Thermal studies on the anation and decomposition of trans-fluoroaquobis(ethylenediamine) and trans-fluoroaquoabis(propylenediamine) dithionate
作者:J. Ribas、J. Casabó、M.D. Baro
DOI:10.1016/0040-6031(81)80106-2
日期:1981.9
Abstract The anation and decomposition reaction of trans [CrF(H 2 O)(aa′) 2 ]S 2 O 6 [aa′ = ethylenediamine (en); 1,3-diaminepropane (tmd)] have been studied by means of ATD, TG and DSC techniques. The first and only perfectly defined step is the anation reaction forming the species cis [CrF(S 2 O 6 )(aa′) 2 ]. By means of DSC techniques, the enthalpies of reaction and the activation energies of both