N-tert-butoxycarbonyl-N-ethylhydroxylamine | 82820-53-9

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: N-tert-butoxycarbonyl-N-ethylhydroxylamine
• 英文别名: tert-butyl N-ethyl-N-hydroxycarbamate
• CAS: 82820-53-9
• 化学式: C₇H₁₅NO₃
• 分子量: 161.201
• InChiKey: MDRMWRGGFATSDG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1
• 重原子数：
  11
• 可旋转键数：
  3
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.86
• 拓扑面积：
  49.8
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  N-tert-butoxycarbonyl-N-ethylhydroxylamine 、 对甲苯磺酰氯 在 三乙胺 作用下， 以 氯仿 为溶剂， 反应 3.0h， 以81%的产率得到O-(p-toluenesulfonyl)-N-tert-butoxycarbonyl-N-ethylhydroxylamine
  参考文献：
  名称：

  Tamura, Yasumitsu; Ikeda, Hiroyuki; Morita, Iwao, Chemical and pharmaceutical bulletin, 1982, vol. 30, # 4, p. 1221 - 1224

  摘要：

  DOI：
• 作为产物：
  描述：

  N-乙基羟胺盐酸盐 、 二碳酸二叔丁酯 在 potassium carbonate 作用下， 以 四氢呋喃 、 水 为溶剂， 以83%的产率得到N-tert-butoxycarbonyl-N-ethylhydroxylamine
  参考文献：
  名称：

  Tamura, Yasumitsu; Ikeda, Hiroyuki; Morita, Iwao, Chemical and pharmaceutical bulletin, 1982, vol. 30, # 4, p. 1221 - 1224

  摘要：

  DOI：

文献信息

• PENTADIENAMIDE DERIVATIVE
  申请人：Kyowa Hakko Kirin Co., Ltd.

  公开号：EP2050734A1

  公开（公告）日：2009-04-22

  The present invention provides a pentadienamide derivative represented by the formula (I): (wherein R1 represents substituted or unsubstituted aryl or a substituted or unsubstituted aromatic heterocyclic group; R2 represents substituted or unsubstituted aryl, a substituted or unsubstituted aromatic heterocyclic group, a substituted or unsubstituted heteroalicyclic group, or the like; R3 represents a hydrogen atom or is combined together with R4 and the adjacent nitrogen atom thereto to form a substituted or unsubstituted heterocyclic group; R4 represents substituted or unsubstituted aryl, a substituted or unsubstituted aromatic heterocyclic group, a substituted or unsubstituted heteroalicyclic group, or the like, or is combined together with R3 and the adjacent nitrogen atom thereto to form a substituted or unsubstituted heterocyclic group; and R5, R6, and R7 may be the same or different, and each represents a hydrogen atom or methyl) or a pharmaceutically acceptable salt thereof, and the like.

  本发明提供了一种由式(I)表示的戊二烯酰胺衍生物:(其中R1代表取代或未取代的芳基或取代或未取代的芳香族杂环基；R2代表取代或未取代的芳基、取代或未取代的芳香族杂环基、取代或未取代的杂环螺环基或类似物；R3代表氢原子或与R4及其相邻的氮原子结合形成取代或未取代的杂环基；R4代表取代或未取代的芳基、取代或未取代的芳香族杂环基、取代或未取代的杂环螺环基或类似物，或与R3及其相邻的氮原子结合形成取代或未取代的杂环基；R5、R6和R7可以相同也可以不同，每个代表氢原子或甲基)或其药学上可接受的盐等。
• PHOTORESIST AND COATED SUBSTRATE COMPRISING SAME
  申请人：Wang Deyan

  公开号：US20140065540A1

  公开（公告）日：2014-03-06

  A polymer includes the polymerized product of monomers including a nitrogen-containing monomer comprising formula (Ia), formula (Ib), or a combination of formulas (Ia) and (Ib), and an acid-deprotectable monomer having the formula (II): wherein a, L 1 , LN, R a , R b , R c , and X are defined herein. The polymer is a useful component of a photoresist composition.

  一种聚合物包括单体的聚合产物，其中包括一种含有氮的单体，其化学式为（Ia）、化学式为（Ib）或化学式（Ia）和（Ib）的组合，并且还包括具有化学式（II）的酸解保护单体：其中a、L1、LN、Ra、Rb、Rc和X的定义如本文所述。该聚合物是光阻组合物的有用组分。
• SURFACE ACTIVE ADDITIVE AND PHOTORESIST COMPOSITION COMPRISING SAME
  申请人：Wang Deyan

  公开号：US20130137035A1

  公开（公告）日：2013-05-30

  A polymer comprises the polymerized product of monomers comprising a nitrogen-containing monomer comprising formula (Ia), formula (Ib), or a combination of formulas (Ia) and (Ib), and an acid-deprotectable monomer having the formula (II): wherein a is 0 or 1, each R a is independently H, F, C 1-10 alkyl, or C 1-10 fluoroalkyl, L 1 is a straight chain or branched C 1-20 alkylene group, or a monocyclic, polycyclic, or fused polycyclic C 3-20 cycloalkylene group, each R b is independently H, C 1-10 alkyl, C 3-20 cycloalkyl, C 3-20 heterocycloalkyl, an aliphatic C 5-20 oxycarbonyl, or a C 1-30 acyl group optionally including a heteroatom substituent group, where each R b is separate or at least one R b is attached to an adjacent R b ; LN is a nitrogen-containing monocyclic, polycyclic, or fused polycyclic C 3-20 heterocycloalkylene group, and X is H, C 1-10 alkyl, aliphatic C 5-20 oxycarbonyl, or a C 1-30 acyl group optionally including a heteroatom substituent group; and each R c is independently C 1-10 alkyl, C 3-20 cycloalkyl, or C 3-20 heterocycloalkyl, wherein each R c is separate or at least one R c is attached to an adjacent R c .

  一种聚合物包括由单体聚合而成的产物，所述单体包括式（Ia）、式（Ib）或式（Ia）和（Ib）的组合所包含的含氮单体，以及具有式（II）的酸去保护单体：其中a为0或1，每个Rais独立地为H、F、C1-10烷基或C1-10氟烷基，L1为直链或支链C1-20烷基，或单环、多环或融合多环C3-20环烷基，每个Rbis独立地为H、C1-10烷基、C3-20环烷基、C3-20杂环烷基、脂肪族C5-20氧羰基或C1-30酰基，可包括一个杂原子取代基，其中每个Rbis分离或至少一个Rbis连接到相邻的Rb上；LN为含氮单环、多环或融合多环C3-20杂环烷基，X为H、C1-10烷基、脂肪族C5-20氧羰基或C1-30酰基，可包括一个杂原子取代基；每个Rcis独立地为C1-10烷基、C3-20环烷基或C3-20杂环烷基，其中每个Rcis分离或至少一个Rcis连接到相邻的Rc上。
• PENTADIENAMIDE DERIVATIVES
  申请人：NAKASATO Yoshisuke

  公开号：US20090203667A1

  公开（公告）日：2009-08-13

  The present invention provides a pentadienamide derivative represented by the formula (I): (wherein R 1 represents substituted or unsubstituted aryl or a substituted or unsubstituted aromatic heterocyclic group; R 2 represents substituted or unsubstituted aryl, a substituted or unsubstituted aromatic heterocyclic group, a substituted or unsubstituted heteroalicyclic group, or the like; R 3 represents a hydrogen atom or is combined together with R 4 and the adjacent nitrogen atom thereto to form a substituted or unsubstituted heterocyclic group; R 4 represents substituted or unsubstituted aryl, a substituted or unsubstituted aromatic heterocyclic group, a substituted or unsubstituted heteroalicyclic group, or the like, or is combined together with R 3 and the adjacent nitrogen atom thereto to form a substituted or unsubstituted heterocyclic group; and R 5 , R 6 , and R 7 may be the same or different, and each represents a hydrogen atom or methyl) or a pharmaceutically acceptable salt thereof, and the like.

  本发明提供了一种由以下公式（I）表示的五二烯酰胺衍生物：（其中，R1代表取代或未取代的芳基或取代或未取代的芳香杂环基；R2代表取代或未取代的芳基，取代或未取代的芳香杂环基，取代或未取代的杂环螺环基或类似物；R3代表氢原子或与R4及其相邻的氮原子结合形成取代或未取代的杂环基；R4代表取代或未取代的芳基，取代或未取代的芳香杂环基，取代或未取代的杂环螺环基或类似物，或与R3及其相邻的氮原子结合形成取代或未取代的杂环基；R5、R6和R7可以相同也可以不同，每个代表氢原子或甲基）或其药学上可接受的盐等。
• TAMURA, YASUMITSU;IKEDA, HIROYUKI;MORITA, IWAO;TSUBOUCHI, HIDETSUGU;IKEDA+, CHEM. AND PHARM. BULL., 1982, 30, N 4, 1221-1224
  作者：TAMURA, YASUMITSU、IKEDA, HIROYUKI、MORITA, IWAO、TSUBOUCHI, HIDETSUGU、IKEDA+

  DOI：——

  日期：——