nitrous oxide | 20259-33-0

• 分子结构分类: 无机化合物 - 均质非金属化合物 - 其他非金属有机物
• 英文名称: nitrous oxide
• 英文别名: Nitrous oxide-15N2,18O
• CAS: 20259-33-0
• 化学式: N₂O
• 分子量: 48.0
• InChiKey: GQPLMRYTRLFLPF-UMGOXHPOSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.5
• 重原子数：
  3
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  19.1
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  nitrous oxide 在 catalyst: Rh/γ-Al2O3 作用下， 以 neat (no solvent, gas phase) 为溶剂， 生成 氮气-15N2 、 氧气
  参考文献：
  名称：

  研究由同位素气体和原位N个光谱（DRIFTS，XPS和Raman）2上的Rh /的CeOö分解机构2和Rh /γ-Al系2个ö 3催化剂

  摘要：

  所述N个2上的Rh /的CeOö分解机构2和Rh /γ-Al系2 ö 3催化剂进行了研究的同位素N个脉冲2 O和O 2连同原位DRIFT，XP和拉曼光谱。的Rh /铈的较高的催化活性2与的Rh /γ-Al系比较2 ö 3是有关的Rh-的CeO 2相互作用并且向CEO的参与2支撑在N 2 Ó分解机理，在γ-Al 2 O 3是惰性载体。铑在Rh /γ-Al系2 ö3在反应条件下被还原为Rh 0，而该催化剂上的N 2 O分解主要通过Eley–Rideal机理发生。相反，二氧化铈载体与铑在N 2 O分解过程中与部分稳定贵金属的阳离子物种强烈相互作用。在Rh / CeO 2中，还原的铑位点（通过N 2 O）可以随后被N 2 O或二氧化铈氧再氧化，然后在二氧化铈载体上产生的空位被N 2 O氧化。 N 2 O的化学吸附和分解不仅位于铑上，而且位于二氧化铈上。

  DOI：

  10.1016/j.jcat.2010.10.001
• 作为产物：
  描述：

  nitric oxide 在 [Fe₂(2,6-bis[((2-hydroxybenzyl)-(2-pyridylmethyl)amino)methyl]-4-methylphenolate)(propionate)₂]*(CoCp₂₎ 作用下， 以 二氯甲烷 为溶剂， 生成 nitrous oxide
  参考文献：
  名称：

  非血红素二铁模型复合物可以介导直接 NO 还原：对 Flavodiiron NO 还原酶的机理洞察

  摘要：

  Flavorodiiron 一氧化氮还原酶 (FNORs) 是一种常见的酶家族，存在于各种类型的病原菌中，能够将一氧化氮 (NO) 还原为一氧化二氮 (N2O)，作为一种保护性解毒机制。在病原菌中利用 FNORs 有助于它们在人体内存活和增殖，从而导致慢性感染。在本文中，我们提出了一种新的二铁模型复合物 [Fe2((Py2PhO2)MP)(OPr)2](OTf)，具有桥接丙酸配体 (OPr-)，能够直接将 NO 以定量产率还原为 N2O，而无需需要（超级）减少复杂性。我们首先制备了二铁前体，并通过紫外-可见光、红外、核磁共振和穆斯堡尔光谱、循环伏安法和质谱法对其进行了表征。然后可以使用 CoCp2 方便地将该复合物还原为二铁复合物。尽管这种二铁复合物具有很高的反应性，但我们已经使用 X 射线晶体学和各种光谱技术成功地分离和表征了该物种。最重要的是，在这种二铁复合物与 NO 气体反应后，我们通过红外气体顶空分析观察到

  DOI：

  10.1021/jacs.8b08567

文献信息

• Over or under: hydride attack at the metal versus the coordinated nitrosyl ligand in ferric nitrosyl porphyrins
  作者：E. G. Abucayon、R. L. Khade、D. R. Powell、M. J. Shaw、Y. Zhang、G. B. Richter-Addo

  DOI：10.1039/c6dt03860c

  日期：——

  Hydride attack at a ferric heme-NO to give an Fe–HNO intermediate is a key step in the global N-cycle. We demonstrate differential reactivity when six- and five-coordinate ferric heme-NO models react with hydride. Although Fe–HNO formation is thermodynamically favored from this reaction, Fe–H formation is kinetically favored for the 5C case.

  在铁血红素-NO上发生氢化物攻击以生成Fe-HNO中间体是全球N循环的关键步骤。当六坐标和五坐标的铁血红素NO模型与氢化物反应时，我们证明了不同的反应性。尽管此反应在热力学上有利于Fe–HNO的形成，但对于5C情况，Fe–HNO的形成在动力学上是有利的。
• Role of active oxygen and NOx species in N2O decomposition over Fe-ferrierite
  作者：Zdeněk Sobalík、Edyta Tabor、Jana Nováková、Naveen K. Sathu、Karel Závěta

  DOI：10.1016/j.jcat.2012.02.007

  日期：2012.5

  Fe(III)–O species were formed; these species are known to be highly active in oxidations at low temperatures. A transformation of Fe(III)–O into Fe–NOx species occurred when the reaction temperature was increased or when the reaction time was increased at low temperatures. This resulted in the disappearance of the oxidation activity of iron ferrierite. In contrast, the formation of Fe–NOx species enhanced

  通过结合程序升温对吸附的表面物种进行解吸以及红外光谱和莫斯鲍尔分光光度法的结合，发现了铁镁碱沸石在N 2 O分解过程中在表面形成的Fe–NO x物种的直接证据。表面NO X物种被暴露铁镁碱沸石（硅/铝= 8.7，铁/铝= 0.07-0.1）至N经由瞬时形成的所述Fe（III）-O的转化产生的2 O.铁的转化（III） Fe-NO x中的–O取决于时间和温度。低于280°C，主要形成Fe（III）–O物种。已知这些物质在低温下具有很高的氧化活性。Fe（III）-O转变为Fe-NO x当升高反应温度或在低温下增加反应时间时，会发生各种杂质。这导致镁碱铁矿的氧化活性消失。与此相反，Fe基NO的形成X物种增强n的速率2 Ó分解。一旦形成，NO x物质在随后的N 2 O分解过程中是稳定的。
• Synchrotron XPS and desorption study of the NO chemistry on a stepped Pt surface
  作者：C.J. Weststrate、J.W. Bakker、E.D.L. Rienks、C.P. Vinod、S. Lizzit、L. Petaccia、A. Baraldi、B.E. Nieuwenhuys

  DOI：10.1016/j.susc.2006.02.035

  日期：2006.5

  The interaction of NO with Pt(410) was studied using high-energy resolution fast XPS and temperature programmed desorption/reaction mass spectroscopy. LEED studies show that the surface in the clean state restructures, which results in the formation of some larger 100} terraces. STM measurements show, that most terraces are small, similar to 1 nm. Two different binding energy (BE) components were observed in the N Is region of the core level spectra, both assigned to molecular forms of NO. NO dissociation starts between 350 and 400 K. This is a significantly higher temperature than previous literature reports suggested. This difference is thought to be caused by the restructuring of the surface used in our experiments. The reaction of NO with H-2, NH3 and CO was also studied. The onset of these NO reduction reactions is determined by the NOad dissociation temperature (between 350 and 400 K) and NOad dissociation is the rate limiting step for all the reactions that were studied. Reaction with H2 yields NH3 below 600 K, but the selectivity shifts towards N-2 at higher temperatures. We did not find any indication that reaction between NOad and NH3 ad proceeds via a special NONH3 intermediate. A new surface species was detected during the reaction between NO and CO, both in the N 1s and the C 1s spectrum. It is tentatively assigned to either CN or CNO. The reactivity of NO on Pt(4 10) is compared with the reactivity that was observed for Pt(100) and other noble metal surfaces, such as I'd and Rh. (c) 2006 Elsevier B.V. All rights reserved.
• Infrared spectra of (NO)2+, (NO)2−, and (NO)3− trapped in solid neon
  作者：Catherine L. Lugez、Warren E. Thompson、Marilyn E. Jacox、Anders Snis、Itai Panas

  DOI：10.1063/1.478967

  日期：1999.6

  New studies of the infrared spectra of the products which result on codeposition at approximately 5 K of a Ne:NO sample with Ne atoms that have been excited in a microwave discharge have led to new and revised assignments for several ionic species. The appearance of the ν1 absorption of ONNO+ for several new species with asymmetric isotopic substitution, but for no symmetrically substituted species, confirms the trans ground-state configuration for ONNO+. The behavior of a neon-matrix product absorption at 1227.5 cm−1 parallels that of an argon-matrix absorption at 1221.0 cm−1 which has recently been assigned to trans-ONNO−. The identity of the carrier of a product absorption at 1424.1 cm−1, contributed by a vibration of two symmetrically equivalent NO groups, has not been definitively established. This absorption exhibits complex photodestruction behavior. Three absorptions are assigned to cis,cis-(NO)3−, which has C2v symmetry, with the aid of density functional calculations of the isotopic substitution pattern for the vibrational fundamentals of this species. Similar calculations of the isotopic substitution patterns for other structures result in poor agreement with the experiments. Photodestruction of cis,cis-(NO)3− trapped in solid neon yields the N2O⋯NO2− complex.
• Non-Heme Diiron Model Complexes Can Mediate Direct NO Reduction: Mechanistic Insight into Flavodiiron NO Reductases
  作者：Hai T. Dong、Corey J. White、Bo Zhang、Carsten Krebs、Nicolai Lehnert

  DOI：10.1021/jacs.8b08567

  日期：2018.10.17

  present a new diiron model complex, [Fe2((Py2PhO2)MP)(OPr)2](OTf), with bridging propionate ligands (OPr-) that is capable of directly reducing NO to N2O in quantitative yield without the need to (super)reduce the complex. We first prepared the diferric precursor and characterized it by UV-vis, IR, NMR and Mössbauer spectroscopies, cyclic voltammetry, and mass spectrometry. This complex can then conveniently

  Flavorodiiron 一氧化氮还原酶 (FNORs) 是一种常见的酶家族，存在于各种类型的病原菌中，能够将一氧化氮 (NO) 还原为一氧化二氮 (N2O)，作为一种保护性解毒机制。在病原菌中利用 FNORs 有助于它们在人体内存活和增殖，从而导致慢性感染。在本文中，我们提出了一种新的二铁模型复合物 [Fe2((Py2PhO2)MP)(OPr)2](OTf)，具有桥接丙酸配体 (OPr-)，能够直接将 NO 以定量产率还原为 N2O，而无需需要（超级）减少复杂性。我们首先制备了二铁前体，并通过紫外-可见光、红外、核磁共振和穆斯堡尔光谱、循环伏安法和质谱法对其进行了表征。然后可以使用 CoCp2 方便地将该复合物还原为二铁复合物。尽管这种二铁复合物具有很高的反应性，但我们已经使用 X 射线晶体学和各种光谱技术成功地分离和表征了该物种。最重要的是，在这种二铁复合物与 NO 气体反应后，我们通过红外气体顶空分析观察到