6,8-二溴靛红酸酐 | 54754-60-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并恶嗪类
• 中文名称: 6,8-二溴靛红酸酐
• 英文名称: 6,8-dibromo-1H-benzo[d][1,3]oxazine-2,4-dione
• 英文别名: 6,8-dibromo-1H-3,1-benzoxazine-2,4-dione
• CAS: 54754-60-8
• 化学式: C₈H₃Br₂NO₃
• mdl: MFCD00519398
• 分子量: 320.925
• InChiKey: ISBVTKNCSLRDBE-UHFFFAOYSA-N

物化性质

• 熔点：
  263.5 °C
• 密度：
  2.158±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.4
• 重原子数：
  14
• 可旋转键数：
  0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  55.4
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  6,8-二溴靛红酸酐 在 三乙胺 作用下， 以 水 为溶剂， 反应 1.0h， 生成 6,8-Dibrom-chinazolin-4-on-3-yl-essigsaeure
  参考文献：
  名称：

  Chinazolincarbonsäuren。七。米特隆。Ein einfacher Zugang zu（4-Oxo-3,4-dihydrochinazolin-3-yl）-alkansäuren，（4-Oxo-3,4-dihydro-1,2,3-benzotriazin-3-yl）-alkansäurenund deren Estern †

  摘要：

  喹唑啉羧酸。轻松合成（4-Oxo-3,4-dihydroquinazolin-3-yl）-链烷酸，（4-Oxo-3,4-dihydro-1,2,3-3-苯并三嗪-3-基）-链烷酸和他们的酯

  DOI：

  10.1002/hlca.19850680410
• 作为产物：
  描述：

  溴靛蓝 在 chromium(VI) oxide 、 溶剂黄146 作用下， 生成 6,8-二溴靛红酸酐
  参考文献：
  名称：

  6,8-DICHLOROBENZOYLENE UREA, AND THE INTERACTION OF 5,7-DIHALOGEN ISATOIC ANHYDRIDES WITH AMMONIA.—A NEW REAGENT FOR SODIUM

  摘要：

  DOI：

  10.1021/jo01222a004

文献信息

• 一种环丙虫酰胺化合物及其制备方法和应用
  申请人：河北艾林国际贸易有限公司

  公开号：CN106317016A

  公开（公告）日：2017-01-11

  本发明为一种环丙虫酰胺化合物及其制备方法和应用，涉及农药领域，本发明的环丙虫酰胺化合物为一种新的化合物，作用于昆虫的鱼尼汀受体，且既能够杀虫又能够杀菌，活性高，用量少，因此能够在制备作用于鱼尼汀受体杀虫剂中使用，也可以用于制备杀菌剂，本发明的环丙虫酰胺化合物的结构式为：
• [EN] PROCESS FOR PREPARING N-SUBSTITUTED 1H-PYRAZOLE-5-CARBONYLCHLORIDE COMPOUNDS<br/>[FR] PROCÉDÉ DE PRÉPARATION DE COMPOSÉS 1H-PYRAZOLE-5-CARBONYLCHORURES N-SUBSTITUÉS
  申请人：BASF SE

  公开号：WO2013024007A1

  公开（公告）日：2013-02-21

  The present invention relates to a process for preparing an N-substi- tuted 1 H-pyrazole-5-carbonylchloride compound of the formula (I) comprising the steps of i) deprotonating a compound of the formula (II) with a base selected from lithium-organic base having a carbon or nitrogen bound lithium or with a magnesium-organic base having a carbon bound magnesium; and ii) subjecting the product obtained in step (i) to a chlorocarbonylation by reacting it with a reagent selected from the group consisting of phosgene or a phosgene equivalent, to obtain a compound of formula (I).

  本发明涉及一种制备式(I)N-取代1H-吡唑-5-羰基氯化物的过程，包括以下步骤：i) 用选择自碳或氮与锂结合的有机锂碱或碳与镁结合的有机镁碱的碱去质子化式(II)化合物；和ii) 将步骤(i)中获得的产物经氯羰基化反应，与磷酰氯或磷酰氯等效物中选择的试剂反应，以获得式(I)化合物。
• [EN] ANILINE TYPE COMPOUNDS<br/>[FR] COMPOSÉS DE TYPE ANILINES
  申请人：BASF SE

  公开号：WO2013024008A1

  公开（公告）日：2013-02-21

  The present invention relates to compounds of the formula (I) wherein R1 and R2 independently of one another are hydrogen, C1-C10-alkyl, C1-C10-haloalkyl, C3-C10-cycloalkyl, C3-C10-halocycloalkyl, C2-C10-alkenyl, C2-C10-haloalkenyl or together represent an aliphatic chain, or the like; R3 is halogen, cyano, C1-C8-alkyl, C1-C8- haloalkyl, C3-C8-cycloalkyl, C3-C8-halocycloalkyl, C2-C8-alkenyl, C2-C8-haloalkenyl, C1-C8-alkoxy, phenyl, or the like; R4 is hydrogen, C1-C10-alkyl, C1-C10-haloalkyl, C3-C8- cycloalkyl, C3-C8-halocycloalkyl, C2-C10-alkenyl, C2-C10-haloalkenyl, phenyl, or the like; t is 0 or 1; p is 0, 1, 2, 3 or 4. The present invention also relates to a process for preparing a compound of the formula (I) which comprises reacting a compound of the formula (II) with a compound of the formulae (III) or (IV): where t, p, R1 R3, R3 and R4 are as defined in any of claims 1 to 6 and where A- is an equivalent of an anion having a pΚB of at least 10 (determined under standard conditions in water).

  本发明涉及以下式(I)的化合物，其中R1和R2彼此独立地为氢、C1-C10-烷基、C1-C10-卤代烷基、C3-C10-环烷基、C3-C10-卤代环烷基、C2-C10-烯基、C2-C10-卤代烯基或者一起代表一个脂肪链等；R3为卤素、氰基、C1-C8-烷基、C1-C8-卤代烷基、C3-C8-环烷基、C3-C8-卤代环烷基、C2-C8-烯基、C2-C8-卤代烯基、C1-C8-烷氧基、苯基等；R4为氢、C1-C10-烷基、C1-C10-卤代烷基、C3-C8-环烷基、C3-C8-卤代环烷基、C2-C10-烯基、C2-C10-卤代烯基、苯基等；t为0或1；p为0、1、2、3或4。本发明还涉及一种制备上述式(I)化合物的方法，包括将式(II)的化合物与式(III)或(IV)的化合物反应：其中t、p、R1、R3、R3和R4如权利要求1至6中的任一所定义，A-是至少在水中标准条件下具有至少10的pΚB值的阴离子的当量。
• [EN] N-THIO-ANTHRANILAMIDE COMPOUNDS AND THEIR USE AS PESTICIDES<br/>[FR] COMPOSÉS N-THIO-ANTHRANILAMIDES ET LEUR UTILISATION COMME PESTICIDES
  申请人：BASF SE

  公开号：WO2013024009A1

  公开（公告）日：2013-02-21

  The present invention relates to N-thio-anthranilamide compounds of the formula (I), the stereoisomers, the salts, the tautomers and the N-oxides thereof, wherein R1 is halogen or halomethyl; R2 is hydrogen, halogen or cyano; R3 is hydrogen, C1-C4 alkyl, C1-C4 haloalkyl, C2-C6-alkenyl or the like; R4 is halogen; R5 and R6 independently of each other are optionally substituted C1-C6-alkyl, C3-C6-cycloalkyl, C2-C6-alkenyl, C2-C6-alkynyl, phenyl, or together represent an (hetero)aliphatic chain, or the like; k is 0 or 1. The present invention further relates to a method for combating or controlling invertebrate pests, to a method for protecting plant propagation material and/or the plants which grow therefrom, to plant propagation material comprising at least one compound according to the present invention, to a method for treating or protecting an animal from infestation or infection by parasites, to a process for the preparation of a composition for treating infested or infected animals and/or for protecting animals against infestation or infection by parasites, and to a compound according to the invention for use as a medicament.

  本发明涉及公式（I）的N-硫代苯甲酰胺化合物，其立体异构体，盐，互变异构体和N-氧化物，其中R1是卤素或卤代甲基；R2是氢，卤素或氰基；R3是氢，C1-C4烷基，C1-C4卤代烷基，C2-C6-烯基或类似物；R4是卤素；R5和R6彼此独立地是可选择取代的C1-C6烷基，C3-C6环烷基，C2-C6烯基，C2-C6炔基，苯基，或者一起代表一个（杂）脂肪链，或类似物；k为0或1。本发明还涉及用于对抗或控制无脊椎动物害虫的方法，用于保护植物繁殖材料和/或由此生长的植物的方法，包括至少一种根据本发明的化合物的植物繁殖材料，用于治疗或保护动物免受寄生虫侵扰或感染的方法，用于制备用于治疗受感染动物和/或保护动物免受寄生虫侵扰或感染的组合物的方法，以及用于作为药物的本发明的化合物。
• [EN] ANTHRANILAMIDE COMPOUNDS AND THEIR USE AS PESTICIDES<br/>[FR] COMPOSÉS D'ANTHRANILAMIDE ET LEUR UTILISATION COMME PESTICIDES
  申请人：BASF SE

  公开号：WO2014128136A1

  公开（公告）日：2014-08-28

  The present invention relates to anthranilamide compounds of the formula (I),the stereoisomers, the salts, the tautomers and the N-oxides thereof, (I) wherein R1a, R1b,R1c,R1d are independently selected from the group consisting of hydrogen, halogen, C1-C8-alkyl, C1-C8-haloalkyl and the like; R2 is hydrogen, C1-C6-alkyl or the like; R3 is CHF2, OCH3, OCH2F or the like; R4 is hydrogen, halogen or C1-C4-haloalkyl; R5 is hydrogen, C1-C6 alkyl or the like; L is -CH2- or the like; Y is R7, OR7 or NR7R8; R6 is hydrogen, C1-C6-alkyl or the like; and R7, R8 are hydrogen, C1-C6-alkyl or the like. The present invention further relates to a method for combating or controlling invertebrate pests, to a method for protecting plant propagation material and/or the plants which grow therefrom, to plant propagation material comprising at least one compound according to the present invention, to a method for treating or protecting an animal from infestation or infection by parasites, to a process for the preparation of a composition for treating infested or infected animals and/or for protecting animals against infestation or infection by parasites, and to a compound according to the invention for use as a medicament.

  本发明涉及公式（I）的蒽酰胺化合物，其立体异构体，盐，互变异构体和N-氧化物，其中R1a，R1b，R1c，R1d分别选自氢，卤素，C1-C8-烷基，C1-C8-卤代烷基等的组成的群；R2为氢，C1-C6-烷基或类似物；R3为CHF2，OCH3，OCH2F或类似物；R4为氢，卤素或C1-C4-卤代烷基；R5为氢，C1-C6烷基或类似物；L为-CH2-或类似物；Y为R7，OR7或NR7R8；R6为氢，C1-C6-烷基或类似物；R7，R8为氢，C1-C6-烷基或类似物。本发明还涉及一种用于 bekämpfung 或控制无脊椎动物害虫的方法，一种用于保护植物繁殖材料和/或生长的植物的方法，包括至少一种根据本发明的化合物的植物繁殖材料，一种用于治疗或保护动物免受寄生虫侵害或感染的方法，一种用于制备用于治疗受感染动物和/或保护动物免受寄生虫侵害或感染的组合物的方法，以及一种根据本发明用作药物的化合物。