二吡嗪并[2,3-f:2',3'-h]喹喔啉 | 79790-37-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二氮杂萘
• 中文名称: 二吡嗪并[2,3-f:2',3'-h]喹喔啉
• 中文别名: 双吡嗪并[2,3-f：2′，3′-h]喹喔啉；二吡嗪[2,3-F:2,3-H]喹噁啉
• 英文名称: 1,4,5,8,9,,12-hexaazatriphenylene
• 英文别名: HAT；Dipyrazino[2,3-f:2',3'-h]quinoxaline；3,6,9,12,15,18-hexazatetracyclo[12.4.0.02,7.08,13]octadeca-1(18),2,4,6,8,10,12,14,16-nonaene
• CAS: 79790-37-7
• 化学式: C₁₂H₆N₆
• 分子量: 234.22
• InChiKey: QPJFIVIVOOQUKD-UHFFFAOYSA-N

物化性质

• 熔点：
  >179°C (dec.)
• 沸点：
  501.5±45.0 °C(Predicted)
• 密度：
  1.549±0.06 g/cm3(Predicted)
• 溶解度：
  可溶于氯仿（少许）

计算性质

• 辛醇/水分配系数(LogP)：
  -1.3
• 重原子数：
  18
• 可旋转键数：
  0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  77.3
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  二吡嗪并[2,3-f:2',3'-h]喹喔啉 以 硝基甲烷 、 乙腈 、 苯 为溶剂， 生成
  参考文献：
  名称：

  A Robust (10,3)-a Network Containing Chiral Micropores in the AgI Coordination Polymer of a Bridging Ligand that Provides Three Bidentate Metal-Binding Sites

  摘要：

  Framework integrity is retained when water molecules replace the nitromethane molecules in the coordination polymer [Ag(hat)ClO4 ]⋅2 CH3 NO2 (see picture for structure), which are arranged in a helical fashion within the chiral micropores of the three-dimensional [Ag(hat)+ ]n network with a (10,3)-a topology. Remarkably, this is also the case after subsequent displacement of the water by nitromethane molecules. hat=1,4,5,8,9,12-hexaazatriphenylene.

  DOI：

  10.1002/(sici)1521-3773(19981016)37:19<2656::aid-anie2656>3.0.co;2-m
• 作为产物：
  描述：

  二吡嗪[2,3-F:2',3'-H]喹啉-2,3,6,7,10,11-六羧酸 在 铜 作用下， 以 二苯醚 为溶剂， 反应 22.0h， 以21%的产率得到二吡嗪并[2,3-f:2',3'-h]喹喔啉
  参考文献：
  名称：

  使用表面反应合成单层二维金属-有机骨架 M3(HAT)2 (M=Ni, Fe, Co, HAT=1,4,5,8,9,12-hexaazatriphenylene)

  摘要：

  1,4,5,8,9,12-六氮杂苯并苯 (HAT) 基二维共轭金属有机骨架 M 3 (HAT) 2 (M=Fe, Ni, Co)表面自组装协议，有效克服了分子间的强空间位阻。

  DOI：

  10.1002/anie.202204528

文献信息

• Benzimidazole, Benzoxazole and Benzothiazole Derivatives, Optical Film Comprising them and Method of Producing thereof
  申请人：Nokel Alexey

  公开号：US20100279122A1

  公开（公告）日：2010-11-04

  The present invention is relates to the synthesis of predominantly planar heterocyclic organic compound and the manufacture of optical films based on these compounds. Said organic compound has the general structural formula where Het is a predominantly planar heterocyclic molecular system possessing hydrophilic properties; B is a binding group; p is the number in the range from 3 to 8; S is a group providing solubility of the organic compound; m is a number in the range from 0 to 8. Said organic compound is transparent for electromagnetic radiation in the visible spectral range from 400 to 700 nm, and a solution of the compound or a salt thereof is capable of forming a substantially transparent optical layer on a substrate, with the heterocyclic molecular planes oriented predominantly parallel to the substrate surface.

  本发明涉及主要呈平面状的杂环有机化合物的合成以及基于这些化合物的光学薄膜的制造。所述有机化合物具有通用结构公式，其中Het是一个主要呈平面状的具有亲水性质的杂环分子体系；B是一个结合基团；p是一个3到8之间的数；S是一个提供有机化合物溶解度的基团；m是一个0到8之间的数。所述有机化合物对可见光谱范围内400到700纳米的电磁辐射是透明的，并且该化合物或其盐的溶液能够在基底上形成基本透明的光学层，其中杂环分子平面主要平行于基底表面。
• NOVEL CHEMISTRY USED IN BIOSENSORS
  申请人：OHMX Corporation

  公开号：US20130112572A1

  公开（公告）日：2013-05-09

  The invention relates to novel compositions of 1,3-disubstituted ferrocenes useful for the modification of electrodes.

  这项发明涉及新型的1,3-二取代二茂铁组合物，可用于修饰电极。
• LUMINESCENT SILVER COMPLEXES
  申请人：Sumitomo Chemical Company, Limited

  公开号：EP2360162A1

  公开（公告）日：2011-08-24

  An luminescent device material which is inexpensive and exhibits excellent durability in the presence of oxygen can be provided using a luminescent silver complex which has an organic multidentate ligand, particularly, a luminescent silver complex wherein the organic multidentate ligand is coordinated to a phosphorus atom, a nitrogen atom, an oxygen atom, a sulfur atom, an arsenic atom, an oxygen anion, a nitrogen anion, or a sulfur anion, or a polymer of the luminescent silver complex.

  可以使用含有有机多齿配体的发光银配合物来提供一种在氧气存在的情况下具有极好耐久性且价格低廉的发光器件材料，特别是一种含有有机多齿配体的发光银配合物，其中有机多齿配体与磷原子、氮原子、氧原子、硫原子、砷原子、氧负离子、氮负离子或硫负离子配位，或者是该发光银配合物的聚合物。
• Multypodal tethers for high-density attachment of redox-active moieties to substrates
  申请人：Lindsey S. Jonathan

  公开号：US20070108438A1

  公开（公告）日：2007-05-17

  This invention provides redox-active molecules attached to polypodal (e.g., bipodal, tripodal, quadrapodal, pentapodal, etc.) tethers that can be used for attachment of the redox-active molecules to a substrate (e.g., an electrode). The tethered redox-active molecules are useful for the fabrication of memory devices.

  这项发明提供了与多脚（例如，双脚、三脚、四脚、五脚等）连接的氧化还原活性分子，可用于将这些氧化还原活性分子连接到基底（例如，电极）。连接的氧化还原活性分子可用于制作存储器件。
• ORGANIC COMPOUND, THREE-DIMENSIONAL ORGANIC FRAMEWORK FORMED BY USING ORGANIC COMPOUND, SEPARATION SIEVE AND OPTICAL LAYER, WHICH COMPRISE ORGANIC FRAMEWORK, AND OPTICAL DEVICE COMPRISING OPTICAL LAYER AS OPTICAL AMPLIFICATION LAYER
  申请人：INDUSTRY-UNIVERSITY COOPERATION FOUNDATION HANYANG UNIVERSITY

  公开号：US20190031586A1

  公开（公告）日：2019-01-31

  An organic compound, a three-dimensional organic structure formed by using the organic compound, a separation sieve and an optical layer having the organic structure, and an optical device having the optical layer as an optical amplification layer are provided. The organic structure includes a plurality of organic molecules self-assembled by non-covalent bonding. Each of the unit organic molecules has an aromatic ring, a first pair of substituents being connected to immediately adjacent positions of substitutable positions of the aromatic ring, and a second pair of substituents being connected to immediately adjacent positions of remaining substitutable positions of the aromatic ring. The unit organic molecules are self-assembled by van der Waals interaction, London dispersion interaction or hydrogen bonding between the first and the second pairs of the substituents and by pi-pi interactions between the aromatic rings.

  提供一种有机化合物，通过使用该有机化合物形成的三维有机结构、分离筛和具有该有机结构的光学层，以及具有光学层作为光学放大层的光学器件。该有机结构包括通过非共价键自组装的多个有机分子。每个单元有机分子具有芳香环，第一对取代基连接到芳香环的可取代位置的相邻位置，第二对取代基连接到芳香环的剩余可取代位置的相邻位置。单元有机分子通过范德华力相互作用、伦敦分散相互作用或氢键作用于第一和第二对取代基之间的π-π相互作用而自组装。