N-苯基-N-十四烷基苯胺 | 124071-29-0

• 分子结构分类: 有机化合物 - 有机氮化合物
• 中文名称: N-苯基-N-十四烷基苯胺
• 英文名称: N-tetradecyl diphenylamine
• 英文别名: N-Phenyl-N-tetradecylaniline
• CAS: 124071-29-0
• 化学式: C₂₆H₃₉N
• 分子量: 365.602
• InChiKey: KHJCTWVHTQLYFU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  10.3
• 重原子数：
  27
• 可旋转键数：
  15
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.54
• 拓扑面积：
  3.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  N-苯基-N-十四烷基苯胺 、 N,N-二甲基甲酰胺 在 三氯氧磷 作用下， 反应 48.5h， 以71%的产率得到N-tetradecyl-diphenylamine-4,4'-dicarbaldehyde
  参考文献：
  名称：

  New diphenylamine-based donor–acceptor-type conjugated polymers as potential photonic materials

  摘要：

  A new series of donor-acceptor-type conjugated polymers (P1 and P2) carrying a diphenyl amine moiety were synthesized via Wittig condensation technique. The polymers structures were well established by FT-IR, H-1 NMR, elemental analysis and gel permeation chromatographic techniques. They exhibited good thermal stability with an onset decomposition temperature of approximately 325 degrees C under nitrogen atmosphere. The optical and electrochemical properties of the polymers were studied by UV-vis, fluorescence emission spectroscopy and cyclic voltammetry. They exhibited good fluorescence in dilute solutions and showed solvatochromic behavior in various polar solvents. The electrochemical studies revealed that the polymers possess low-lying LUMO energy levels that ranging from -3.47 to -3.73 eV and high-lying HOMO energy levels that ranging from -5.57 to -5.81 eV. The thirdorder nonlinear optical properties of the polymers were investigated using the Z-scan technique. The effective two-photon absorption (TPA) coefficients (beta) of the polymers were found to be 0.645 x 10(-10) and 0.212 x 10(-10) m/W. (C) 2011 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.reactfunctpolym.2011.08.011
• 作为产物：
  描述：

  溴代十四烷 、 二苯胺 在 sodium hydride 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 5.5h， 以82%的产率得到N-苯基-N-十四烷基苯胺
  参考文献：
  名称：

  New diphenylamine-based donor–acceptor-type conjugated polymers as potential photonic materials

  摘要：

  A new series of donor-acceptor-type conjugated polymers (P1 and P2) carrying a diphenyl amine moiety were synthesized via Wittig condensation technique. The polymers structures were well established by FT-IR, H-1 NMR, elemental analysis and gel permeation chromatographic techniques. They exhibited good thermal stability with an onset decomposition temperature of approximately 325 degrees C under nitrogen atmosphere. The optical and electrochemical properties of the polymers were studied by UV-vis, fluorescence emission spectroscopy and cyclic voltammetry. They exhibited good fluorescence in dilute solutions and showed solvatochromic behavior in various polar solvents. The electrochemical studies revealed that the polymers possess low-lying LUMO energy levels that ranging from -3.47 to -3.73 eV and high-lying HOMO energy levels that ranging from -5.57 to -5.81 eV. The thirdorder nonlinear optical properties of the polymers were investigated using the Z-scan technique. The effective two-photon absorption (TPA) coefficients (beta) of the polymers were found to be 0.645 x 10(-10) and 0.212 x 10(-10) m/W. (C) 2011 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.reactfunctpolym.2011.08.011

文献信息

• LUBRICANT COMPOSITIONS CONTAINING A HETEROAROMATIC COMPOUND
  申请人：MATHUR Naresh

  公开号：US20120291737A1

  公开（公告）日：2012-11-22

  An ashless additive for lubricating oil compositions, lubricating oil compositions and methods for lubricating that are effective to improve the total base number (TBN) of a lubricant composition. The additive is a reaction product of a compound of the formula: with NH 3 , an alcohol, an amine, or a hydrocarbyl amine, wherein R 1 is selected from H, a hydrocarbyl group, the alcohol or amine contains from 1 to about 24 carbon atoms, and the hydrocarbyl amine has a number average molecular weight ranging from about 100 to about 6000

  一种无灰添加剂，用于润滑油组合物，润滑油组合物和润滑方法，能够有效地提高润滑剂组合物的总碱值（TBN）。该添加剂是以下化合物与NH3、醇、胺或烃基胺的反应产物：其中R1选自H、烃基基团，醇或胺含有1至约24个碳原子，烃基胺的数均分子量范围从约100到约6000。
• Additives and lubricant formulations for improved antioxidant properties
  申请人：Esche K. Carl

  公开号：US20060205615A1

  公开（公告）日：2006-09-14

  A method and compositions for lubricating surfaces with lubricating oils exhibiting increased antioxidant properties. The lubricated surface includes a lubricant composition containing a base oil of lubricating viscosity and an amount of at least one hydrocarbon soluble metal compound effective to provide a reduction in oxidation of the lubricant composition greater than a reduction in oxidation of the lubricant composition devoid of the hydrocarbon soluble metal compound. The metal of the metal compound is selected from the group consisting of titanium, zirconium, and manganese.

  一种润滑表面的方法和组合物，使用具有增强抗氧化性质的润滑油润滑。润滑表面包括一种润滑剂组合物，其中包含具有润滑粘度的基础油和至少一种亲水烃溶性金属化合物，其有效提供的润滑剂组合物的氧化还原反应的抑制程度大于不含亲水烃溶性金属化合物的润滑剂组合物的氧化还原反应的抑制程度。金属化合物的金属选自钛、锆和锰组成的组。
• Benzotriazole stabilizers for polyols and polyurethane foam
  申请人：R.T. VANDERBILT COMPANY, Inc.

  公开号：EP0839861A2

  公开（公告）日：1998-05-06

  Polyether and polyester poloyols and polyurethane foams are stabilized by including therein stabilizers selected from (1) diphenylaminomethylbenzotriazole substituted by alkyl or phenylalkyl groups or (2) synergistic compositions consisting of (a) benzotriazole or alkylbenzotriazole and (b) secondary aromatic amine substituted by alkyl or phenylalkyl groups wherein the benzotriazole and amine is present in critical ratios. Furthermore, a method is disclosed for preparation of polyurethane foams from polyols and polyisocyanate that have reduced discoloration due to scorch by adding diphenylamino methylbenzotriazole or compositions of benzotriazole and secondary aromatic amine as scorch inhibitors to the polyol, foaming the polyol and curing.

  聚醚和聚酯多元醇以及聚氨酯泡沫的稳定剂选自 (1) 被烷基或苯基烷基取代的二苯基氨基甲基苯并三唑或 (2) 由 (a) 苯并三唑或烷基苯并三唑和 (b) 被烷基或苯基烷基取代的仲芳香族胺组成的增效组合物，其中苯并三唑和胺以临界比例存在。 此外，还公开了一种用多元醇和多异氰酸酯制备聚氨酯泡沫的方法，通过向多元醇中添加二苯基氨基甲基苯并三唑或苯并三唑和仲芳香族胺的组合物作为焦烧抑制剂，使多元醇发泡并固化，从而减少焦烧引起的变色。
• An antioxidant additives combination for lubricants containing a molybdenum complex and an alkylated phenothiazine
  申请人：ETHYL CORPORATION

  公开号：EP1369469A1

  公开（公告）日：2003-12-10

  A lubricating oil composition having improved antioxidant properties, contains a molybdenum compound and an alkylated phenothiazine and may also include a secondary diarylamine.

  一种具有更好抗氧化性能的润滑油组合物，含有一种钼化合物和一种烷基化吩噻嗪，还可能包括一种仲二芳基胺。
• Diarylamine containing lubricating composition
  申请人：Afton Chemical Corporation

  公开号：EP1657293A2

  公开（公告）日：2006-05-17

  There is provided a lubricating composition having a major amount of a lubricating oil having less than about 40% by weight alkylcycloparaffins and a minor amount of at least one diarylamine, and processes for making and using thereof.

  本文提供了一种润滑油组合物，其主要成分是重量百分比小于约 40% 的烷基环烷烃，次要成分是至少一种二芳基胺，以及制造和使用该组合物的工艺。