N,N,N',N'-tetra-(1-naphthyl)-2,7-diamino-9,9-dimethylfluorene | 248584-66-9

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: N,N,N',N'-tetra-(1-naphthyl)-2,7-diamino-9,9-dimethylfluorene
• 英文别名: 9,9-dimethyl-2-N,2-N,7-N,7-N-tetranaphthalen-1-ylfluorene-2,7-diamine
• CAS: 248584-66-9
• 化学式: C₅₅H₄₀N₂
• 分子量: 728.936
• InChiKey: HVKFWXWMBUOHOT-UHFFFAOYSA-N

物化性质

• 熔点：
  331.0-332.7 °C(Solv: hexane (110-54-3); toluene (108-88-3))
• 密度：
  1.244±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  15.9
• 重原子数：
  57
• 可旋转键数：
  6
• 环数：
  11.0
• sp3杂化的碳原子比例：
  0.05
• 拓扑面积：
  6.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  9,9-dimethyl-9H-fluorene-2,7-diamine 、 1-碘萘 、 1-甲基-4-正己基苯 、 邻二氯苯 在 铜 、 potassium carbonate 作用下， 以 丙酮 为溶剂， 以84.1%的产率得到N,N,N',N'-tetra-(1-naphthyl)-2,7-diamino-9,9-dimethylfluorene
  参考文献：
  名称：

  Triarylamine compound and luminescent device

  摘要：

  公开号：

  EP0953624B1

文献信息

• AMINE COMPOUND HAVING FLUORENE GROUP AS FRAMEWORK, PROCESS FOR PRODUCING THE AMINE COMPOUND, AND USE OF THE AMINE COMPOUND
  申请人：TOSOH CORPORATION

  公开号：EP1752440A1

  公开（公告）日：2007-02-14

  Novel amine compounds that can be utilized as hole transport materials, hole injection materials or the like of organic electroluminescence devices, electrophotographic receptors or the like, and their production processes are provided. The novel amine compound is represented by the following general formula (1). In the formula, R1 and R2 each independently represents hydrogen atom, a linear, branched or cyclic alkyl group or alkoxy group, an aryl group, an aryloxy group or a halogen atom; Ar1 and Ar2 each independently represents a substituted or unsubstituted aryl group or heteroaryl group, and may form a nitrogen-containing heterocyclic ring together with the nitrogen atom bonded thereto; and Ar3 each independently represents a substituted or unsubstituted phenyl group, naphthyl group, biphenylyl group, terphenylyl group, anthryl group, fluorenyl group or pyridyl group (except for amino-substituted groups); and M represents a single bond, an arylene group or a heteroarylene group.

  本发明提供了可用作有机电致发光器件、电致发光受体或类似器件的空穴传输材料、空穴注入材料或类似材料的新型胺化合物及其生产工艺。 新型胺化合物由以下通式（1）表示。 式中，R1 和 R2 各自独立地代表氢原子、直链、支链或环状烷基或烷氧基、芳基、芳氧基或卤原子；Ar1 和 Ar2 各自独立地代表取代或未取代的芳基或杂芳基，并可与其键合的氮原子一起形成含氮杂环；和 Ar3 各自独立地代表取代或未取代的苯基、萘基、联苯基、三苯基、蒽基、芴基或吡啶基（氨基取代的基团除外）；以及 M 代表单键、芳烯基或杂芳烯基。
• 新規なトリアリ―ルアミン化合物及び該化合物を用いた発光素子
  申请人：キヤノン株式会社

  公开号：JP2000016973A

  公开（公告）日：2000-01-18

  (57)【要約】\n【課題】 有機発光素子については、現状では更なる高輝度の光出力や長時間の使用による経時変化や酸素を含む雰囲気気体や湿気などによる劣化等の耐久性の面に未だ課題がある。\n【解決手段】 有機化合物層を下記一般式［１］\n【外１】\n（式中、Ｒ1 、Ｒ2 はそれぞれ独立に水素原子、ハロゲン原子、置換もしくは未置換のアルキル基、アルコキシ基、アリール基のいずれかを表わし、Ａｒ1 、Ａｒ2 、Ａｒ3 、Ａｒ4 はそれぞれ同一であっても異なってもよい、置換もしくは未置換のアリール基またはヘテロ環基を表わす。但し、Ａｒ1 、Ａｒ2 、Ａｒ3、Ａｒ4 の少なくとも一つ以上は縮合芳香環である。）で示される化合物を用いて構成した発光素子。\n

  (57) [摘要] Јn[问题] 关于有机发光器件，目前在耐用性方面仍存在问题，例如进一步的高亮度光输出、因长期使用而随时间变化以及因包括氧气和湿气在内的大气气体而降解。\有机化合物层是通过一种方法形成的，其中有机化合物层由以下通式[1]Јn形成（式中，R1和R2各自独立地代表氢原子、卤素原子、取代或未取代的烷基、烷氧基或芳基，Ar1、Ar2、Ar3和Ar4各自可以相同或不同）。Ar1、Ar2、Ar3 和 Ar4 各代表一个取代或未取代的芳基或杂环基团，它们可以相同或不同。不过，Ar1、Ar2、Ar3 和 Ar4 中至少有一个或多个是融合芳环（fused aromatic ring)。一种发光器件，包含如图所示的化合物\n
• Luminescent device with a triarylamine compound
  申请人：CANON KABUSHIKI KAISHA

  公开号：US20030207153A1

  公开（公告）日：2003-11-06

  A luminescent device having a pair of electrodes and a luminescent layer disposed between the electrodes. The luminescent layer comprises a compound represented by the following general formula: 1

  一种发光装置，具有一对电极和置于电极之间的发光层。发光层包括由以下通式表示的化合物： 1
• Amine Compound Having Fluorene Group as Framework, Process for Producing the Amine Compound, and Use of the Amine Compound
  申请人：Nishiyama Masakazu

  公开号：US20080194878A1

  公开（公告）日：2008-08-14

  Novel amine compounds that can be utilized as hole transport materials, hole injection materials or the like of organic electroluminescence devices, electrophotographic receptors or the like, and their production processes are provided. The novel amine compound is represented by the following general formula (1). In the formula, R 1 and R 2 each independently represents hydrogen atom, a linear, branched or cyclic alkyl group or alkoxy group, an aryl group, an aryloxy group or a halogen atom; Ar 1 and Ar 2 each independently represents a substituted or unsubstituted aryl group or heteroaryl group, and may form a nitrogen-containing heterocyclic ring together with the nitrogen atom bonded thereto; and Ar 3 each independently represents a substituted or unsubstituted phenyl group, naphthyl group, biphenylyl group, terphenylyl group, anthryl group, fluorenyl group or pyridyl group (except for amino-substituted groups); and M represents a single bond, an arylene group or a heteroarylene group.
• ORGANIC ELECTROLUMINESCENCE DEVICE
  申请人：IDEMITSU KOSAN CO., LTD.

  公开号：US20140061602A1

  公开（公告）日：2014-03-06

  An organic electroluminescence device contains an anode and a cathode facing each other, and intervening therebetween at least two hole transporting layers and a light emitting layer sequentially, and one of the hole transporting layers contains a compound having a particular structure having a fluorene structure at the center thereof, and is not adjacent to the light emitting layer. The organic electroluminescence device has a hole transporting layer having an increased thickness, is capable of being controlled in the thickness of the optical film, and has an enhanced device capability.