phenylcyclohexyl ketone | 68983-74-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: phenylcyclohexyl ketone
• 英文别名: Bis(1-phenylcyclohexyl)methanone
• CAS: 68983-74-4
• 化学式: C₂₅H₃₀O
• 分子量: 346.513
• InChiKey: WYEGLTFNZQPMQK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.1
• 重原子数：
  26
• 可旋转键数：
  4
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.48
• 拓扑面积：
  17.1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  1-苯基-1-环己基甲腈 在 盐酸 作用下， 以 苯 为溶剂， 生成 phenylcyclohexyl ketone
  参考文献：
  名称：

  Mazaleyrat,J.-P., Canadian Journal of Chemistry, 1978, vol. 56, p. 2731 - 2736

  摘要：

  DOI：

文献信息

• SYNTHESIS OF HYPERVALENT IODINE REAGENTS WITH DIOXYGEN
  申请人：The Texas A&M University System

  公开号：US20190002487A1

  公开（公告）日：2019-01-03

  Methods of synthesis of hypervalent iodine reagents and methods for oxidation of organic compounds are disclosed.

  揭示了高价碘试剂的合成方法和有机化合物氧化的方法。
• METHOD OF PRODUCING AN OPTICALLY ACTIVE CYANOHYDRIN DERIVATIVE
  申请人：Yeo Wee Chuan

  公开号：US20100179343A1

  公开（公告）日：2010-07-15

  The present invention relates to a method of producing an optically active cyanohydrin derivative, which comprises reacting an aldehyde or an asymmetrical ketone with a cyanating agent in the presence of a Lewis base and a titanium compound produced from a partial hydrolysate of titanium tetraalkoxide and an optically active ligand represented by formula (II) or a titanium oxoalkoxide compound represented by formula (I) [Ti x O y ](OR 1 ) 4x-2y , and an optically active ligand represented by formula (II), wherein R 1 is an optionally substituted alkyl group or an optionally substituted aryl group; x is an integer of not less than 2; y is an integer of not less than 1; and y/x satisfies 0.1

  本发明涉及一种制备光学活性氰醇衍生物的方法，包括在Lewis碱和由钛四烷氧化物的部分水解物和式(I)[TixOy](OR1)4x-2y，以及由式(II)表示的光学活性配体组成的钛氧烷衍生物的存在下，将醛或不对称酮与氰化试剂反应。其中，R1是可选的取代基的烷基或芳基；x为不小于2的整数；y为不小于1的整数；且y/x满足0.1
• Method for producing adhesive polyacrylates using mercapto functional photoinitiators
  申请人：——

  公开号：US20040049972A1

  公开（公告）日：2004-03-18

  A process for preparing pressure-sensitively adhesive polyacrylates by free-radical addition polymerization, characterized in that mercapto-functionalized photoinitiators of the general formula (I) and/or (II). H—S—R   (I) R—S—S—R′  (II) are added to the monomer mixture or to the reaction mixture, R and R′ being chosen independently of one another from the following groups: a) benzophenone, acetophenone, benzil, benzoin, hydroxyalkylphenone, phenylcyclohexyl ketone, anthraquinone, thioxanthone, triazine, or fluorenone radicals, it being possible for each of these radicals to be substituted by one or more halogen atoms and/or one or more alkoxy groups and/or one or more amino groups or hydroxyl groups, b) radicals which comprise one or more of the substituted or unsubstituted radicals specified under a).

  一种通过自由基加成聚合制备压敏粘合剂聚丙烯酸酯的方法，其特征在于向单体混合物或反应混合物中添加通式（I）和/或（II）的巯基功能化光引发剂。其中R和R'分别独立地选择以下基团：a）苯基酮，乙酰苯，苯并二酮，苯并酚，羟基烷基苯酮，苯基环己基酮，蒽醌，噻吩酮，三嗪或芴酮基团，每个基团都可以被一个或多个卤素原子和/或一个或多个烷氧基团和/或一个或多个氨基或羟基团取代，b）包括在a）中指定的一个或多个取代或未取代基团的基团。
• Synthesis of hypervalent iodine reagents with dioxygen
  申请人：The Texas A&M University System

  公开号：US10487099B2

  公开（公告）日：2019-11-26

  Methods of synthesis of hypervalent iodine reagents and methods for oxidation of organic compounds are disclosed.

  公开了超价碘试剂的合成方法和有机化合物的氧化方法。
• Continuous two-stage preparation of solvent-free polyacrylate hotmelt PSAs
  申请人：——

  公开号：US20040024111A1

  公开（公告）日：2004-02-05

  In a continuous two-stage process for preparing solvent-free polyacrylate hotmelt pressure sensitive adhesives which is gentle on the polymer and redeploys the solvent used in the process the following steps are carried out: polymerizing a self-adhesive pressure sensitive adhesive in solution, the solvent having a low vapor pressure; continuously mixing the polymer solution with antioxidants and preheating the mixture under superatmospheric pressure without boiling it; concentrating the polymer solution to a residual solvent content of less than 0.1% by weight in a concentrating extruder under the effect of reduced pressure and elevated temperatures; condensing, collecting, and re-using the solvent stripped off in the extruder; compounding the abovementioned solvent-freed hotmelt pressure sensitive adhesive with tackifying resins, fillers, stabilizers, crosslinkers or other additives in a second extruder at a moderate melt temperature; transferring the blended solvent-free self-adhesive pressure sensitive adhesive to a downstream coating unit.

  在制备无溶剂聚丙烯酸酯热熔压敏胶的连续两阶段工艺中，对聚合物温和，并重新利用了工艺中使用的溶剂： 在溶液中聚合自粘性压敏胶，溶剂的蒸汽压较低； 将聚合物溶液与抗氧化剂持续混合，在超大气压下预热混合物，但不使其沸腾； 在减压和升温的作用下，在浓缩挤压机中将聚合物溶液浓缩至残留溶剂含量小于 0.1%（按重量计）； 冷凝、收集和再利用挤压机中剥离的溶剂； 将上述无溶剂热熔压敏胶与增粘树脂、填料、稳定剂、交联剂或其他添加剂在中等熔融温度下在第二挤压机中混合； 将混合后的无溶剂自粘压敏胶输送到下游涂覆装置。