butyltetramethylene sulfone | 71053-03-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 硫杂环戊烷
• 英文名称: butyltetramethylene sulfone
• 英文别名: 2-n-Butylthiolane, S,S-dioxide；2-butylthiolane 1,1-dioxide
• CAS: 71053-03-7
• 化学式: C₈H₁₆O₂S
• 分子量: 176.28
• InChiKey: YZERTSBRDCEIGS-UHFFFAOYSA-N

物化性质

• 沸点：
  304.4±10.0 °C(Predicted)
• 密度：
  1.062±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.9
• 重原子数：
  11
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  42.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  butyltetramethylene sulfone 生成 2,2'-Bis(perfluoroctylsulfonyloxy)biphenyl
  参考文献：
  名称：

  Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: F: PerFHalOrg.2, 1.3.4, page 137 - 166

  摘要：

  DOI：
• 作为产物：
  描述：

  环丁砜 、 正溴丁烷 在 正丁基锂 作用下， 生成 butyltetramethylene sulfone
  参考文献：
  名称：

  Frazier, L.; Claypool, D. P., Synthetic Communications, 1988, vol. 18, # 6, p. 583 - 588

  摘要：

  DOI：

文献信息

• [EN] INTEGRATED PROCESS FOR PRODUCING CYCLIC ACETALS AND OXYMETHYLENE POLYMERS<br/>[FR] PROCÉDÉ INTÉGRÉ DE PRODUCTION D'ACÉTALS CYCLIQUES ET DE POLYMÈRES D'OXYMÉTHYLÈNE
  申请人：TICONA GMBH

  公开号：WO2013076288A1

  公开（公告）日：2013-05-30

  A process for producing cyclic acetals is described. A formaldehyde source is contacted with an aprotic compound in the presence of a catalyst to produce the cyclic acetals. The aprotic compound can increase conversion rates and/or efficiency. In one embodiment, the formaldehyde source is obtained from methanol. In particular, methanol can be converted into formaldehyde which is then converted into a cyclic acetal. In one embodiment, the cyclic acetal can then be used to produce oxymethylene polymers.

  本文描述了一种制备环状缩醛的过程。在催化剂的存在下，将甲醛源与非质子溶剂化合物接触以产生环状缩醛。非质子溶剂可以提高转化率和/或效率。在一种实施方式中，甲醛源来自甲醇。特别地，甲醇可以转化为甲醛，然后再转化为环状缩醛。在一种实施方式中，环状缩醛可以用于制备氧甲基聚合物。
• [EN] PROCESS FOR PRODUCING A CYCLIC ACETAL IN A HETEROGENEOUS REACTION SYSTEM<br/>[FR] PROCÉDÉ DE PRODUCTION D'UN ACÉTAL CYCLIQUE DANS UN SYSTÈME RÉACTIONNEL HÉTÉROGÈNE
  申请人：TICONA GMBH

  公开号：WO2013076290A1

  公开（公告）日：2013-05-30

  A process for producing a cyclic acetal is disclosed. According to the process, a formaldehyde source is combined with an aprotic compound and contacted with a heterogeneous catalyst which causes the formaldehyde source to convert into a cyclic acetal such as trioxane. The catalyst, for instance, may comprise a solid catalyst such as an ion exchange resin. In one embodiment, the process is used for converting anhydrous formaldehyde gas to trioxane. The anhydrous formaldehyde gas may be produced form an aqueous formaldehyde solution by an extractive distillation.

  本发明揭示了一种生产环状缩醛的工艺。根据该工艺，将甲醛源与无质子溶剂化合物结合，并与使甲醛源转化为环状缩醛的异相催化剂接触。例如，催化剂可以包括固体催化剂，如离子交换树脂。在一种实施例中，该工艺用于将无水甲醛气体转化为三聚氧杂环己烷。无水甲醛气体可以通过萃取蒸馏从水甲醛溶液中产生。
• ACROLEIN MANUFACTURING METHOD AND ACRYLIC ACID MANUFACTURING METHOD
  申请人：Aoki Takanori

  公开号：US20110087050A1

  公开（公告）日：2011-04-14

  The present invention relates to a method for producing acrolein, comprising step (1) of subjecting glycerol to dehydration reaction in the presence of a copper compound and a compound containing a heteroatom; step (2) of recovering acrolein generated in the dehydration reaction step (1); step (3) of recovering part or all of the copper compound which remained after the recovery of acrolein; step (4) of treating part or all of the recovered copper compound with at least one member selected from a group consisting of an oxidizing agent and acid; and step (5) of returning part or all of the copper compound treated in the above step to step (1); and a method for producing acrylic acid, comprising reacting acrolein obtained by the above method with molecular oxygen. The production method of the present invention enables efficient production of acrolein and acrylic acid from glycerol contained in plant oil and animal fats derived from carbon dioxide in air without depending on the oxidation of propylene derived from fossil resources.

  本发明涉及一种制备丙烯醛的方法，包括步骤（1）：在铜化合物和含有杂原子的化合物的存在下，将甘油进行脱水反应；步骤（2）：回收在脱水反应步骤（1）中生成的丙烯醛；步骤（3）：在回收丙烯醛后，回收部分或全部剩余的铜化合物；步骤（4）：用至少选自氧化剂和酸的一种成员处理部分或全部回收的铜化合物；步骤（5）：将上述步骤中处理的部分或全部铜化合物返回步骤（1）。本发明还涉及一种制备丙烯酸的方法，包括将通过上述方法获得的丙烯醛与分子氧反应。本发明的生产方法能够高效地从植物油和动物脂肪中含有的甘油中制备丙烯醛和丙烯酸，而不依赖于来自化石资源的丙烯氧化。
• TETRAHYDROPYRANOCHROMENE GAMMA SECRETASE INHIBITORS
  申请人：Wu Wen-Lian

  公开号：US20110236400A1

  公开（公告）日：2011-09-29

  Disclosed are novel gamma secretase inhibitors of the formula. Also disclosed are methods of inhibiting gamma-secretase, methods of treating neurodegenerative diseases, and methods of treating Alzheimer's Disease. Also disclosed are processes for preparing alkenes in one reaction step using a mixture of an aldehyde (or ketone) and an alkyl substituted with two electron withdrawing groups, and reacting the mixture with: (a) a sulfonyl halide (e.g., a sulfonyl chloride) and a basic tertiary amine, or, (b) a sulfonyl anhydride and a basic amine, or (c) an aryl-C(O)-halide and a basic tertiary amine, or (d) an aryl-C(O)—O—C(O)-aryl and a basic tertiary amine, or (e) an heteroaryl-C(O)-halide and a basic tertiary amine, or (f) a heteroaryl-C(O)—O—C(O)-heteroaryl and a basic tertiary amine.

  本发明涉及一种新型伽马分泌酶抑制剂的公开。还公开了抑制伽马分泌酶的方法、治疗神经退行性疾病的方法和治疗阿尔茨海默病的方法。还公开了一种使用醛（或酮）和烷基取代的两个电子提取基团的混合物，在一步反应中制备烯烃的方法，并将该混合物与：（a）磺酰卤化物（例如磺酰氯）和碱性三级胺反应，或（b）磺酰酐和碱性胺反应，或（c）芳基-C（O）-卤和碱性三级胺反应，或（d）芳基-C（O）-O-C（O）-芳基和碱性三级胺反应，或（e）杂环芳基-C（O）-卤和碱性三级胺反应，或（f）杂环芳基-C（O）-O-C（O）-杂环芳基和碱性三级胺反应。
• Ink jet ink compositions and processes for high resolution and high speed printing
  申请人：XEROX CORPORATION

  公开号：EP0853108A1

  公开（公告）日：1998-07-15

  A thermal ink jet printing comprises incorporating into a thermal ink jet printer at least one ink jet ink with an ink composition comprising water; a colorant of a dye or pigment; a hydroxyamide derivative having at least one hydroxyl group and at least one amide group or a reaction product of oxyalkylene(s) and the said hydroxyamide derivative; a sulfur-containing humectant that is a sulfoxide or a sulfone or a thiol derivative. Printing with the ink jet ink is according to digital signals with at least one printhead which is selected from a group consisting of single, partial-width, and full-width array printheads using a checkerboard or single pass method onto a print substrate either with or without the presence of heat for drying. The ink jet ink has a good latency, long-term jetting stability, and good image quality on plain papers when it is used in a high resolution thermal ink jet printhead including a 600 spi printhead.

  一种热喷墨打印包括在热喷墨打印机中加入至少一种喷墨墨水，其墨水组合物包括水；染料或颜料的着色剂；具有至少一个羟基和至少一个酰胺基的羟酰胺衍生物或氧亚烷基与上述羟酰胺衍生物的反应产物；亚砜或砜或硫醇衍生物的含硫保湿剂。喷墨墨水的打印是根据数字信号，使用至少一个打印头，该打印头选自单个、部分宽度和全宽度阵列打印头组成的组，使用棋盘式或单程方法打印到打印基底上，可以有或没有加热干燥。当喷墨墨水用于包括 600 spi 喷头在内的高分辨率热喷墨喷头时，具有良好的延迟性、长期喷射稳定性以及在普通纸上的良好图像质量。