N1-苯基-N4-(1-苯基乙基)苯-1,4-二胺 | 2830-40-2

• 分子结构分类: 有机化合物 - 有机氮化合物
• 中文名称: N1-苯基-N4-(1-苯基乙基)苯-1,4-二胺
• 英文名称: N-(1-phenylethyl)-N'-phenyl-1,4-phenylenediamine
• 英文别名: N-Phenyl-N'-1-phenylethyl-1,4-phenylenediamine；1-N-phenyl-4-N-(1-phenylethyl)benzene-1,4-diamine
• CAS: 2830-40-2
• 化学式: C₂₀H₂₀N₂
• 分子量: 288.392
• InChiKey: RRUHMDSGRHUALW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.3
• 重原子数：
  22
• 可旋转键数：
  5
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.1
• 拓扑面积：
  24.1
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  N-(1-phenylethylidene)-N'-phenyl-1,4-phenylenediamine 在 镍 氢气 作用下， 以 正庚烷 为溶剂， 150.0 ℃ 、3.0 MPa 条件下， 生成 N1-苯基-N4-(1-苯基乙基)苯-1,4-二胺
  参考文献：
  名称：

  [EN] METHOD OF PREPARATION OF N-(1-PHENYLETHYL)-N'-PHENYL-1,4-PHENYLENEDIAMINE AND USE THEREOF
  [FR] PROCEDE DE PREPARATION DE N-(1-PHENYLETHYL)-N'-PHENYL-1,4-PHENYLENEDIAMINE ET UTILISATION DE CETTE DERNIERE

  摘要：

  高纯度的N-(1-苯乙基)-N'-苯基-1,4-苯二胺是通过两步合成得到的，第一步中4-氨基二苯胺在酸性催化剂的存在下与苯乙酮反应。反应进行到4-氨基二苯胺未完全转化为止，得到高纯度的中间产物，第二步在非均相催化剂上进行氢化。N-(1-苯乙基)-N'-苯基-1,4-苯二胺可用作抗降解系统的组分。

  公开号：

  WO2005051886A1

文献信息

• [EN] METHOD OF PREPARATION OF N-(1-PHENYLETHYL)-N'-PHENYL-1,4-PHENYLENEDIAMINE AND USE THEREOF<br/>[FR] PROCEDE DE PREPARATION DE N-(1-PHENYLETHYL)-N'-PHENYL-1,4-PHENYLENEDIAMINE ET UTILISATION DE CETTE DERNIERE
  申请人：DUSLO AS

  公开号：WO2005051886A1

  公开（公告）日：2005-06-09

  N-(1-phenylethyl)-N'-phenyl-1,4-phenylenediamine of high purity is produced by a two-step synthesis, where in the first step 4-aminodiphenylamine reacts with acetophenone in the presence of an acidic catalyst. The reaction is performed to an incomplete conversion of 4-aminodiphenylamine, whereby an intermediate product of high purity is obtained, which is hydrogenated on a heterogeneous catalyst in the second step. N-(1-phenylethyl)-N'-phenyl-1,4-phenylenediamine can be used as a component of anti-degradation systems.

  高纯度的N-(1-苯乙基)-N'-苯基-1,4-苯二胺是通过两步合成得到的，第一步中4-氨基二苯胺在酸性催化剂的存在下与苯乙酮反应。反应进行到4-氨基二苯胺未完全转化为止，得到高纯度的中间产物，第二步在非均相催化剂上进行氢化。N-(1-苯乙基)-N'-苯基-1,4-苯二胺可用作抗降解系统的组分。
• GLOBULAR RUBBER ADJUVANTS AND THE METHOD OF PREPARATING THE SAME
  申请人：Jiangsu Sinorgchem Technology Co., Ltd

  公开号：EP2085135A1

  公开（公告）日：2009-08-05

  The present invention provides spherical rubber chemicals and the method for preparing the same. The spherical rubber chemicals of the present invention include spherical antioxidants, spherical vulcanization agents, spherical processing aids, spherical reinforcing agents, or spherical adhesive agents. With the spherical rubber chemicals of the present invention, the shortcomings of powdery or semi-spherical rubber chemicals are overcome, including eliminating the dust pollution during granulation procedure and avoiding the raw material loss and the environmental pollution, while solving the quality problem of lower melting point of product caused by the presence of fine powder crystal. Furthermore, the resultant rubber chemicals has an improved smoothness of surface, which is helpful to improve the flowing and mixing behaviors of the rubber chemicals in mixing or open milling process with rubbers.

  本发明提供了球形橡胶助剂及其制备方法。本发明的球形橡胶助剂包括球形防老剂、球形硫化剂、球形加工助剂、球形补强剂或球形粘合剂。本发明的球状橡胶助剂克服了粉状或半球状橡胶助剂的缺点，包括消除了造粒过程中的粉尘污染，避免了原料损失和环境污染，同时解决了因细小粉晶的存在而导致产品熔点降低的质量问题。此外，制得的橡胶助剂表面更加光滑，有助于改善橡胶助剂在与橡胶混炼或开炼过程中的流动性和混合行为。
• Organic compound, crystal dielectric layer and capacitor
  申请人：Capacitor Sciences Incorporated

  公开号：US10026553B2

  公开（公告）日：2018-07-17

  The present disclosure provides an organic compound characterized by electronic polarizability and having a following general structural formula: where Core is an aromatic polycyclic conjugated molecule, R1 is group providing solubility of the organic compound in an organic solvent, n is 1, 2, 3, 4, 5, 6, 7 or 8, R2 is substitute located in apex positions, R3 and R4 are substitutes located in side (lateral) positions and, the core has flat anisometric form and the R2 substitutes are selected from hydrogen and electrophilic groups (acceptors) and R3 substitutes and R4 substitutes are independently selected from hydrogen and nucleophilic groups (donors) or vice versa R3 substitutes and R4 substitutes are independently selected from hydrogen and nucleophilic groups (donors) and R2 substitutes are selected from hydrogen and electrophilic groups (acceptors), and the substitutes R2, R3 and R4 cannot all be hydrogen.

  本公开提供了一种有机化合物，其特点是具有电子极化性，并具有以下结构通式： 其中 Core 是芳香族多环共轭分子，R1 是提供有机化合物在有机溶剂中溶解度的基团，n 是 1、2、3、4、5、6、7 或 8，R2 是位于顶点位置的取代基，R3 和 R4 是位于侧（横向）位置的取代基，并且、核心具有扁平异形，R2 取代基选自氢和亲电基团（受体），R3 取代基和 R4 取代基独立选自氢和亲核基团（供体），反之亦然，R3 取代基和 R4 取代基独立选自氢和亲核基团（供体），R2 取代基选自氢和亲电基团（受体），且取代基 R2、R3 和 R4 不能都是氢。
• Capacitor and method of production thereof
  申请人：CAPACITOR SCIENCES INCORPORATED

  公开号：US10340082B2

  公开（公告）日：2019-07-02

  A capacitor includes a first electrode, a second electrode, and a dielectric layer of molecular material disposed between said first and second electrodes. The molecular material is described by the general formula: Dp-(Core)-Hq, where Core is a polarizable conductive anisometric core, having conjugated π-systems, and characterized by a longitudinal axis, D and H are insulating substituents, and p and q are numbers of the D and H substituents accordingly. And Core possesses at least one dopant group that enhances polarizability.

  一种电容器包括一个第一电极、一个第二电极和一个介于所述第一和第二电极之间的分子材料介电层。分子材料按通式描述： Dp-(Core)-Hq、 其中，Core 是具有共轭 π 系统的可极化导电异构磁芯，其特征是具有纵轴；D 和 H 是绝缘取代基；p 和 q 是相应的 D 和 H 取代基的数目。Core 具有至少一个可增强极化性的掺杂基团。
• Multilayered electrode and film energy storage device
  申请人：Capacitor Sciences Incorporated

  公开号：US10395841B2

  公开（公告）日：2019-08-27

  The present disclosure provides a multilayered electrode comprising an electro-conductive layer and at least one protective layer located on one side of the electro-conductive layer and selected from the list comprising a field-planarization layer, a tunneling injection blocking layer and a coulomb blocking layer.

  本公开提供了一种多层电极，包括一个导电层和至少一个位于导电层一侧的保护层，保护层可从包括场平面化层、隧道注入阻挡层和库仑阻挡层的列表中选择。