3,4,6-trichloroguaiacol | 60712-44-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 酚类
• 英文名称: 3,4,6-trichloroguaiacol
• 英文别名: 3,4,6-trichloro-2-methoxyphenol
• CAS: 60712-44-9
• 化学式: C₇H₅Cl₃O₂
• 分子量: 227.475
• InChiKey: HYCQPRXDNCTPOU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.8
• 重原子数：
  12
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  29.5
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  3,4-二氯苯-1,2-二醇 在 磺酰氯 、 potassium carbonate 作用下， 以 溶剂黄146 、 丙酮 为溶剂， 反应 4.0h， 生成 3,4,6-trichloroguaiacol
  参考文献：
  名称：

  Isomer specific syntheses of chlorinated catechols and guaiacols relevant to pulp bleaching

  摘要：

  A variety of chlorinated catechols and guaiacols relevant to pulp bleaching were synthesized by employing fundamental differences in the acidities of phenolic hydroxyl groups in chlorinated catechols, and directive effects in guaiacols. (C) 2001 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0045-6535(00)00568-3

文献信息

• Mass spectra of chlorinated aromatics formed in pulp bleaching 2—Chlorinated guaiacols
  作者：Juha Knuutinen、Ilpo O. O. Korhonen

  DOI：10.1002/oms.1210190210

  日期：1984.2

  AbstractThe fragmentation of chlorinated guaiacols (2‐methoxyphenols) on electron impact has been studied. The most common fragmentation processes are interpreted and in some cases the small differences between spectra of positional isomers are explained. In addition to the well‐known alkyl‐oxygen fission (loss of methyl radical), metastable ion studies and deuterium labelling have indicated several new fragmentation pathways. The most characteristic are the formation of [MCH3HCl]+ and [MCH3Cl]+· ions. In general, however, the spectra of positional isomers are shown to be very similar.
• A PROCESS FOR THE MICROBIOLOGICAL PURIFICATION OF WATER AND A MICROORGANISM FOR USE IN SAID PROCESS
  申请人：ALKO LIMITED

  公开号：EP0396648A1

  公开（公告）日：1990-11-14
• A PROCESS FOR THE MICROBIOLOGICAL PURIFICATION OF WATER
  申请人：ALKO LIMITED

  公开号：EP0396648B1

  公开（公告）日：1994-04-13
• US4410738A
  申请人：——

  公开号：US4410738A

  公开（公告）日：1983-10-18
• US4410737A
  申请人：——

  公开号：US4410737A

  公开（公告）日：1983-10-18