7-amino-1,12-tridecadiene | 1402226-20-3

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 7-amino-1,12-tridecadiene
• 英文别名: Trideca-1,12-dien-7-amine；trideca-1,12-dien-7-amine
• CAS: 1402226-20-3
• 化学式: C₁₃H₂₅N
• 分子量: 195.348
• InChiKey: BIITUHGHGXXKPJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.1
• 重原子数：
  14
• 可旋转键数：
  10
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.69
• 拓扑面积：
  26
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  7-amino-1,12-tridecadiene 在 铂(0)-1,3-二乙烯-1,1,3,3-四甲基二硅氧烷 、 zinc diacetate 作用下， 以 喹啉 、 甲苯 为溶剂， 反应 5.0h， 生成 N,N'-Bis[1,13-bis(1,1,3,3,3-pentamethylpropanedisiloxane-1-yl)tridecane-7-yl]perylene-3,4:9,10-bis(dicarbimide)
  参考文献：
  名称：

  PERYLENE TETRACARBOXYLIC ACID BISIMIDE DERIVATIVE, n-TYPE SEMICONDUCTOR, PROCESS FOR PRODUCING n-TYPE SEMICONDUCTOR, AND ELECTRONIC DEVICE

  摘要：

  公开号：

  EP2695885B1
• 作为产物：
  描述：

  壬-1,8-二烯-5-醇 在 一水合肼 、 三苯基膦 作用下， 以 四氢呋喃 、 甲醇 为溶剂， 反应 18.5h， 生成 7-amino-1,12-tridecadiene
  参考文献：
  名称：

  PERYLENE TETRACARBOXYLIC ACID BISIMIDE DERIVATIVE, n-TYPE SEMICONDUCTOR, PROCESS FOR PRODUCING n-TYPE SEMICONDUCTOR, AND ELECTRONIC DEVICE

  摘要：

  公开号：

  EP2695885B1

文献信息

• Liquid-crystalline perylene tetracarboxylic bisimide derivatives bearing cyclotetrasiloxane moieties
  作者：Masahiro Funahashi、Mika Yamaoka、Kaede Takenami、Akinari Sonoda

  DOI：10.1039/c3tc31567c

  日期：——

  Liquid-crystalline perylene tetracarboxylic bisimide derivatives bearing heptamethylcyclotetrasiloxane moieties have been synthesized. Compound 2 bearing four heptamethylcyclotetrasiloxane moieties exhibits a rectangular columnar phase at room temperature. In the columnar phase, the cyclotetrasiloxane rings interdigitate into neighbouring columns and their interaction promotes the formation of the columnar mesomorphic structure. A time-of-flight measurement reveals that the electron mobility in the columnar phase of compound 2 is on the order of 10−2 cm2 V−1 s−1 at room temperature. Compound 2 is soluble in various organic solvents except for alcohol.

  我们合成了含有七甲基环四硅氧烷分子的液晶包烯四羧酸二亚胺衍生物。含有四个七甲基环四硅氧烷分子的化合物 2 在室温下呈矩形柱状相。在柱状相中，环四硅氧烷环相互咬合成相邻的柱状，它们之间的相互作用促进了柱状介形结构的形成。飞行时间测量显示，在室温下，化合物 2 柱状相中的电子迁移率约为 10-2 cm2 V-1 s-1。除酒精外，化合物 2 可溶于各种有机溶剂。
• In situ polymerization of liquid-crystalline thin films of electron-transporting perylene tetracarboxylic bisimide bearing cyclotetrasiloxane rings
  作者：Kaede Takenami、Shinobu Uemura、Masahiro Funahashi

  DOI：10.1039/c5ra23518a

  日期：——

  tetracarboxylic bisimide (PTCBI) derivative bearing four cyclotetrasiloxane rings that forms a columnar phase at room temperature despite the presence of the bulky cyclotetrasiloxane rings was prepared. The electron mobility in the columnar phase of this PTCBI derivative at room temperature is 0.12 cm2 V−1 s−1, which is comparable to those of molecular crystals. The PTCBI derivative is soluble in various organic

  制备了带有四个环四硅氧烷环的per四羧酸双酰亚胺（PTCBI）衍生物，尽管存在庞大的环四硅氧烷环，该环四硅氧烷环在室温下仍形成柱状相。该PTCBI衍生物在室温下在柱状相中的电子迁移率为0.12 cm 2 V -1 s -1，可与分子晶体相媲美。PTCBI衍生物可溶于各种有机溶剂中，并且通过旋涂法成功地制备了液晶薄膜。旋涂的薄膜在暴露于三氟甲磺酸蒸气后不溶。在聚合过程中，LC相中的柱状结构得以保留。使用摩擦转移方法，制备了宏观取向的LC薄膜，并且在聚合后保留了光学各向异性。
• PERYLENE TETRACARBOXYLIC ACID BISIMIDE DERIVATIVE, N-TYPE SEMICONDUCTOR, A METHOD FOR PRODUCING N-TYPE SEMICONDUCTOR, AND ELECTRONIC DEVICE
  申请人：Funahashi Masahiro

  公开号：US20140024171A1

  公开（公告）日：2014-01-23

  The present invention provides a perylene tetracarboxylic acid bisimide derivative which enables the formation of an n-type semiconductor having high carrier mobility and has superior solubility. The perylene tetracarboxylic acid bisimide derivative is a perylene tetracarboxylic acid bisimide derivative represented by the following chemical formula (I), a tautomer or stereoisomer of the perylene tetracarboxylic acid bisimide derivative, or a salt of the perylene tetracarboxylic acid bisimide derivative or the tautomer or stereoisomer, In the chemical formula (I), R 1 to R 6 each represents a hydrogen atom, organooligosiloxane, or any substituent, at least one of R 1 to R 6 represents a monovalent substituent derived from organooligosiloxane, L 1 and L 2 each represents a single bond or a linking group, R 7 to R 10 each represents a lower alkyl group or a halogen, and o, p, q, and r each represents an integer from 0 to 2.

  本发明提供了一种苝酞菁四羧酸双亚胺衍生物，其能够形成具有高载流子迁移率的n型半导体，并具有优异的溶解性。该苝酞菁四羧酸双亚胺衍生物是由以下化学式（I）所表示的苝酞菁四羧酸双亚胺衍生物，其互变异构体或立体异构体，或者是该苝酞菁四羧酸双亚胺衍生物或其互变异构体或立体异构体的盐。在化学式（I）中，R1至R6分别表示氢原子、有机寡硅氧烷或任何取代基，其中至少一个R1至R6表示来自有机寡硅氧烷的一价取代基，L1和L2分别表示单键或连接基，R7至R10分别表示低碳烷基或卤素，o、p、q和r分别表示0至2的整数。
• MULTI-HEADED CHAIN SHUTTLING AGENTS AND THEIR USE FOR THE PREPARATION OF BLOCK COPOLYMERS
  申请人：Dow Global Technologies Llc

  公开号：EP3243846A2

  公开（公告）日：2017-11-15

  This disclosure relates to olefin polymerization catalysts and compositions, their manufacture, and the production of polyolefins using specific catalyst compositions, including the use of chain-shuttling agents in the olefin polymerization process. Specifically, this disclosure provides for dual-headed and multi-headed chain shuttling agents (CSAs or MSAs) and for their use in preparing blocky copolymers. By controlling the ratio of dual-headed and multi-headed CSA sites to mono-headed CSA sites, a blocky copolymer can be provided having properties such as a narrow molecular weight distribution and/or improved melt properties.

  本公开涉及烯烃聚合催化剂和组合物、其制造以及使用特定催化剂组合物生产聚烯烃，包括在烯烃聚合过程中使用链穿梭剂。具体而言，本公开提供了双头和多头链穿梭剂（CSA 或 MSA）及其在制备块状共聚物中的用途。通过控制双头和多头 CSA 位点与单头 CSA 位点的比例，可提供具有窄分子量分布和/或改善熔融特性等特性的块状共聚物。
• CHAIN SHUTTLING AGENTS AND THEIR USE FOR THE PREPARATION OF BLOCK COPOLYMERS
  申请人：Dow Global Technologies Llc

  公开号：EP3489264A1

  公开（公告）日：2019-05-29

  The present disclosure relates to olefin polymerization catalysts and compositions, their manufacture and the production of polyolefins using specific catalyst compositions, including the use of chain-shuttling agents in the olefin polymerization process. Specifically, the present disclosure provides for dual-headed and multi-headed chain shuttling agents and their use in preparing block copolymers. By controlling the ratio of dual-headed and multi-headed chain shuttling agent sites to mono-headed chain shuttling agent sites, a block copolymer can be provided having properties such as narrow molecular weight distribution and/or improved melt properties.

  本公开涉及烯烃聚合催化剂和组合物、其制造以及使用特定催化剂组合物生产聚烯烃，包括在烯烃聚合过程中使用链穿梭剂。具体而言，本公开提供了双头和多头链穿梭剂及其在制备嵌段共聚物中的用途。通过控制双头和多头链穿梭剂位点与单头链穿梭剂位点的比例，可提供具有窄分子量分布和/或改善熔融性能等特性的嵌段共聚物。