3-甲基萘-1,2,4-三醇 | 70691-78-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 中文名称: 3-甲基萘-1,2,4-三醇
• 英文名称: 3-methyl-naphthalene-1,2,4-triol
• 英文别名: 1,3,4-Trihydroxy-2-methyl-naphthalin；3-Methyl-naphthalin-1,2,4-triol；2-Methyl-naphthalin-1,3,4-triol；2-Methyl-1,3,4-trihydroxynaphthalene；3-methylnaphthalene-1,2,4-triol
• CAS: 70691-78-0
• 化学式: C₁₁H₁₀O₃
• 分子量: 190.199
• InChiKey: ATIBDYUPBDXLAU-UHFFFAOYSA-N

物化性质

• 熔点：
  184-186 °C
• 沸点：
  439.1±15.0 °C(Predicted)
• 密度：
  1.407±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.5
• 重原子数：
  14
• 可旋转键数：
  0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.09
• 拓扑面积：
  60.7
• 氢给体数：
  3
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  3-甲基萘-1,2,4-三醇 在 air 、 phthalocyanine[Fe⁽³⁺⁾] 、 Montmorillonite K₁₀ 作用下， 以 甲醇 为溶剂， 反应 1.0h， 以357 mg的产率得到2-羟基-3-甲基-1,4-萘醌
  参考文献：
  名称：

  SUPPORTED METALATED PHTHALOCYANINE AS CATALYST FOR OXIDATION BY MOLECULAR OXYGEN. SYNTHESIS OF QUINONES AND CARBONYL COMPOUNDS

  摘要：

  Supported metalated phthalocyanine on K10 or on lamellar zirconium phosphate catalyses the oxidation of hydroquinones (and phenols) into quinones. Some interesting natural napthoquinones were also prepared (Juglone, Menadione, Lawsone, Phthiocol). Supported metalated phthalocyanine was also used in re-oxidation by oxygen of palladium and ruthenium, in the Wacker oxidation of olefins into ketones, in the oxidation of cyclohexadiene and in oxidation of benzylic alcohols in aldehydes.

  DOI：

  10.1081/scc-120004139
• 作为产物：
  描述：

  1,2,4-triacetoxy-3-methylnaphthalene 在 sodium methylate 作用下， 以 甲醇 为溶剂， 生成 3-甲基萘-1,2,4-三醇
  参考文献：
  名称：

  SUPPORTED METALATED PHTHALOCYANINE AS CATALYST FOR OXIDATION BY MOLECULAR OXYGEN. SYNTHESIS OF QUINONES AND CARBONYL COMPOUNDS

  摘要：

  Supported metalated phthalocyanine on K10 or on lamellar zirconium phosphate catalyses the oxidation of hydroquinones (and phenols) into quinones. Some interesting natural napthoquinones were also prepared (Juglone, Menadione, Lawsone, Phthiocol). Supported metalated phthalocyanine was also used in re-oxidation by oxygen of palladium and ruthenium, in the Wacker oxidation of olefins into ketones, in the oxidation of cyclohexadiene and in oxidation of benzylic alcohols in aldehydes.

  DOI：

  10.1081/scc-120004139

文献信息

• Condensation of Allylic Alcohols with Hydroxyhydroquinones
  作者：Louis F. Fieser、Marshall D. Gates

  DOI：10.1021/ja01856a025

  日期：1941.11
• Carrara; Bonacci, Gazzetta Chimica Italiana, 1943, vol. 73, p. 225,234
  作者：Carrara、Bonacci

  DOI：——

  日期：——
• US4701354A
  申请人：——

  公开号：US4701354A

  公开（公告）日：1987-10-20
• US4916031A
  申请人：——

  公开号：US4916031A

  公开（公告）日：1990-04-10
• SUPPORTED METALATED PHTHALOCYANINE AS CATALYST FOR OXIDATION BY MOLECULAR OXYGEN. SYNTHESIS OF QUINONES AND CARBONYL COMPOUNDS
  作者：Didier Villemin、Mohamed Hammadi、Messaoud Hachemi

  DOI：10.1081/scc-120004139

  日期：2002.1

  Supported metalated phthalocyanine on K10 or on lamellar zirconium phosphate catalyses the oxidation of hydroquinones (and phenols) into quinones. Some interesting natural napthoquinones were also prepared (Juglone, Menadione, Lawsone, Phthiocol). Supported metalated phthalocyanine was also used in re-oxidation by oxygen of palladium and ruthenium, in the Wacker oxidation of olefins into ketones, in the oxidation of cyclohexadiene and in oxidation of benzylic alcohols in aldehydes.