2,4,6,8,9,10-六硫杂-1,3,5,7-四磷杂三环[3.3.1.1(3,7)]癸烷 1,3,5-三硫化物 | 25070-46-6

• 分子结构分类: 无机化合物 - 均质非金属化合物 - 均质其他非金属化合物
• 中文名称: 2,4,6,8,9,10-六硫杂-1,3,5,7-四磷杂三环[3.3.1.1(3,7)]癸烷 1,3,5-三硫化物
• 中文别名: 2,4,6,8,9,10-六硫杂-1,3,5,7-四磷杂三环[3.3.1.1(3,7)]癸烷1,3,5-三硫化物
• 英文名称: α-P4S9
• 英文别名: tetraphosphorus nonasulfide；1,3,5-tris(sulfanylidene)-2,4,6,8,9,10-hexathia-1λ5,3λ5,5λ5,7-tetraphosphatricyclo[3.3.1.13,7]decane
• CAS: 25070-46-6
• 化学式: P₄S₉
• 分子量: 412.489
• InChiKey: VFWRPFQSIRTMSW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.7
• 重原子数：
  13
• 可旋转键数：
  0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  248
• 氢给体数：
  0
• 氢受体数：
  9

反应信息

• 作为反应物：
  描述：

  2,4,6,8,9,10-六硫杂-1,3,5,7-四磷杂三环[3.3.1.1(3,7)]癸烷 1,3,5-三硫化物 在 三苯基膦 作用下， 以 二硫化碳 为溶剂， 生成 phosphorus sulfide
  参考文献：
  名称：

  N.m.r. evidence for the existence of P₄S₈

  摘要：

  近红外光谱证据表明，Ph3P 对 P4S9 的脱硫作用的主要产物是 P4S8，这是一种稳定性有限的新品种。

  DOI：

  10.1039/c39820000176
• 作为产物：
  描述：

  phosphorus sulfide 以 萘烷 为溶剂， 以0%的产率得到2,4,6,8,9,10-六硫杂-1,3,5,7-四磷杂三环[3.3.1.1(3,7)]癸烷 1,3,5-三硫化物
  参考文献：
  名称：

  Thamm, R.; Heckmann, G.; Fluck, E., Phosphorus and Sulfur and the Related Elements, 1981, vol. 12, p. 319 - 324

  摘要：

  DOI：

文献信息

• Ein neues Phosphorsulfid mit Adamantangerüst: δ-P4S7
  作者：Heike Nowottnick、Roger Blachnik

  DOI：10.1002/(sici)1521-3749(200003)626:3<611::aid-zaac611>3.0.co;2-o

  日期：2000.3

  A New Phosphorus Sulfide with Adamantane Structure: δ-P4S7 By sulfur abstraction from α-P4S9/P4S10 with triphenylphosphine a new phosphorus sulfide δ-P4S7 with adamantane skeleton and an additional sulfur in exo-position was identified in CS2-solution by 31P-NMR spectroscopy. Product distribution and 31P-NMR parameter are given.

  一种新的具有金刚烷结构的硫化磷：δ-P4S7 通过用三苯基膦从 α-P4S9/P4S10 中提取硫，通过 31P-NMR 在 CS2 溶液中鉴定出一种新的具有金刚烷骨架和外位硫的硫化磷 δ-P4S7光谱学。给出了产物分布和 31 P-NMR 参数。
• Reduction of cyanohydrins
  申请人：Ethyl Corporation

  公开号：US04952718A1

  公开（公告）日：1990-08-28

  Arylacetonitriles corresponding to the formula Ar-CH(R)CN are prepared by reducing a cyanohydrin corresponding to the formula Ar-C(R)(OH)CN with phosphorus pentasulfide in an inert solvent; Ar in the formulas representing aryl and R being hydrogen or alkyl. The products are primarily useful as pharmaceutical and agricultural intermediates.

  配方为Ar-CH（R）CN的芳基乙腈可通过在惰性溶剂中使用五硫化二磷还原配方为Ar-C（R）（OH）CN的腈醇制备而成。其中，Ar表示芳基，R表示氢或烷基。这些产物主要用作制药和农业中间体。
• Products and Mechanisms in the Oxidation of Phosphorus by Sulfur at Low Temperature
  作者：Mark E. Jason、Toan Ngo、Shahidur Rahman

  DOI：10.1021/ic9614879

  日期：1997.6.1

  The oxidation of phosphorus by sulfur at low temperatures (<100 degrees C) has been shown to produce complex mixtures that include 12 of the 17 known binary phosphorus sulfides. Two of these 17 sulfides have been observed in these mixtures for the first time, The rate-determining and first step in the reaction appears to be the formation of the Ss diradical, This proposal is supported by the observed rate at which the sulfides are formed and the distribution of the sulfide product stoichiometries. Photoinitiation of this oxidation at O degrees C produces a similar array of sulfides, The differences in the product distributions between the thermal and photochemical processes facilitate the understanding of the mother-daughter relationships between the products. The effects of oxidation by sulfur and reduction by phosphorus have been determined for several of the known phosphorus sulfides. The characterizations of phosphorus compounds in molten mixtures of phosphorus and sulfur were performed by P-31 NMR and Raman spectroscopy directly on the reaction mixtures.
• Blachnik, Roger; Peukert, Ulrike; Czediwoda, Anette, Zeitschrift fur Anorganische und Allgemeine Chemie
  作者：Blachnik, Roger、Peukert, Ulrike、Czediwoda, Anette、Engelen, B.、Boldt, K.

  DOI：——

  日期：——
• Barieux, Jean-Jacques; Demarcq, Michel C., Revue de Chimie Minerale, 1984, vol. 21, p. 611 - 626
  作者：Barieux, Jean-Jacques、Demarcq, Michel C.

  DOI：——

  日期：——