2-(2-hydroxybenzylideneamino)ethanesulfonic acid | 63346-85-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 酚类
• 英文名称: 2-(2-hydroxybenzylideneamino)ethanesulfonic acid
• 英文别名: Salicylidenetaurine；Ethanesulfonic acid, 2-[[(2-hydroxyphenyl)methylene]amino]-；2-[(2-hydroxyphenyl)methylideneamino]ethanesulfonic acid
• CAS: 63346-85-0
• 化学式: C₉H₁₁NO₄S
• 分子量: 229.257
• InChiKey: NRMJWVBMZKPSSH-UHFFFAOYSA-N

物化性质

• 密度：
  1.35±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  0
• 重原子数：
  15
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.22
• 拓扑面积：
  95.3
• 氢给体数：
  2
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  2-(2-hydroxybenzylideneamino)ethanesulfonic acid 、 copper dichloride 以 水 为溶剂， 生成
  参考文献：
  名称：

  Haemaelaeinen, Reijo; Turpeinen, Urho; Salo, Marja, Zeitschrift fur Kristallographie

  摘要：

  DOI：
• 作为产物：
  描述：

  牛磺酸 、 水杨醛 以 水 为溶剂， 反应 3.0h， 生成 2-(2-hydroxybenzylideneamino)ethanesulfonic acid
  参考文献：
  名称：

  Magnetism of novel Schiff-base copper(II) complexes derived from aminoacids

  摘要：

  Magnetic properties of five copper(II) complexes of the formula [CuL3(H2O)(2)] or [CuL4(H2O)] were investigated. These contain a Schiff-base L derived from salicylaldehyde and aminoacids. The ligand L is represented by four bonding isomers (1 through 4) and it is either tridentate (L-3) or tetradentate (L-4). The fifth ligand contains sulfonato group instead of the carboxyl one. Structurally, two complexes are monomers (I and 4), one is a dimer (5), and two are polymers (2 and 3). Their magnetic behaviour is more complex: 1 behaves as an antiferromagnetic Heisenberg diad, 2 and 4 are ferromagnetic chains, 3 is a combined ferromagnetic/antiferromagnetic ladder (ribbon), and 5 exhibits a complex 3D-ordering with unusual temperature evolution of the effective magnetic moment. (C) 2013 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2013.05.045

文献信息

• Syntheses, Structures, Thermal and Photoluminescence Properties of Two Zn(II) and Cd(II) Coordination Polymers Constructed from Taurine-derived Schiff Base and 4,4’-Bipyridine Ligands
  作者：Wei-Ting Guo、Zhi-Min Miao、Yun-Long Wang

  DOI：10.5560/znb.2012-0170

  日期：2012.8.1

  O-monodentate ligand in 2. In the crystal, both 1and 2form a 3D supramolecular architecture by O-H···O, C-H···O interactions or π···π stacking. The thermal and solid-state photoluminescence properties of both complexes have been investigated Graphical Abstract Syntheses, Structures, Thermal and Photoluminescence Properties of Two Zn(II) and Cd(II) Coordination Polymers Constructed from Taurine-derived Schiff

  两种链状配位聚合物，即[Zn(saes)(4,4'-bipy)(H2O)]· }n(1)和[Cd(Hsaes)2(4,4'-bipy) ( )2]·2 }n (2)，其中H2saes=2-(2-羟基亚苄基氨基)乙磺酸和4,4'-bipy=4,4'-联吡啶，已被合成并通过单晶X射线表征衍射、红外光谱、元素、热重和光致发光分析。X 射线衍射分析表明，1 和 2 分别显示具有 N3O3 和 N2O4 供体组的八面体金属中心。席夫碱在 1 中作为常见的 N,O'-三齿配体，在 2 中作为独特的 O-单齿配体。 在晶体中，1 和 2 均通过 OH···O、CH···形成 3D 超分子结构O 相互作用或 π……π 堆积。
• Lia, Jia-Ming; He, Kun-Huan; Jiang, Yi-Min, Zeitschrift fur Naturforschung, B: Chemical Sciences, 2012, vol. 67, # 1, p. 11 - 16
  作者：Lia, Jia-Ming、He, Kun-Huan、Jiang, Yi-Min

  DOI：——

  日期：——
• A New One-Dimensional Double Chains Cobalt Coordination Polymer With Taurine Schiff-Base and 4,4′-Bipyridine Ligands: Synthesis, Spectral, Thermal Properties, and Crystal Structure
  作者：Jiaming Li、Kunhuan He、Yimin Jiang

  DOI：10.1080/15533174.2012.752391

  日期：2013.7.3

  A new 1D double chains cobalt(II) coordination polymer with the doubly deprotonated Schiff-base and 4,4-bipyridine ligands, [Co(Saes)(H2O)(Bipy)]center dot H2O}n, where H2Saes = 2-(2-hydroxy- benzylideneamino)ethanesulfonic acid, has been synthesized and characterized by single-crystal X-ray diffraction, IR spectroscopy, and elemental and thermogravimetric analysis. The asymmetric unit of 1 comprises two cobalt(II) dimmer with tridentate Schiff-base, 4,4-bipyridine, and water molecule ligands with the N3O3 donor set, exhibiting a slightly distorted octahedral geometry. In the crystal, dimmers are interacted with O-H center dot center dot center dot O, C-H center dot center dot center dot O interactions and C-H center dot center dot center dot stacking, leading to an interwoven three-dimensional network and stabilizing the coordination complex. The spectral and thermal properties are also discussed.