bis(1-oxo-2-phenylinden-3-yl) sulfide | 24063-04-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 茚和异茚
• 英文名称: bis(1-oxo-2-phenylinden-3-yl) sulfide
• 英文别名: bis-(1-oxo-2-phenyl-3-indenyl)sulfide；bis(1-oxo-2-phenylinden-3-yl)sulfide；bis(3-oxo-2-phenyl-1-indenyl)sulfide；bis(2-phenyl-3-indenonyl) sulfide；Bis-(1-oxo-2-phenyl-inden-3-yl)-sulfid；Bis-(2-phenyl-inden-1-on-3-yl)-sulfid；Bis(1-oxo-2-phenyl-3-indenyl) sulfide；3-(3-oxo-2-phenylinden-1-yl)sulfanyl-2-phenylinden-1-one
• CAS: 24063-04-5
• 化学式: C₃₀H₁₈O₂S
• 分子量: 442.538
• InChiKey: RYNGRQBUTTUOAS-UHFFFAOYSA-N

物化性质

• 熔点：
  200 °C(Solv: methanol (67-56-1))
• 沸点：
  653.4±55.0 °C(Predicted)
• 密度：
  1.37±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  6.7
• 重原子数：
  33
• 可旋转键数：
  4
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  59.4
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  bis(1-oxo-2-phenylinden-3-yl) sulfide 、 乙酸铵 生成 3-Imino-2-phenyl-indanon-(1)
  参考文献：
  名称：

  MUTSENIETSE D. X.; VIGANTE B. A.; ROTBERG YU. T., ZH. ORGAN. XIMII, 1978, 14, HO 1, 152-154

  摘要：

  DOI：
• 作为产物：
  描述：

  生成 bis(1-oxo-2-phenylinden-3-yl) sulfide
  参考文献：
  名称：

  KORCHEVIN N. A.; USOV V. A.; TSETLINA E. O.; PESTUNOVICH V. A.; BOPOHKOB +, XIMIYA GETEROTSIKL. SOEDIN., 1978, HO 1, 36-42

  摘要：

  DOI：

文献信息

• Korchevin, N. A.; Usov, V. A.; Voronkov, M. G., Journal of Organic Chemistry USSR (English Translation), 1986, vol. 22, # 6, p. 1150 - 1154
  作者：Korchevin, N. A.、Usov, V. A.、Voronkov, M. G.、Borodina, N. M.

  DOI：——

  日期：——
• Timokhina, L. V.; Usov, V. A.; Lavlinskaya, L. I., Journal of Organic Chemistry USSR (English Translation), 1985, vol. 21, # 1, p. 108 - 112
  作者：Timokhina, L. V.、Usov, V. A.、Lavlinskaya, L. I.、Voronkov, M. G.

  DOI：——

  日期：——
• Hydrothiolysis of carbofunctional α,β-unsaturated sulfides as an approach to the synthesis of 1,7-dithiocarbonyl compounds
  作者：L. V. Timokhina、O. V. Sokol’nikova、L. V. Kanitskaya、M. P. Yashchenko、D. -S. D. Toryashinova、M. G. Voronkov

  DOI：10.1134/s1070428006080185

  日期：2006.8

  Bis(1-N,N-dimethylimmonio-3-phenylprop-2-en-3-yl) sulfide diperchlorate and (1-N,N-dimethylimmonio-3-phenylprop-2-en-3-yl) (5,5-dimethyl-1-morpholiniocyclohex-2-en-3-yl) sulfide diperchlorate react with hydrogen sulfide giving rise to the corresponding 1,7-thioxoimmonio sulfides. Treating with the hydrogen sulfide (1-N,N-dimethylimmonio-3-phenylprop-2-en-3-yl) (1-oxo-2-phenyl-inden-3-yl) sulfide perchlorate led to preparation of (1-oxo-2-phenylinden-3-yl) (1-thioxo-3-phenylprop-2-en-3-yl) sulfide. The hydrothiolysis of (5,5-dimethyl-1-morpholiniocyclohex-2-en-3-yl) (1-N,N-dimethylimmonio-2-phenylinden-3-yl) sulfide diperchlorate and (5,5-dimethyl-1-morpholiniocyclohex-2-en-3-yl) (1-oxo-2-phenylinden-3-yl) sulfidea perchlorate resulted in products of the sulfide bond cleavage in the initial immonium salts.
• Timokhina; Sokol'nikova; Panova, Russian Journal of Organic Chemistry, 2000, vol. 36, # 11, p. 1665 - 1666
  作者：Timokhina、Sokol'nikova、Panova、Toryashinova、Voronkov

  DOI：——

  日期：——
• Korchevin, N. A.; Usov, V. A.; Voronkov, M. G., Journal of Organic Chemistry USSR (English Translation), 1986, vol. 22, p. 203
  作者：Korchevin, N. A.、Usov, V. A.、Voronkov, M. G.

  DOI：——

  日期：——