[6-Bis(3,5-dimethylphenyl)phosphanyl-5-[2-bis(3,5-dimethylphenyl)phosphanyl-6-methoxyphenyl]-1-(2,2-dimethylpropanoyloxy)-4-methoxycyclohexa-2,4-dien-1-yl] 2,2-dimethylpropanoate

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [6-Bis(3,5-dimethylphenyl)phosphanyl-5-[2-bis(3,5-dimethylphenyl)phosphanyl-6-methoxyphenyl]-1-(2,2-dimethylpropanoyloxy)-4-methoxycyclohexa-2,4-dien-1-yl] 2,2-dimethylpropanoate
• 英文别名: [6-bis(3,5-dimethylphenyl)phosphanyl-5-[2-bis(3,5-dimethylphenyl)phosphanyl-6-methoxyphenyl]-1-(2,2-dimethylpropanoyloxy)-4-methoxycyclohexa-2,4-dien-1-yl] 2,2-dimethylpropanoate
• 化学式: C₅₆H₆₆O₆P₂
• 分子量: 897.1
• InChiKey: PZKTVYPAZBYJDL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  13.1
• 重原子数：
  64
• 可旋转键数：
  15
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.36
• 拓扑面积：
  71.1
• 氢给体数：
  0
• 氢受体数：
  6

文献信息

• METHOD FOR PREVENTING DECREASE IN OPTICAL PURITY
  申请人：Takasago International Corporation

  公开号：EP2774908A1

  公开（公告）日：2014-09-10

  The present invention provides a method for producing a reduction reaction product, wherein recovery of the reaction solvent and/or distillation is carried out after adding a nitrogen-containing compound into a reaction liquid of a reduction reaction that has been conducted using a transition metal complex. The present invention is capable of suppressing decrease in the optical purity of the reduction reaction product due to the transition metal complex used as a catalyst.

  本发明提供了一种生产还原反应产物的方法，其中在使用过渡金属络合物进行还原反应的反应液中加入含氮化合物后，进行反应溶剂回收和/或蒸馏。本发明能够抑制由于过渡金属络合物用作催化剂而导致的还原反应产物光学纯度的降低。