2,5-Dinitrosobenzenecarboximidamide

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2,5-Dinitrosobenzenecarboximidamide
• 英文别名: 2,5-dinitrosobenzenecarboximidamide
• 化学式: C₇H₆N₄O₂
• 分子量: 178.15
• InChiKey: ANKRRTBHBIQDLU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.4
• 重原子数：
  13
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  109
• 氢给体数：
  2
• 氢受体数：
  5

文献信息

• INTERMEDIATE FOR MANUFACTURE OF POLYMERIZABLE COMPOUND AND PROCESS FOR MANUFACTURE THEREOF
  申请人：Zeon Corporation

  公开号：EP2762465A1

  公开（公告）日：2014-08-06

  The present invention pertains to a compound represented by a formula (I) and a method for producing thereof (in the formula, Ax is an organic group having 2 to 30 carbon atoms that includes at least one aromatic ring selected from a group consisting of an aromatic hydrocarbon ring and an aromatic hetero ring, Ay is a hydrogen atom, an alkyl group having 1 to 18 carbon atoms, a cycloalkyl group, an alkenyl group having 2 to 18 carbon atoms, an organic group having 2 to 30 carbon atoms that includes at least one aromatic ring selected from a group consisting of an aromatic hydrocarbon ring and an aromatic hetero ring, or the like. Ax and Ay optionally bond to each other to form a ring, and Q is a hydrogen atom, an alkyl group having 1 to 6 carbon atoms, or the like.). Accordinng to the invention, provided are a novel compound that makes it possible to produce an optical film that achieves uniform conversion of polarized light over a wide wavelength band can be inexpensively produced in high yield by utilizing the compound according to one aspect of the invention as an intermediate for producing the polymerizable compound, and a method for producing thereof.

  本发明涉及一种由式(I)表示的化合物及其生产方法（式中，Ax为具有2至30个碳原子的有机基团，其中包括至少一个芳香环，该芳香环选自由芳香烃环和芳香杂环组成的组、Ay 是氢原子、具有 1 至 18 个碳原子的烷基、环烷基、具有 2 至 18 个碳原子的烯基、具有 2 至 30 个碳原子的有机基团，其中包括至少一个从芳香烃环和芳香杂环组成的组中选出的芳香环，或类似物。Ax和Ay可选择彼此结合形成一个环，Q是氢原子、具有1至6个碳原子的烷基或类似物）。根据本发明，提供了一种新型化合物，通过利用根据本发明一个方面的化合物作为生产可聚合化合物的中间体，可以廉价地高产率生产出一种光学薄膜，该光学薄膜可以实现宽波长带内偏振光的均匀转换，并提供了一种生产方法。
• POLYMERIZABLE COMPOUND, POLYMERIZABLE COMPOSITION, POLYMER, AND OPTICAL ISOMER
  申请人：Zeon Corporation

  公开号：EP3106456A1

  公开（公告）日：2016-12-21

  The present invention is a polymerizable compound represented by a general formula (I), a polymerazable composition, a polymer, and an optically anisotropic product. In the formula: Q1 to Q4 represent hydrogen atoms, an alkyl group having 1 to 6 carbon atoms or the like; X represents a divalent aromatic group having 6 to 12 carbon atoms or the like; Ax represents a group represented by a general formula (II); Ay represents a group represented by a general formula (III); n represents 0 or 1; "*" indicates a bonding position; Y1x to Y6x and Y1y to Y8y represent a chemical single bond, -O-, -S-, -O-C(=O)-, -C(=O)-O-, -O-C(=O)-O- or the like; G1x,G2x, G1y and G2y represent a divalent aliphatic group having 1 to 20 carbon atoms or the like; Z1x ,Z2x, Z1y and Z2y represent an alkenyl group having 2 to 10 carbon atoms or the like; A1x and A1y represent a trivalent aromatic group or the like; A2x, A3x A4y and A5y represent a divalent aromatic group having 4 to 30 carbon atoms or the like; and A2y and A3y represent a divalent alicyclic hydrocarbon group having 3 to 30 carbon atoms or the like.

  本发明是一种由通式（I）表示的可聚合化合物、一种可聚合的组合物、一种聚合物和一种光学各向异性产品。在通式中Q1 至 Q4 代表氢原子、具有 1 至 6 个碳原子的烷基或类似基团； X 代表具有 6 至 12 个碳原子的二价芳香基团或类似基团； Ax 代表通式（II）所代表的基团；Ay 代表通式 (III) 所代表的基团；n 代表 0 或 1；"*"表示键合位置；Y1x 至 Y6x 和 Y1y 至 Y8y 代表化学单键、-O-、-S-、-O-C(=O)-、-C(=O)-O-、-O-C(=O)-O- 或类似键；G1x、G2x、G1y 和 G2y 代表具有 1 至 20 个碳原子的二价脂肪族基团或类似基团；Z1x、Z2x、Z1y 和 Z2y 代表具有 2 至 10 个碳原子的烯基或类似基团；A1x 和 A1y 代表三价芳香族基团或类似基团；A2x、A3x A4y 和 A5y 代表具有 4 至 30 个碳原子的二价芳香基团或类似基团；以及 A2y 和 A3y 代表具有 3 至 30 个碳原子的二价脂环烃基团或类似基团。