1,2-bis[6-(3,4-ethylenedioxythienyl)-2-methyl-1-benzothiophen-3-yl]perfluorocyclopentene | 922737-62-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并噻吩类
• 英文名称: 1,2-bis[6-(3,4-ethylenedioxythienyl)-2-methyl-1-benzothiophen-3-yl]perfluorocyclopentene
• 英文别名: 5-[3-[2-[6-(2,3-Dihydrothieno[3,4-b][1,4]dioxin-5-yl)-2-methyl-1-benzothiophen-3-yl]-3,3,4,4,5,5-hexafluorocyclopenten-1-yl]-2-methyl-1-benzothiophen-6-yl]-2,3-dihydrothieno[3,4-b][1,4]dioxine；5-[3-[2-[6-(2,3-dihydrothieno[3,4-b][1,4]dioxin-5-yl)-2-methyl-1-benzothiophen-3-yl]-3,3,4,4,5,5-hexafluorocyclopenten-1-yl]-2-methyl-1-benzothiophen-6-yl]-2,3-dihydrothieno[3,4-b][1,4]dioxine
• CAS: 922737-62-0
• 化学式: C₃₅H₂₂F₆O₄S₄
• 分子量: 748.812
• InChiKey: BXGGVUYTFPUDOD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  9.7
• 重原子数：
  49
• 可旋转键数：
  4
• 环数：
  9.0
• sp3杂化的碳原子比例：
  0.26
• 拓扑面积：
  150
• 氢给体数：
  0
• 氢受体数：
  14

反应信息

• 作为反应物：
  描述：

  1,2-bis[6-(3,4-ethylenedioxythienyl)-2-methyl-1-benzothiophen-3-yl]perfluorocyclopentene 以 二氯甲烷 为溶剂， 反应 0.5h， 生成
  参考文献：
  名称：

  Electropolymerization of an EDOT-modified diarylethene

  摘要：

  A diarylethene substituted with 3,4-ethylenedioxythiophene (EDOT) was synthesized to induce electrochemical anodic polymerization. Upon electrochemical oxidation of 1,2-bis(2-methylbenzo[b]thiophene-3-yl)perfluorocyclopentene (BTF)-substituted EDOT at the 6,6'-position (BTFTT), a red-purple polymeric film (PBTFTT) was deposited on a working electrode. A similar film was deposited on an electrode from the solution exposed to UV light through electrochemical oxidation. The film growth was controlled by the cycle numbers in cyclic voltammetry during the electropolymerization. The film thickness was linearly correlated to the potential cycle numbers, with a slope of 17.9 nm/cycle. The IR spectrum of the electrodeposited polymer showed characteristic C=C stretching frequency at 1630 and 1481 cm(-1) indicating that the BTF units in the polymer are closed. (c) 2006 Published by Elsevier Ltd.

  DOI：

  10.1016/j.tetlet.2006.11.039
• 作为产物：
  描述：

  1,2-二[2-甲基苯并[B]噻吩-3-基]-3,3,4,4,5,5-六氟-1-环戊烯 在 bis-triphenylphosphine-palladium(II) chloride 、 硫酸 、 碘 、 过碘酸 作用下， 以 溶剂黄146 、 甲苯 为溶剂， 反应 24.0h， 生成 1,2-bis[6-(3,4-ethylenedioxythienyl)-2-methyl-1-benzothiophen-3-yl]perfluorocyclopentene
  参考文献：
  名称：

  Electropolymerization of an EDOT-modified diarylethene

  摘要：

  A diarylethene substituted with 3,4-ethylenedioxythiophene (EDOT) was synthesized to induce electrochemical anodic polymerization. Upon electrochemical oxidation of 1,2-bis(2-methylbenzo[b]thiophene-3-yl)perfluorocyclopentene (BTF)-substituted EDOT at the 6,6'-position (BTFTT), a red-purple polymeric film (PBTFTT) was deposited on a working electrode. A similar film was deposited on an electrode from the solution exposed to UV light through electrochemical oxidation. The film growth was controlled by the cycle numbers in cyclic voltammetry during the electropolymerization. The film thickness was linearly correlated to the potential cycle numbers, with a slope of 17.9 nm/cycle. The IR spectrum of the electrodeposited polymer showed characteristic C=C stretching frequency at 1630 and 1481 cm(-1) indicating that the BTF units in the polymer are closed. (c) 2006 Published by Elsevier Ltd.

  DOI：

  10.1016/j.tetlet.2006.11.039