1,3,3a,4,7,7a-hexahydro-4,7-methano-benzo[c]thiophene | 916139-00-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 硫杂环戊烷
• 英文名称: 1,3,3a,4,7,7a-hexahydro-4,7-methano-benzo[c]thiophene
• 英文别名: 4,7-Methanobenzo[c]thiophene, 1,3,3a,4,7,7a-hexahydro-；4-thiatricyclo[5.2.1.02,6]dec-8-ene
• CAS: 916139-00-9
• 化学式: C₉H₁₂S
• 分子量: 152.26
• InChiKey: FKWKBPUUCQAMPI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.2
• 重原子数：
  10
• 可旋转键数：
  0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.78
• 拓扑面积：
  25.3
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  1,3,3a,4,7,7a-hexahydro-4,7-methano-benzo[c]thiophene 在 N-氯代丁二酰亚胺 、 oxone 作用下， 以 甲醇 、 水 为溶剂， 生成 ((E)-3-Hept-1-enyl)-4-thia-tricyclo[5.2.1.0^2,6]dec-8-ene 4,4-dioxide
  参考文献：
  名称：

  A novel stereoselective synthesis of 1,3,5-trienes via so2 extrusion from sulfolenes.

  摘要：

  DOI：

  10.1016/s0040-4039(00)94876-7
• 作为产物：
  描述：

  5,6-Bis(methylsulfonyloxymethyl)bicyclo[2.2.1]hept-2-ene 、 硫化碱 以85%的产率得到
  参考文献：
  名称：

  BLOCH, R.;ABECASSIS, J., TETRAHEDRON LETT., 1982, 23, N 32, 3277-3280

  摘要：

  DOI：

文献信息

• BLOCH, R.;ABECASSIS, J.;HASSAN, D., J. ORG. CHEM., 1985, 50, N 9, 1544-1545
  作者：BLOCH, R.、ABECASSIS, J.、HASSAN, D.

  DOI：——

  日期：——
• Ether-containing cyclic structure-containing polymer, polymer composition for optical material, and molded article thereof, optical component and lens
  申请人：Sakurai Seiya

  公开号：US20110077372A1

  公开（公告）日：2011-03-31

  Disclosed is an ether-containing cyclic structure-containing polymer derived from a monomer represented by formula (1) below, or derived from a monomer represented by formula (1) below and a single or more species of cyclic olefinic monomer(s), having a refractive index of equal to or larger than 1.53 and an Abbe number of equal to or larger than 56. Each of R 11 to R 14 independently represents a hydrogen atom or a substituent, or R 11 to R 14 may bond with each other to form a cyclic structure; each of X and Y independently represents a substituted or non-substituted, carbon atom, oxygen atom, or sulfur atom; and m represents 0 or 1.
• POLYMER, METHOD FOR PRODUCING POLYMER, RESIN COMPOSITION FOR OPTICAL MATERIAL, SHAPED ARTICLE, OPTICAL MATERIAL, AND LENS
  申请人：OKUTSU Rie

  公开号：US20120046420A1

  公开（公告）日：2012-02-23

  A polymer containing a recurring unit having an aliphatic polycyclic structure, wherein at least two atoms constituting the ring skeleton of the aliphatic polycyclic structure constitute the main chain of the polymer, and the recurring unit has an aliphatic ring containing a sulfonyl group as the constitutive group of the ring skeleton, has high refractivity, high Abbe's number, high-level heat resistance, high-level light transmittance and low water absorption.
• US9090729B2
  申请人：——

  公开号：US9090729B2

  公开（公告）日：2015-07-28
• A novel stereoselective synthesis of 1,3,5-trienes via so2 extrusion from sulfolenes.
  作者：R. Bloch、C. Benecou、E. Guibé-Jampel

  DOI：10.1016/s0040-4039(00)94876-7

  日期：1985.1