chlorosulfenyl[O-(1-methylthioethylimino)-N-methylcarbamate] | 1051431-26-5

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫基化合物
• 英文名称: chlorosulfenyl[O-(1-methylthioethylimino)-N-methylcarbamate]
• CAS: 1051431-26-5
• 化学式: C₅H₉ClN₂O₂S₂
• 分子量: 228.724
• InChiKey: UGVKILBMGPDTKX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.55
• 重原子数：
  12.0
• 可旋转键数：
  2.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.6
• 拓扑面积：
  41.9
• 氢给体数：
  0.0
• 氢受体数：
  5.0

反应信息

• 作为反应物：
  描述：

  chlorosulfenyl[O-(1-methylthioethylimino)-N-methylcarbamate] 在 吡啶 作用下， 以 二氯甲烷 为溶剂， 生成 penfluron-S-methomyl
  参考文献：
  名称：

  Insecticidal Benzoylphenylurea-S-Carbamate:  A New Propesticide with Two Effects of Both Benzoylphenylureas and Carbamates

  摘要：

  New propesticides with two effects of both benzoylphenylureas and carbamates were designed and synthesized by the key intermediate N-chlorosulfenyl-N-methylcarbamate, which was prepared for the first time. These benzoylphenylurea-S-carbamates were identified by H-1 NMR spectroscopy and elemental analyses. The bioactivities of the new compounds were evaluated. These benzoylphenylurea-S-carbamates exhibited excellent larvicidal activities against Oriental armyworm, some of which were good as compared to the parent benzoylphenylureas. Toxicity assays indicated that these benzoylphenylurea-S-carbamates had knockdown activities of carbamates at higher concentrations and insect growth regulator activities of benzoylphenylureas at lower concentrations. We found that the title compounds exhibited good systemic larvicidal activities against Oriental armyworm, which were especially advantageous when combating sucking pests. Some of these title compounds can kill aphids and mosquitoes as well.

  DOI：

  10.1021/jf063564g
• 作为产物：
  描述：

  灭多威 在 吡啶 、 二氯化硫 作用下， 以 二氯甲烷 为溶剂， 反应 4.0h， 生成 chlorosulfenyl[O-(1-methylthioethylimino)-N-methylcarbamate]
  参考文献：
  名称：

  N-叔丁基-N′-硫代[O-(1-甲硫基乙基亚氨基)-N″-甲基氨基甲酸酯]-N,N′-二酰基肼的合成及杀虫评价

  摘要：

  通过氯磺基[O-(1-甲硫基乙亚氨基)-N”-甲基氨基甲酸酯]-N,N'-二酰基肼的反应合成了一系列新型N-叔丁基-N'-硫代[O-(1-甲硫基乙基亚氨基)-N”-甲基氨基甲酸酯]-N,N'-二酰基肼-N-甲基氨基甲酸酯]与 N-叔丁基-N,N'-二酰基肼在氢化钠存在下。首次报道了二氯化硫与O-(1-甲硫基乙基亚氨基)-N-甲基氨基甲酸酯(灭多威)在吡啶存在下反应生成氯磺基[O-(1-甲硫基乙基亚氨基)-N-甲基氨基甲酸酯]。N-叔丁基-N'-硫代[O-(1-甲硫基乙基亚氨基)-N″-甲基氨基甲酸酯]-N,N'-二苯甲酰肼的X射线单晶衍射表明母体化合物N-叔丁基-N ,N'-二苯甲酰肼和O-(1-甲硫基乙基亚氨基)-N-甲基氨基甲酸酯通过NSN谱带结合得到产物。评价了它们对东方粘虫和蚜虫的杀幼虫活性。它们都对东方粘虫表现出优异的杀幼虫活性，其中一些表现出比亲本二酰基肼更高的杀幼虫活性。毒性试验表明，该产品在较高浓度下对

  DOI：

  10.1002/hc.20360