8-amino-1-naphthalenethiol | 72319-64-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 8-amino-1-naphthalenethiol
• 英文别名: 8-amino-naphthalene-1-thiol；8-Amino-naphthalin-1-thiol；(8-Amino-naphthyl-(1))-mercaptan；8-Amino-1-mercapto-naphthalin；8-Amino-thionaphthol-(1)；1-Amino-8-naphthalinthiol；8-aminonaphthalene-1-thiol
• CAS: 72319-64-3
• 化学式: C₁₀H₉NS
• 分子量: 175.254
• InChiKey: WADVNNXCMDTMFG-UHFFFAOYSA-N

物化性质

• 熔点：
  75-76 °C
• 沸点：
  366.3±17.0 °C(Predicted)
• 密度：
  1.265±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.6
• 重原子数：
  12
• 可旋转键数：
  0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  27
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  8-amino-1-naphthalenethiol 生成 (+/-)-erythro-3-[(8-Amino-1-naphthalenyl)-thio]-2-hydroxy-3-(4-methoxyphenyl)propanoic Acid Methyl Ester
  参考文献：
  名称：

  摘要：

  DOI：
• 作为产物：
  描述：

  bis-(8-nitro-[1]naphthyl)-disulfide 在 溶剂黄146 、 锌 作用下， 生成 8-amino-1-naphthalenethiol
  参考文献：
  名称：

  Reissert, Chemische Berichte, 1922, vol. 55, p. 873

  摘要：

  DOI：

文献信息

• NOVEL TETRACARBOXYLIC DIANHYDRIDE, POLYIMIDE RESIN AND METHOD FOR PRODUCING THE SAME, PHOTOSENSITIVE RESIN COMPOSITIONS, PATTERNING PROCESS, METHOD FOR FORMING CURED FILM, INTERLAYER INSULATING FILM, SURFACE PROTECTIVE FILM, AND ELECTRONIC PARTS
  申请人：SHIN-ETSU CHEMICAL CO., LTD.

  公开号：US20190169211A1

  公开（公告）日：2019-06-06

  The present invention has been made in view of the circumstances herein. An object of the present invention is to provide: a tetracarboxylic dianhydride which can lead to a polyimide usable as a base resin of a photosensitive resin composition capable of forming a fine pattern and obtaining high resolution without impairing excellent characteristics such as mechanical strength and adhesiveness; a polyimide resin obtained by using the tetracarboxylic dianhydride; and a method for producing the polyimide resin. The tetracarboxylic dianhydride is shown by the following general formula (1).

  本发明是基于本文中的情况而作出的。本发明的目的是提供：一种四羧酸二酐，可导致聚酰亚胺，作为感光树脂组合物的基树脂，能够形成细微图案并获得高分辨率，同时不损害优异的特性，如机械强度和粘附性；通过使用该四羧酸二酐获得的聚酰亚胺树脂；以及生产该聚酰亚胺树脂的方法。该四羧酸二酐由以下通用式（1）所示。
• General synthetic approach towards annelated 3a,6-epoxyisoindoles by tandem acylation/IMDAF reaction of furylazaheterocycles. Scope and limitations
  作者：Fedor I. Zubkov、Eugenia V. Nikitina、Timur R. Galeev、Vladimir P. Zaytsev、Victor N. Khrustalev、Roman A. Novikov、Daria N. Orlova、Alexey V. Varlamov

  DOI：10.1016/j.tet.2014.01.008

  日期：2014.2

  investigated. The obtained Diels–Alder adducts are attractive and useful substrates for further transformations. Fused isoindoles can be prepared from them in one-step by aromatization of the 7-oxabicyclo[2.2.1]heptene ring. Other transformations, including halogenation, ring cleavage, and Wagner–Meerwein skeletal rearrangement, are also demonstrated. The spatial structures of the obtained compounds have

  提出了与恶嗪，恶唑，噻嗪，噻唑，嘧啶片段及其苯甲酰化类似物退火的3,6a-环氧异吲哚的一种有效且通用的一锅合成方法。该方法基于α，β-不饱和酸酐与α-呋喃基取代的氮杂杂环之间的串联N-酰化/分子内环加成反应（呋喃的分子内Diels-Alder反应，IMDAF）。后者可通过将各种糠醛与1,2-或1,3-N，X-双亲核试剂（氨基醇，氨基硫醇，二胺）缩合而轻松制备。观察到的IMDAF反应是立体选择性的：仅在非对映异构体之一普遍存在的情况下才形成外加合物。在大多数情况下，缩合/ N-酰化/ IMDAF反应顺序可以通过一锅多米诺协议进行。对该方法的范围和局限性进行了彻底的研究。所获得的Diels–Alder加合物是诱人且有用的底物，可用于进一步转化。熔融异吲哚可通过将7-氧杂双环[2.2.1]庚烯环芳构化而一步一步制得。还显示了其他转化，包括卤化，环裂解和Wagner-Meerwein骨架重排。通过
• 유기전기 소자용 화합물, 이를 이용한 유기전기소자 및 그 전자 장치
  申请人：DUK SAN NEOLUX CO., LTD. 덕산네오룩스 주식회사(120150011099) Corp. No ▼ 161511-0176036BRN ▼312-86-74729

  公开号：KR20190010811A

  公开（公告）日：2019-01-31

  본 발명은 소자의 높은 발광효율, 낮은 구동전압 및 수명을 향상시킬 수 있는 화합물, 이를 이용한 유기전기소자 및 그 전자장치를 제공한다.

  本发明提供了一种化合物，可提高器件的高发光效率、低驱动电压和寿命，以及利用该化合物的有机电子器件和电子设备。
• NOVEL COMPOUND, POLYIMIDE RESIN AND METHOD OF PRODUCING THE SAME, PHOTOSENSITIVE RESIN COMPOSITION, PATTERNING METHOD AND METHOD OF FORMING CURED FILM, INTERLAYER INSULATING FILM, SURFACE PROTECTIVE FILM, AND ELECTRONIC COMPONENT
  申请人：International Business Machines Corporation

  公开号：US20210317270A1

  公开（公告）日：2021-10-14

  Provided is a compound that can be used as a base resin for a photosensitive resin composition. The photosensitive resin can form a fine pattern and can achieve high resolution without impairing mechanical strength and solubility. The compound is represented by the general formula (1): wherein Z represents a linear, branched or cyclic divalent hydrocarbon group having 2 to 30 carbon atoms; X 1 to X 3 represent any of —CO 2 —, —CONR X1 —, —O—, —NR X1 —, —S—, —SO 2 —, —SO 3 — and —SO 2 NR X1 — and may be the same as or different from each other, provided that R X1 is a hydrogen atom or a monovalent hydrocarbon group having 1 to 30 carbon atoms; Ar represents a divalent aromatic group having 2 to 30 carbon atoms; L 1 and L 2 independently represent a divalent hydrocarbon group having 1 to 30 carbon atoms; and x and y are each independently 0 or 1.

  提供的是一种可以用作光敏树脂组合物的基树脂的化合物。这种光敏树脂可以形成精细图案，并且可以在不影响机械强度和溶解性的情况下实现高分辨率。该化合物由通式（1）表示：其中Z代表具有2到30个碳原子的线性、支链或环状二价碳氢基团；X1到X3代表任何一种—CO2—、—CONRX1—、—O—、—NRX1—、—S—、—SO2—、—SO3—和—SO2NRX1—中的一种，并且它们可以相同也可以不同，只要RX1是氢原子或具有1到30个碳原子的一价碳氢基团；Ar代表具有2到30个碳原子的二价芳香基团；L1和L2分别代表具有1到30个碳原子的二价碳氢基团；x和y分别独立地为0或1。
• Interactions between Functional Groups Part IV. The responses of four diazonium groups to adjacent electron-rich atoms in peri-substituted naphthalene and quinoline derivatives
  作者：John D. Wallis、Robert J. C. Easton、Jack D. Dunitz

  DOI：10.1002/hlca.19930760402

  日期：1993.6.30

  naphthalene-1-diazonium cations all show short attractive interactions between an electron-rich atom of the peri-substituent and the α -N-atom of the diazonium group. These are interpreted as models for incipient nucleophilic attack on a NN bond. The diazonium group is a better acceptor of electron density ‘through space’ than the NO2 group, which parallels their relative ‘through-σ-bond’ inductive effects.

  四个被周围取代的萘-1-重氮阳离子均显示出在周围取代基的富电子原子与重氮基团的α-N原子之间的短暂吸引相互作用。这些被解释为对NN键的初期亲核攻击的模型。与NO 2基团相比，重氮基团是更好的电子密度“穿透空间”受体，这与它们的相对“穿透-σ-键”感应效应平行。