1,4-di(N,N-di-n-butyl-acetamido)-quinoxaline-2,3-dione | 958640-84-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二氮杂萘
• 英文名称: 1,4-di(N,N-di-n-butyl-acetamido)-quinoxaline-2,3-dione
• 英文别名: N,N-dibutyl-2-[4-[2-(dibutylamino)-2-oxoethyl]-2,3-dioxoquinoxalin-1-yl]acetamide
• CAS: 958640-84-1
• 化学式: C₂₈H₄₄N₄O₄
• 分子量: 500.682
• InChiKey: MBZMQTRDFOHIEU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.9
• 重原子数：
  36
• 可旋转键数：
  16
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.64
• 拓扑面积：
  81.2
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  1,4-di(N,N-di-n-butyl-acetamido)-quinoxaline-2,3-dione 、 terbium(III) nitrate hexahydrate 以 乙酸乙酯 为溶剂， 生成 [Tb(NO3)3(1,4-di(N,N-di-n-butyl-acetamino)-quinoxaline-2,3-dione)]*H2O
  参考文献：
  名称：

  Synthesis and spectroscopic properties of lanthanide nitrate complexes with a new amide-based quinoxaline-2,3-dione ligand

  摘要：

  Solid complexes of lanthanide nitrate with 1,4-di(N,N-di-n-butyl-acetamido)-quinoxaline-2,3-dione (L), [Ln(NO3)(3)L center dot H2O] (Ln = La, Nd, Eu, Gd, Tb, Er), have been prepared and characterized by elemental analysis, IR, UV-vis spectra and conductivity measurements. The fluorescence property of the europium complex in solid state and in MeCN, acetone, AcOEt and THF was studied. Under the excitation, the europium complex exhibited characteristic emissions of europium. The result indicates that the triplet state energy level of the ligand matches better to the resonance level of Eu(III) than Tb(III) ion. (C) 2007 Elsevier B.V. All fights reserved.

  DOI：

  10.1016/j.saa.2006.12.048
• 作为产物：
  描述：

  2-氯-N,N-二丁基乙酰胺 、 2,3-二羟基喹喔啉 在 potassium carbonate 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 以72%的产率得到1,4-di(N,N-di-n-butyl-acetamido)-quinoxaline-2,3-dione
  参考文献：
  名称：

  Synthesis and spectroscopic properties of lanthanide nitrate complexes with a new amide-based quinoxaline-2,3-dione ligand

  摘要：

  Solid complexes of lanthanide nitrate with 1,4-di(N,N-di-n-butyl-acetamido)-quinoxaline-2,3-dione (L), [Ln(NO3)(3)L center dot H2O] (Ln = La, Nd, Eu, Gd, Tb, Er), have been prepared and characterized by elemental analysis, IR, UV-vis spectra and conductivity measurements. The fluorescence property of the europium complex in solid state and in MeCN, acetone, AcOEt and THF was studied. Under the excitation, the europium complex exhibited characteristic emissions of europium. The result indicates that the triplet state energy level of the ligand matches better to the resonance level of Eu(III) than Tb(III) ion. (C) 2007 Elsevier B.V. All fights reserved.

  DOI：

  10.1016/j.saa.2006.12.048