1-氨基-2-萘硫醇 | 63512-54-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 中文名称: 1-氨基-2-萘硫醇
• 英文名称: 1-aminonaphthalene-2-thiol
• 英文别名: 1-amino-2-naphthalenethiol；1-Amino-naphthalin-2-thiol；1-Amino-2-mercapto-naphthalin；1-Amino-thionaphthol-(2)；(1-Amino-naphthyl-(2))-mercaptan
• CAS: 63512-54-9
• 化学式: C₁₀H₉NS
• 分子量: 175.254
• InChiKey: VPSMSRGGNXFQIO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.6
• 重原子数：
  12
• 可旋转键数：
  0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  27
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  1-氨基-2-萘硫醇 生成 1,1-二氨基-2,2-二萘二硫化物
  参考文献：
  名称：

  Jacobson, Chemische Berichte, 1887, vol. 20, p. 1899

  摘要：

  DOI：
• 作为产物：
  描述：

  安妥 在 氢氧化钾 、 ammonium hydroxide 、 溴 、 溶剂黄146 作用下， 以 乙二醇甲醚 、 水 为溶剂， 生成 1-氨基-2-萘硫醇
  参考文献：
  名称：

  新的1,4-苯并噻嗪衍生物的合成和生物活性。

  摘要：

  合成了新的2H-1,4-苯并噻嗪-3（4H）-在2位具有（4-苯基-1-哌嗪基）烷基部分的衍生物，并测试了其钙拮抗和钙调蛋白拮抗活性。还评估了自发性高血压大鼠的抗高血压作用。通常，这些化合物是相当弱的钙通道阻滞剂，尽管相反，它们中的许多具有中度至强效的钙调蛋白拮抗活性，以及​​2- [3-（4-（4-氟苯基）-1-哌嗪基]丙基]- 2H-1,4-苯并噻嗪-3（4H）-一衍生物45、74和75显示有效的降压作用。

  DOI：

  10.1248/cpb.39.2888

文献信息

• Metallic Compound and Organic Electroluminescence Device Comprising the Same
  申请人：Suh Dong-Hack

  公开号：US20080200678A1

  公开（公告）日：2008-08-21

  The present invention relates to a light-emitting transition metal compound represented by the Chemical Formula 1 and Chemical Formula 2 and an organic electroluminescence device including the same. In the Chemical Formulae 1 and 2, M is Ir, Pt, Rh, Re, Os, and the like, m is 2 or 3, n is 0 or 1, the sum of m and n is 3, provided that the sum of m and n is 2 when M is Pt, X, and Z are the same or different, N or P, and Y and Q are O, S, or Se, R 1 and R 5 are hydrogen, a C1 to C20 alkyl excluding an aromatic cyclic substituent, a cycloalkyl, a halogen, a linear or branched substituent including at least one halogen, or a linear or branched substituent including at least one heteroatom, and R 2 , R 3 , R 4 , R 6 , R 7 , R 8 , R 9 , and R 10 are hydrogen, a C1 to C20 alkyl, an aryl, a cycloalkyl, a halogen, a linear or branched substituent including at least one halogen, a linear or branched substituent including at least one heteroatom, carbonyl, vinyl, or acetylenyl, or may form a cycle, and may be the same or different.

  本发明涉及一种由化学式1和化学式2表示的发光过渡金属化合物，以及包括该化合物的有机电致发光器件。在化学式1和2中，M为Ir、Pt、Rh、Re、Os等，m为2或3，n为0或1，m和n的总和为3，当M为Pt时，m和n的总和为2，X和Z相同或不同，为N或P，Y和Q为O、S或Se，R1和R5为氢、除芳香环取代基外的C1到C20烷基、环烷基、卤素、线性或支链取代基，包括至少一个卤素，或包括至少一个杂原子的线性或支链取代基，R2、R3、R4、R6、R7、R8、R9和R10为氢、C1到C20烷基、芳基、环烷基、卤素、线性或支链取代基，包括至少一个卤素，线性或支链取代基，包括至少一个杂原子，羰基、烯基或乙炔基，或可形成环，并且可以相同或不同。
• NOVEL TETRACARBOXYLIC DIANHYDRIDE, POLYIMIDE RESIN AND METHOD FOR PRODUCING THE SAME, PHOTOSENSITIVE RESIN COMPOSITIONS, PATTERNING PROCESS, METHOD FOR FORMING CURED FILM, INTERLAYER INSULATING FILM, SURFACE PROTECTIVE FILM, AND ELECTRONIC PARTS
  申请人：SHIN-ETSU CHEMICAL CO., LTD.

  公开号：US20190169211A1

  公开（公告）日：2019-06-06

  The present invention has been made in view of the circumstances herein. An object of the present invention is to provide: a tetracarboxylic dianhydride which can lead to a polyimide usable as a base resin of a photosensitive resin composition capable of forming a fine pattern and obtaining high resolution without impairing excellent characteristics such as mechanical strength and adhesiveness; a polyimide resin obtained by using the tetracarboxylic dianhydride; and a method for producing the polyimide resin. The tetracarboxylic dianhydride is shown by the following general formula (1).

  本发明是基于本文中的情况而作出的。本发明的目的是提供：一种四羧酸二酐，可导致聚酰亚胺，作为感光树脂组合物的基树脂，能够形成细微图案并获得高分辨率，同时不损害优异的特性，如机械强度和粘附性；通过使用该四羧酸二酐获得的聚酰亚胺树脂；以及生产该聚酰亚胺树脂的方法。该四羧酸二酐由以下通用式（1）所示。
• MONOAZO COMPOUND AND METHOD FOR PRODUCING SAME
  申请人：Kabushiki Kaisha Ueno Seiyaku Oyo Kenkyujo

  公开号：EP1650267A1

  公开（公告）日：2006-04-26

  The present invention provides a monoazo compound represented by formula (1) or a salt thereof: wherein, Y1 and Y2 represent a group selected from hydrogen atom, formula (2) and formula (3);         -CO-E-X     (3) provided that at least one of Y1 and Y2 is a group represented by formula (2); Z is a group selected from formulae (4), (5) and (6);

  本发明提供一种由化学式（1）表示的单偶氮化合物或其盐：其中，Y1和Y2代表从氢原子、化学式（2）和化学式（3）中选择的基团；其中至少有一个Y1和Y2是由化学式（2）表示的基团；Z是从化学式（4）、（5）和（6）中选择的基团。
• Naphtho[1,2-b][1,4]thiazepin-4(5H)-ones and use thereof in treatment of
  申请人：Hoffmann-La Roche Inc.

  公开号：US04808580A1

  公开（公告）日：1989-02-28

  Compounds of the formula: ##STR1## wherein R.sub.1 is phenyl substituted with 1 to 3 substituents selected from the group consisting of lower alkoxy and halogen; R.sub.2 is hydroxy, lower alkoxy, lower alkanoyloxy, lower cycloalkylcarbonyloxy; ##STR2## or ##STR3## R.sub.3 and R.sub.4 are independently lower alkyl, phenyl lower alkyl or together form a piperidine or pyrrolidine ring; n is 2 to 4; m is 1 to 2; or pharmaceutically acceptable acid addition salts thereof are described. The compounds of formula I have activity as calcium channel blockers and accordingly, are useful as agents for lowering blood pressure, and as agents for treating ischemia.

  公式如下：##STR1## 其中R.sub.1是苯基，上面带有1到3个取代基，选择自下列取代基组成：较低的烷氧基和卤素；R.sub.2是羟基、较低的烷氧基、较低的烷酰氧基、较低的环烷基羰基氧基；##STR2## 或 ##STR3## R.sub.3 和 R.sub.4 分别是较低的烷基、苯基较低的烷基，或者一起形成哌啶环或吡咯环；n为2到4；m为1到2；或其药学上可接受的酸盐。公式I的化合物具有作为钙通道阻滞剂的活性，因此，它们可用作降低血压的药物，以及用于治疗缺血的药物。
• Structure Determination from Powder X-ray Diffraction Data of Black Azo (Hydrazone) Pigments
  作者：Junji Otani、Michio Matsumura、Kotaro Fujii、Hidehiro Uekusa

  DOI：10.1246/cl.150036

  日期：2015.5.5

  Crystal structures of two black monoazo (hydrazone) pigments have been determined from powder X-ray diffraction data combined with DFT calculations. The DFT calculations suggested the molecules are in hydrazone forms but not in azo forms in both crystal structures. The molecular arrangements in the crystal structures suggested Davydov splitting may occur by excitonic interactions and it causes the red absorption band shift in the crystalline state leading to the characteristic black colors.

  结合粉末X射线衍射数据与DFT计算，确定了两种黑色单偶氮（脎）颜料的晶体结构。DFT计算表明，在这两种晶体结构中，分子均以脎形式存在而非偶氮形式。晶体结构中的分子排列暗示了由激子相互作用引起的达维多夫分裂，这种分裂导致晶态下红色吸收带发生偏移，从而呈现出特有的黑色。