3,5-di-tert.butyl-4-hydroxybenzyl-isocyanuric acid | 29623-79-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 3,5-di-tert.butyl-4-hydroxybenzyl-isocyanuric acid
• 英文别名: 1-[(3,5-Ditert-butyl-4-hydroxyphenyl)methyl]-1,3,5-triazinane-2,4,6-trione
• CAS: 29623-79-8
• 化学式: C₁₈H₂₅N₃O₄
• 分子量: 347.414
• InChiKey: AGHHRSWORINRIV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.5
• 重原子数：
  25
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  98.7
• 氢给体数：
  3
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  3,5-di-tert.butyl-4-hydroxybenzyl-isocyanuric acid 、 溴乙酸乙酯 生成 1-3-bis-[(1,2,2,6,6-pentamethyl-piperidin-4-yl-oxycarbonyl)-methyl]-5-[3,5-di-tert.butyl-4-hydroxybenzyl]-isocyanuric acid
  参考文献：
  名称：

  Piperidine containing cyanuric acid derivatives

  摘要：

  含有至少一个受阻酚基团和至少一个受阻胺基团的新的异三嗪酸衍生物对聚合材料具有良好的光稳定性和抗氧化性能。

  公开号：

  US04317911A1

文献信息

• Substituted 2-(2,6-di-t-butyl-4-alkylphenoxy) 4H-1,3,2-benzodioxaphosphorins and compositions thereof
  申请人：The B.F. GOODRICH Company

  公开号：EP0106169A1

  公开（公告）日：1984-04-25

  Substituted 2-(2,6-di-t-butyl-4-alkylphenoxy)-4H-1,3,2-benzodioxaphosphorins that are readily prepared, for example from hindered phenols and ortho-methylolphenols, are effective heat and anti-oxidant stabilizers for organic materials subject to degradation by heat and oxygen, and provide particularly efficient stabilizer systems when combined with hydroxyphenylalkyleneyl isocyanurates.

  取代的 2-(2,6-二叔丁基-4-烷基苯氧基)-4H-1,3,2-苯并二氧磷酸盐很容易制备，例如从受阻酚和邻甲基苯酚中制备，对于受热和受氧降解的有机材料来说是有效的热稳定剂和抗氧化剂，当与羟基苯亚烷基异氰酸酯结合使用时，可提供特别有效的稳定剂体系。
• Sterically hindered phenyl bis(naphthyl)phosphites and compositions thereof
  申请人：The B.F. GOODRICH Company

  公开号：EP0110293A2

  公开（公告）日：1984-06-13

  2,6-di-t-butyl-4-substituted phenyl bis(3,6-di-t-butyl-2-naphthyl)phosphites, readily prepared by reacting together a phosphorodichloridite of a 4-substituted-2,6-di-t-butylphenol and a sodium salt of 3,6-di-t-butyl-2-naphthol, to form antioxidant and ultraviolet stabilizers that form particularly effective combinations with hydroxyphenylalkyleneyl isocyanurates to provide enhanced oven aging properties to organic materials subject to attack by heat and oxygen.

  2,6-二-叔丁基-4-取代苯基双(3,6-二-叔丁基-2-萘基)亚磷酸盐，可通过将 4-取代-2,6-二-叔丁基苯酚的亚磷酰二氯与 3,6-二-叔丁基-2-萘酚的钠盐反应制备，形成抗氧化剂和紫外线稳定剂，与羟基苯基亚烷基异氰尿酸酯形成特别有效的组合，为受热和氧侵蚀的有机材料提供更强的烘箱老化性能。
• Corrosion inhibition of polymethylpentene
  申请人：PHILLIPS PETROLEUM COMPANY

  公开号：EP0331041A2

  公开（公告）日：1989-09-06

  The corrosion tendencies of polymers of 4-methyl-1-pentene, when combined with tris-(3,5-ditert-butyl-4-hydroxybenzyl)isocyanurate and bis-(2,4-ditert-butyl)pentaerythritol diphosphite are reduced. Optionally, metal stearates and/or poly[[6-[(1,1,3,3-tetramethylbutyl)­amino]-5-triazine-2,4-diyl][2,2,6,6-tetramethyl-4-piperidyl)imino]hexa­methylene]2,2,6,6-tetramethyl-4-piperidyl)imino]] can be added to further reduce the polymer corrosion tendencies.

  当 4-甲基-1-戊烯聚合物与三-(3,5-二叔丁基-4-羟基苄基)异氰脲酸酯和双-(2,4-二叔丁基)季戊四醇二亚磷酸酯结合使用时，其腐蚀倾向会降低。可选择添加金属硬脂酸盐和/或聚[[6-[(1,1,3,3-四甲基丁基)氨基]-5-三嗪-2,4-二基][2,2,6,6-四甲基-4-哌啶基)亚氨基]六亚甲基]2,2,6,6-四甲基-4-哌啶基)亚氨基]]，以进一步降低聚合物的腐蚀倾向。
• Stabilized polyethylene composition
  申请人：BP Chemicals Limited

  公开号：EP0366305A1

  公开（公告）日：1990-05-02

  A stabilized polyethylene composition containing catalyst residues comprising at least one transition metal comprises (a) polyethylene, (b) 100 to 2000 ppm by weight based on the total weight of the composition of one or more antioxidants of the phenolic type and (c) 100 to less than 2000 ppm by weight, based on the total weight of the composition of zinc oxide but substantially no calcium stearate. The composition has improved colour and improved resistance to colouration effects.

  一种含有至少一种过渡金属的催化剂残留物的稳定聚乙烯组合物包括：(a) 聚乙烯；(b) 以组合物总重量为基准，100 至 2000 ppm 重量级的一种或多种酚类抗氧化剂；(c) 以组合物总重量为基准，100 至低于 2000 ppm 重量级的氧化锌，但基本上不含硬脂酸钙。该组合物具有更好的色泽和抗着色效果。
• Air impermeable containers
  申请人：EXXON CHEMICAL PATENTS INC.

  公开号：EP0376558A1

  公开（公告）日：1990-07-04

  Vehicle inner tubes are formed with walls comprising thermoplastic elastomeric polymer compositions containing semi-crystalline ethylene copolymer such as ethylene vinyl acetate, and vulcanized butyl or halogenated butyl rubber particles.

  汽车内胎的内壁由热塑性弹性聚合物组成，其中包含半结晶乙烯共聚物（如乙烯-醋酸乙烯）和硫化丁基橡胶或卤化丁基橡胶颗粒。