZRQP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.2
• 重原子数：
  37
• 可旋转键数：
  8
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.09
• 拓扑面积：
  44.2
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  甲醇 、 copper dichloride 、 bis(2-[(pyridin-2-yl)methoxy]naphthalen-1-yl)methane 以 甲醇 、 氯仿 为溶剂， 以0%的产率得到aqua(bis(2-[(pyridin-2-yl)methoxy]naphthalen-1-yl)methane)(perchlorato)copper(II) perchlorate*2(methanol)
  参考文献：
  名称：

  Coordination characteristics of di-O-picolyl derivative of 1,1′-methylene-bis(2-naphthol): First crystal structure of a monomeric Cu(II) complex of bis{2-[(pyridin-2-yl)methoxy] naphthalen-1-yl}methane

  摘要：

  Monomeric Cu(II) complex of bis{2-[(pyridin-2-yl)methoxy] naphthalen-1-yl}methane (L) having a composition, {[Cu(L)(H2O)(ClO4)](ClO4)(CH3OH)(2)} (1) has been synthesized and characterized by analytical, spectral and magnetic methods and the structure has been established for the first time based on single crystal XRD. The Cu2+ center shows axially elongated octahedron with a bound water and perchlorate moieties, where two of the coordinations were long but within the van der Waals distance. The bound water, perchlorate ions and the methanol of crystallization are primarily responsible for the formation of extended lattice structure resulted from the intra-helical interactions. Complex 1 exhibit catecholase activity as studied using 3,5-di-tert-butyl catechol. (C) 2008 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2008.12.019
• 作为产物：
  描述：

  2-氯甲基吡啶 、 1,1-亚甲基-2-萘酚 在 potassium carbonate 作用下， 以 乙腈 为溶剂， 生成 bis(2-[(pyridin-2-yl)methoxy]naphthalen-1-yl)methane
  参考文献：
  名称：

  Rao, P. Venkateswara; Rao, Chebrolu P., Indian Journal of Chemistry, Section A: Inorganic, Physical, Theoretical and Analytical, 2002, vol. 41, # 1, p. 124 - 124

  摘要：

  DOI：

文献信息

• Coordination characteristics of di-O-picolyl derivative of 1,1′-methylene-bis(2-naphthol): First crystal structure of a monomeric Cu(II) complex of bis{2-[(pyridin-2-yl)methoxy] naphthalen-1-yl}methane
  作者：Garima Singh Baghel、Shaikh M. Mobin、Chebrolu P. Rao

  DOI：10.1016/j.ica.2008.12.019

  日期：2009.6

  Monomeric Cu(II) complex of bis2-[(pyridin-2-yl)methoxy] naphthalen-1-yl}methane (L) having a composition, [Cu(L)(H2O)(ClO4)](ClO4)(CH3OH)(2)} (1) has been synthesized and characterized by analytical, spectral and magnetic methods and the structure has been established for the first time based on single crystal XRD. The Cu2+ center shows axially elongated octahedron with a bound water and perchlorate moieties, where two of the coordinations were long but within the van der Waals distance. The bound water, perchlorate ions and the methanol of crystallization are primarily responsible for the formation of extended lattice structure resulted from the intra-helical interactions. Complex 1 exhibit catecholase activity as studied using 3,5-di-tert-butyl catechol. (C) 2008 Elsevier B.V. All rights reserved.
• Rao, P. Venkateswara; Rao, Chebrolu P., Indian Journal of Chemistry, Section A: Inorganic, Physical, Theoretical and Analytical, 2002, vol. 41, # 1, p. 124 - 124
  作者：Rao, P. Venkateswara、Rao, Chebrolu P.

  DOI：——

  日期：——