LIQUID CRYSTAL ALIGNING AGENT, LIQUID CRYSTAL ALIGNMENT FILM AND LIQUID CRYSTAL DISPLAY DEVICE
申请人:NISSAN CHEMICAL INDUSTRIES, LTD.
公开号:US20160244673A1
公开(公告)日:2016-08-25
To provide a liquid crystal aligning agent to obtain a liquid crystal alignment film which is excellent in the adhesion to a sealing agent and in the liquid crystal alignment property.
A liquid crystal aligning agent containing at least one polymer selected from the group consisting of a polyimide precursor having structural units represented by the formula (1) and structural units represented by the formula (3) and an imidized polymer of the polyimide precursor:
wherein X
1
and X
4
are a tetravalent organic group, Y
1
is a bivalent organic group having a thermally-leaving group, Y
2
is a bivalent organic group, R
1
and R
2
are a hydrogen atom or a C
1-5
alkyl group, and Z
1
and Z
2
are a hydrogen atom, or a C
1-10
alkyl group, C
2-10
alkenyl group or C
2-10
alkynyl group which may have a substituent.
提供一种液晶定向剂,以获得具有优异密封剂附着性和液晶定向性的液晶定向膜。所述液晶定向剂包含至少一种聚合物,所述聚合物从以下组中选择:具有由公式(1)和公式(3)表示的结构单元的聚酰亚胺前体和聚酰亚胺前体的缩酐聚合物:其中X1和X4是四价有机基团,Y1是具有热离基的双价有机基团,Y2是双价有机基团,R1和R2是氢原子或C1-5烷基基团,Z1和Z2是氢原子或C1-10烷基基团、C2-10烯基基团或C2-10炔基基团,可以具有取代基。