peroxydiphosphate | 15538-83-7

• 分子结构分类: 无机化合物 - 均质非金属化合物 - 非金属氧阴离子化合物
• 英文名称: peroxydiphosphate
• 英文别名: perdiphosphate；peroxodiphosphate(4-)；phosphonatooxy phosphate
• CAS: 15538-83-7
• 化学式: O₈P₂
• 分子量: 189.943
• InChiKey: NUGJFLYPGQISPX-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  -3.5
• 重原子数：
  10
• 可旋转键数：
  1
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  145
• 氢给体数：
  0
• 氢受体数：
  8

反应信息

• 作为反应物：
  描述：

  peroxydiphosphate 以 水 为溶剂， 生成 phosphate radical
  参考文献：
  名称：

  Subramanian, P; Rajaram, J; Ramarkrishnan, V, Indian Journal of Chemistry, Section A: Inorganic, Physical, Theoretical and Analytical, 1991, vol. 30, # 11, p. 913 - 919

  摘要：

  DOI：
• 作为产物：
  描述：

  磷酸肌酸 在 OH^(1-) 作用下， 以 not given 为溶剂， 生成 peroxydiphosphate
  参考文献：
  名称：

  Khomutov, N. E.; Khachaturyan, O. B.; Bakharev, V. E., Journal of applied chemistry of the USSR, 1988, vol. 61, p. 932 - 936

  摘要：

  DOI：

文献信息

• A Novel Reaction of HCrO₄⁻with PH₂O₂⁻, Induced by Molecular Oxygen, Forming Peroxodiphosphate Ions in an Aqueous Solution
  作者：Masaru Kimura、Aki Takahashi、Hiroko Kayanoki、Tomomi Sakata、Keiichi Tsukahara

  DOI：10.1246/bcsj.70.2699

  日期：1997.11

  The chromate (VI) ion HCrO4− at pH 2—4 was not appreciablly reduced by the phosphinate ion PH2O2− in the absence of molecular oxygen (O2), but was reduced in the presence of O2, forming peroxodiphosphate ions (denoted by PDP and meaning all forms of P2O84−, HP2O83− etc.) in much higher concentrations than those of the added chromate(VI). Both the rates of the chromate decay and the PDP formation increased with decreasing pH. When the chromate(VI) ion disappeared completely, PDP formation stopped and its concentration remained constant. However, such PDP once formed in the presence of O2 began to decompose after the solution was saturated with N2 gas; its decomposition ceased again when the solution was again saturated with air. Such behaviors are discussed while presenting the reaction mechanisms.

  在没有分子氧 (O2) 的情况下，pH 2-4 时的铬酸根 (VI) 离子 HCrO4− 不会被次膦酸根离子 PH2O2− 明显还原，但在 O2 存在的情况下会被还原，形成过氧二磷酸根离子（用 PDP 和 PDP 表示）指所有形式的 P2O84−、HP2O83− 等），其浓度比添加的铬酸盐 (VI) 的浓度高得多。铬酸盐腐烂和 PDP 形成的速率都随着 pH 值的降低而增加。当铬(VI)离子完全消失时，PDP形成停止并且其浓度保持恒定。然而，这种PDP一旦在O2存在下形成，在溶液被N2气体饱和后就开始分解；当溶液再次被空气饱和时，其分解再次停止。在介绍反应机制的同时讨论了此类行为。
• Formation of Peroxodiphosphate by the Copper(II)-Catalyzed Oxidation Reaction of the Phosphinate Ion by the Molecular Oxygen. Kinetics and Mechanisms in Aqueous Solutions
  作者：Masaru Kimura、Kyouko Seki、Hitomi Horie、Keiichi Tsukahara

  DOI：10.1246/bcsj.69.613

  日期：1996.3

  IrIV and CeIV were used in place of the copper(II) ion. Thus, this reaction is specific only for the copper(II) ion, which can be easily reduced to Cu+ by the phosphinate ion, where the reduced species are capable of reacting with molecular oxygen to efficiently produce the superoxide of O2−• or HO2•. After some PDP had been formed in the presence of air or oxygen, if the reacting solution was changed

  发现过二磷酸根离子（用 PDP 表示，意思是所有形式的 P2O84-、HP2O83-、H2P2O82- 等）是通过分子氧 (O2) 使用痕量的铜（II）离子在水溶液中作为催化剂。形成速率取决于酸度在 pH 3.5 左右达到最大值，并受到自由基清除剂或乙二胺四乙酸 (EDTA) 络合物形成物质的抑制。当使用 IrIV 和 CeIV 等离子代替铜 (II) 离子时，未观察到 PDP 的形成。因此，该反应仅针对铜 (II) 离子，铜 (II) 离子可以很容易地被次膦酸盐离子还原为 Cu+，其中被还原的物种能够与分子氧反应以有效地产生 O2−• 或 HO2• .
• Kinetics of oxidation of hexacyanoferrate(II) by peroxodiphosphate
  作者：P. Maruthamuthu、M. Santappa

  DOI：10.1016/s0020-1693(00)91688-8

  日期：1976.1

  Abstract Kinetic evidence for inner sphere oxidative path was observed in the oxidation of hexacyanoferrate(II) by peroxodiphosphate at pH = 10 and 26°C. The reaction obeys the rate law suggesting the mechanism Added free ligand, CN − , effects a remarkable decrease in the reaction rate in accordance with the rate law. Effect of pH on the reaction rate was studied and evidence for free radical intermediates

  摘要在pH = 10和26°C的条件下，过氧二磷酸过氧化六氰合铁酸盐（II）时，观察到了内球氧化途径的动力学证据。该反应遵循速率规律，表明机理：根据速率规律，添加的游离配体CN-会显着降低反应速率。研究了pH对反应速率的影响，并获得了自由基中间体的证据。
• Oxidation of<i>trans</i>-1,2-Cyclohexanediaminetetraacetatocobaltate(II) by Peroxodiphosphate Catalyzed by Ag(I) in Acetate Buffers. A Kinetic Study
  作者：Pathaneni Sivaswaroop、Kondapi Anandkumar、Panuganti V. K. Rao

  DOI：10.1246/bcsj.64.641

  日期：1991.2

  The kinetics of oxidation of trans-1,2-cyclohexanediaminetetraacetatocobaltate(II) by peroxodiphosphate (PDP) in acetate buffers was studied in the presence of Ag(I). For the first time, this study gives a clear evidence for the involvement of Ag(I)/Ag(II) cycle in the Ag(I)-catalyzed PDP oxidation reactions in acetate buffers. A plausible mechanism consistent with the observed kinetic features is proposed

  在 Ag(I) 存在下，研究了醋酸盐缓冲液中过氧二磷酸盐 (PDP) 氧化反式-1,2-环己二胺四乙酰钴酸盐 (II) 的动力学。该研究首次为 Ag(I)/Ag(II) 循环参与醋酸盐缓冲液中 Ag(I) 催化的 PDP 氧化反应提供了明确的证据。提出了一种与观察到的动力学特征一致的合理机制。
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: P: MVol.C, 130, page 300 - 302
  作者：

  DOI：——

  日期：——