1-(4-But-3-enylphenyl)-2,3-difluoro-4-(4-methylphenyl)benzene

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1-(4-But-3-enylphenyl)-2,3-difluoro-4-(4-methylphenyl)benzene
• 英文别名: 1-(4-but-3-enylphenyl)-2,3-difluoro-4-(4-methylphenyl)benzene
• 化学式: C₂₃H₂₀F₂
• 分子量: 334.4
• InChiKey: KFHMFADMURNAOA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.1
• 重原子数：
  25
• 可旋转键数：
  5
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.13
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  2

文献信息

• LIQUID CRYSTAL COMPOSITION, AND LIQUID CRYSTAL DISPLAY ELEMENT USING SAME
  申请人：DIC Corporation

  公开号：EP2883937A1

  公开（公告）日：2015-06-17

  An object of the present invention is to provide a liquid crystal composition suitable for use in a liquid crystal display device, with which various properties of liquid crystal display devices, such as dielectric anisotropy, viscosity, nematic phase upper limit temperature, low-temperature nematic phase stability, and γ1, and ghosting properties of a display device are not degraded, dropping marks that occur during production are suppressed, and a liquid crystal material can be discharged in stable amounts in an ODF process. A liquid crystal display device that uses such a liquid crystal composition is also provided. Provided is a liquid crystal composition that includes a first component which is at least one selected from the group consisting of compounds represented by general formula (1) and a second component which is at least one component selected from the group consisting of compounds represented by general formula (2). Also provided is a liquid crystal display device that uses a liquid crystal composition that contains the first component and the second component.

  本发明的目的是提供一种适用于液晶显示设备的液晶组合物，使用这种组合物，液晶显示设备的各种特性，如介电各向异性、粘度、向列相上限温度、低温向列相稳定性和γ1，以及显示设备的重影特性不会降低，生产过程中出现的滴痕也会被抑制，而且液晶材料可以在 ODF 工艺中以稳定的量排出。此外，还提供了一种使用这种液晶组合物的液晶显示设备。 本发明提供了一种液晶组合物，它包括至少一种从通式（1）所代表的化合物组成的组中选出的第一组分和至少一种从通式（2）所代表的化合物组成的组中选出的第二组分。此外，还提供了一种液晶显示装置，该装置使用的液晶组合物包含第一种成分和第二种成分。
• LIQUID CRYSTAL COMPOSITION, LIQUID CRYSTAL DISPLAY ELEMENT, AND LIQUID CRYSTAL DISPLAY
  申请人：DIC Corporation

  公开号：EP2883938A1

  公开（公告）日：2015-06-17

  There is provided a liquid crystal composition containing at least any one of compounds represented by General Formula (i) and at least any one of compounds represented by General Formula (ii). In the formulae, Ri1 represents an alkyl group having 1 to 8 carbon atoms; and Ai1 represents a 1,4-cyclohexylene group (of which one -CH2- or at least two -CH2- not adjoining each other are optionally substituted with -O-), a 1,4-phenylene group (of which at least one hydrogen atom is optionally substituted with a fluorine atom), or a single bond; Rii1 represents an alkyl group having 1 to 8 carbon atoms; and one -CH2- or at least two -CH2- not adjoining each other in the alkyl group are each independently optionally substituted with -CH=CH-, -C=C-, -O-, -CO-, -COO-, or -OCO-; Rii2 represents a fluorine atom, a chlorine atom, a cyano group, or an alkyl group having 1 to 8 carbon atoms; one-CH2- or at least two -CH2- not adjoining each other in the alkyl group are each independently optionally substituted with -CH=CH-, -C=C-, -O-, -CO-, -COO-, or -OCO-; and one or two or more hydrogen atoms of the alkyl group are each independently optionally substituted with a fluorine atom; Aii1 and Aii2 each independently represent a 1,4-cyclohexylene group (of which one -CH2- or at least two -CH2- not adjoining each other are optionally substituted with -O-) or a 1,4-phenylene group (of which at least one hydrogen atom is optionally substituted with a fluorine atom); Zii1 and Zii2 each independently represent a single bond, - CH2CH2-, -(CH2)4-, -CH2-, -CH2O-, -OCF2-, -CF2O-, -COO-, -OCO-, or -C=C-; mii1 and mii2 each independently represent 0, 1, 2, or 3; and mii1 + mii2 is equal to 1, 2, 3, or 4; in the case where Aii1 and Zii1 are multiple, the Aii1 moieties and the Zii1 moieties are the same as or different from each other, respectively; and in the case where Aii2 and Zii2 are multiple, the Aii2 moieties and the Zii2 moieties are the same as or different from each other, respectively. [Chem. 1]

  本发明提供了一种液晶组合物，其中含有通式(i)和通式(ii)所代表的至少任一种化合物。 在通式中，Ri1 代表具有 1 至 8 个碳原子的烷基；Ai1 代表 1，4-环己烯基团（其中一个-CH2-或至少两个互不相邻的- -任选被-O-取代）、1，4-亚苯基基团（其中至少一个氢原子任选被氟原子取代）或单键； Rii1 代表具有 1 至 8 个碳原子的烷基； 烷基中的一个- -或至少两个互不相邻的- -各自独立地任选被-CH=CH-、-C=C-、-O-、-CO-、-COO-或-OCO-取代； Rii2 代表氟原子、氯原子、氰基或具有 1 至 8 个碳原子的烷基；烷基中的一个- -或至少两个互不相邻的- -各自独立地任选被-CH=CH-、-C=C-、-O-、-CO-、-COO-或-OCO-取代；以及烷基中的一个或两个或多个氢原子各自独立地任选被氟原子取代； Aii1 和 Aii2 各自独立地代表 1,4-环己烯基团（其中一个- -或至少两个互不相邻的- -任选被-O-取代）或 1,4-苯基团（其中至少一个氢原子任选被氟原子取代）； Zii1和Zii2各自独立地代表单键、- -、-( )4-、- -、- O-、-OCF2-、-CF2O-、-COO-、-OCO-或-C=C-； mii1 和 mii2 各自独立地代表 0、1、2 或 3；且 mii1 + mii2 等于 1、2、3 或 4； 在 Aii1 和 Zii1 为多个的情况下，Aii1 分子和 Zii1 分子分别彼此相同或不同；以及 在 Aii2 和 Zii2 为多个的情况下，Aii2 分子和 Zii2 分子分别相同或不同。 [化学 1］
• LIQUID CRYSTAL COMPOSITION AND LIQUID CRYSTAL DISPLAY ELEMENT USING SAME
  申请人：DIC Corporation

  公开号：EP2902465A1

  公开（公告）日：2015-08-05

  The present invention relates to a liquid crystal composition used in a liquid crystal display device. A problem to be solved by the invention is to provide a liquid crystal composition and a liquid crystal display device using the liquid crystal composition, the liquid crystal composition being suitable for a liquid crystal display device, causing little dropping marks during manufacture and realizing stable discharge of a liquid crystal material in an ODF process without degrading characteristics as a liquid crystal display device, such as dielectric anisotropy, bulk viscosity, nematic phase upper limit temperature, rotational viscosity γ1, voltage holding ratio, etc. and image sticking characteristic of a display device. The present invention relates to a liquid crystal composition having negative dielectric anisotropy and containing compounds represented by formula (i) and formula (XIII-1-2) or formula (XIII-1-4) and also relates to a liquid crystal display device using the liquid crystal composition.

  本发明涉及一种用于液晶显示装置的液晶组合物。本发明要解决的问题是提供一种液晶组合物和一种使用该液晶组合物的液晶显示装置，该液晶组合物适用于液晶显示装置，在制造过程中几乎不会产生滴痕，并能在 ODF 工艺中实现液晶材料的稳定放电，而不会降低作为液晶显示装置的特性，如介电常数、体积粘度、向列相上限温度、旋转粘度γ1、电压保持比等，以及显示装置的图像粘滞特性。本发明涉及一种具有负介电各向异性并含有由式（i）和式（XIII-1-2）或式（XIII-1-4）表示的化合物的液晶组合物，还涉及一种使用该液晶组合物的液晶显示设备。
• POLYMERIZABLE-MONOMER-CONTAINING LIQUID CRYSTAL COMPOSITION AND LIQUID CRYSTAL DISPLAY ELEMENT USING SAME
  申请人：DIC Corporation

  公开号：EP3159393A1

  公开（公告）日：2017-04-26

  The problem to be solved by the present invention is to provide: a liquid crystal composition suitable for a liquid crystal display element which hardly generates drop marks in production without worsening various characteristics thereof as liquid crystal display elements such as dielectric anisotropy, viscosity, nematic phase upper limit temperature, low-temperature nematic phase stability, γ1 and others, and also burn-in characteristics of display elements, and which realizes a stable discharge amount of a liquid crystal material in an ODF process, and to provide a liquid crystal display element using the composition. The purpose of the present invention is to provide a liquid crystal composition provided with photosensitizing properties as the entire composition where a polymerizable monomer is combined with specific liquid crystal compounds.

  本发明要解决的问题是：提供一种适用于液晶显示元件的液晶组合物，该组合物在生产过程中几乎不会产生液滴痕迹，同时不会使其作为液晶显示元件的各种特性（如介电各向异性、粘度、向列相上限温度、低温向列相稳定性、γ1 等）以及显示元件的烧损特性恶化，并且能够在 ODF 工艺中实现稳定的液晶材料放电量，以及提供一种使用该组合物的液晶显示元件。本发明的目的是提供一种具有光敏特性的液晶组合物，作为可聚合单体与特定液晶化合物结合的整个组合物。
• LIQUID CRYSTAL COMPOSITION AND LIQUID CRYSTAL DISPLAY DEVICE USING SAME
  申请人：DIC Corporation

  公开号：EP2902465B1

  公开（公告）日：2018-06-06