dichlorotrifluoroethane sulphenic acid chloride | 20705-19-5

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫基化合物
• 英文名称: dichlorotrifluoroethane sulphenic acid chloride
• 英文别名: 2,2-dichlorotrifluoroethanesulfenyl chloride；2,2-dichlorotrifluoroethylsulfenyl chloride；1,1,2-Trifluor-2,2-dichlor-1-chlormercapto-aethan；(2,2-dichloro-1,1,2-trifluoroethyl) thiohypochlorite
• CAS: 20705-19-5
• 化学式: C₂Cl₃F₃S
• 分子量: 219.442
• InChiKey: MARWZDQJIMZWMW-UHFFFAOYSA-N

物化性质

• 沸点：
  112 °C
• 密度：
  1.740±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.6
• 重原子数：
  9
• 可旋转键数：
  1
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  25.3
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  乙烯酮 、 dichlorotrifluoroethane sulphenic acid chloride 以 四氯化碳 为溶剂， 反应 0.5h， 以55%的产率得到2,2-dichlorotrifluoroethylthioacetyl chloride
  参考文献：
  名称：

  Electrophilic addition of 2-chloropolyfluoroalkylsulfenyl chlorides to ketene

  摘要：

  DOI：

  10.1007/bf00962023
• 作为产物：
  描述：

  bis-(2,2-dichlorotrifluoroethyl) disulfide 在 氯 作用下， 反应 8.0h， 以82%的产率得到dichlorotrifluoroethane sulphenic acid chloride
  参考文献：
  名称：

  Fokin, A. V.; Shkurak, S. N.; Kolomiets, A. F., Journal of Organic Chemistry USSR (English Translation), 1985, vol. 21, p. 1678 - 1682

  摘要：

  DOI：

文献信息

• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: F: PerFHalOrg.1, 1.1.6.5.2, page 157 - 193
  作者：

  DOI：——

  日期：——
• Kondrashov, N. V.; Kolomiets, A. F.; Sokol'skii, G. A., Journal of Organic Chemistry USSR (English Translation), 1986, vol. 22, p. 463 - 466
  作者：Kondrashov, N. V.、Kolomiets, A. F.、Sokol'skii, G. A.

  DOI：——

  日期：——
• ——
  作者：R. N. Serdyuk、A. Yu. Sizov、A. F. Ermolov

  DOI：10.1023/a:1026033527150

  日期：——

  A procedure was developed for the synthesis of polyfluoroalkylthiotrifluoroacetylketenes, and their reactions with nucleophilic reagents were studied. The resulting compounds were demonstrated to act as heterodienes in reactions with unsaturated compounds.
• Reactions of polyfluoroalkylsulfenyl chlorides with phenols
  作者：A. Yu. Sizov、A. F. Kolomiets、A. V. Fokin

  DOI：10.1007/bf00961248

  日期：1991.7

  Polyfluoroalkylsulfenyl chlorides thiolate phenol and its ortho- and meta-substituted derivatives regiospecifically at the para-position in the absence of a catalyst and of a hydrogen chloride acceptor. Ortho thiolation occurs with significantly greater difficulty in the para-substituted phenols, and is only possible with the strong electron-donor properties of the substituent. Polyfluoroalkylthiolation of phenols is rendered more difficult with the increase in the steric impediments at the sulfur atom of the sulfenyl chloride and the volume of the substituents by the OH group of the phenol.
• Reaction of polyfluoroalkylsulfenyl chlorides with ?,?-unsaturated acids and their derivatives
  作者：A. Yu. Sizov、V. V. Linev、N. V. Kondrashov、A. F. Kolomiets、A. V. Fokin

  DOI：10.1007/bf00963018

  日期：1990.1