1-Methylamino(9,10H)anthraceneone | 86762-23-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: 1-Methylamino(9,10H)anthraceneone
• 英文别名: 1-Methylamino-anthron-(9)；1-(Methylamino)anthracen-9(10H)-one；1-(methylamino)-10H-anthracen-9-one
• CAS: 86762-23-4
• 化学式: C₁₅H₁₃NO
• 分子量: 223.274
• InChiKey: CCKWWOOMSJESCP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.9
• 重原子数：
  17
• 可旋转键数：
  1
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.13
• 拓扑面积：
  29.1
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  1-Methylamino(9,10H)anthraceneone 、 劳森试剂 以 甲苯 为溶剂， 反应 3.0h， 以59%的产率得到2-(4-Methoxy-phenyl)-3-methyl-3H-1-oxa-3-aza-2-phospha-benzo[de]anthracene 2-sulfide
  参考文献：
  名称：

  Synthesis of anthraoxaza- and anthradioxaphosphorine derivatives

  摘要：

  Anthraoxaza- and anthradioxaphosphorine sulfides were obtained by treatment of 1-amino- and 1-hydroxy-9-anthrones with Lawesson's reagent.

  DOI：

  10.1007/bf00696975
• 作为产物：
  描述：

  分散红9 生成 1-Methylamino(9,10H)anthraceneone
  参考文献：
  名称：

  Baughman George L., Weber Eric J., Environ. Sci. and Technol., 28 (1994) N 2, S 267-276

  摘要：

  DOI：

文献信息

• Transformation of dyes and related compounds in anoxic sediment: kinetics and products
  作者：George L. Baughman、Eric J. Weber

  DOI：10.1021/es00051a013

  日期：1994.2.1

  The reactions of several azo, anthraquinone, and quinoline dyes were studied in settled sediments. Several 1-substituted anthraquinones were lost from sediment with half-lives less than 10 days. For monosubstituted 1-amino and 1-methylamino (Disperse Red 9) compounds, the most stable product is the intramolecularly hydrogen-bonded anthrone. The 1,4-diaminoanthraquinone (Disperse Violet 1) and 1,4-diamino-2-methoxyanthraquinone (Disperse Red 11) were lost without formation of detectable products except for a demethylation product of the latter. Both the anthrone from Disperse Red 9 and the demethylation product of Disperse Red 11 reacted with half-lives of a few months, but other major products were not detected. An azo dye (Solvent Red 1) and a quinoline dye (Solvent Yellow 33) were transformed with half-lives of a few days and months, respectively. The azo dye reacted by reductive cleavage of the azo bond.
• Baughman George L., Weber Eric J., Environ. Sci. and Technol., 28 (1994) N 2, S 267-276
  作者：Baughman George L., Weber Eric J.

  DOI：——

  日期：——
• Loskutow W. A., Mamatjuk W. I., Isw. AN. Ser. khim, (1995) N 1, S 142-144
  作者：Loskutow W. A., Mamatjuk W. I.

  DOI：——

  日期：——
• Synthesis of anthraoxaza- and anthradioxaphosphorine derivatives
  作者：V. A. Loskutov、V. I. Mamatyuk

  DOI：10.1007/bf00696975

  日期：1995.1

  Anthraoxaza- and anthradioxaphosphorine sulfides were obtained by treatment of 1-amino- and 1-hydroxy-9-anthrones with Lawesson's reagent.