Benzeneacetic acid, alpha-((methoxy(methylthio)phosphinyl)thio)-, ethyl ester | 37565-83-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Benzeneacetic acid, alpha-((methoxy(methylthio)phosphinyl)thio)-, ethyl ester
• 英文别名: ethyl 2-[methoxy(methylsulfanyl)phosphoryl]sulfanyl-2-phenylacetate
• CAS: 37565-83-6
• 化学式: C₁₂H₁₇O₄PS₂
• 分子量: 320.4
• InChiKey: OBXULSHFYPVXMT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.4
• 重原子数：
  19
• 可旋转键数：
  8
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.42
• 拓扑面积：
  103
• 氢给体数：
  0
• 氢受体数：
  6

文献信息

• Method for preparation of a shaped chitin body containing a physiologically active substance
  申请人：UNITIKA LTD.

  公开号：EP0159139A2

  公开（公告）日：1985-10-23

  A shaped chitin body containing a high content of a physiologically active substance, such as a drug to be used for the cure or prevention of disease, is prepared by incorporating said physiologically active substance into a dope comprising (a) a water-insoluble chitin, (b) lithium chloride, and (c) N-methylpyrrolidone and/or dimethylacetamide, with the amount of said physiologically active substance incorporated being 0.5 wt. % or more with respect to the amount of the chitin contained in said dope, and there after coagulating the resulting mixture with a coagulant to obtain a shaped body. The high content of the physiologically active substance thus incorporated in the shaped chitin can be slowly released therefrom over a long period of time. The shaped-chitin of the present invention is characterized by long duration of the physiological activity of the active substance contained therein.

  一种含有高含量生理活性物质（如用于治疗或预防疾病的药物）的成型甲壳素体的制备方法是，将所述生理活性物质加入由以下成分组成的涂料中：(a) 水不溶性甲壳素、(b) 氯化锂和 (c) N-甲基吡咯烷酮和/或二甲基乙酰胺，其中所述生理活性物质的加入量为所述涂料中所含甲壳素量的 0.5 wt. % 或更多，然后用凝固剂将所得混合物凝固，得到成型体。 这样在成型甲壳素中加入的高含量生理活性物质可以在很长一段时间内从其中缓慢释放出来。本发明的异型甲壳素的特点是其中所含活性物质的生理活性持续时间长。
• Enhancement of biocide activity
  申请人：Kao Corporation

  公开号：EP0197622A1

  公开（公告）日：1986-10-15

  57 The biological effect of a biocide is enhanced by applying an esterase to a plant stem, leaves or an insect prior to, or together with, the application of the biocide.

  57 在施用杀菌剂之前或同时在植物茎、叶或昆虫身上施用酯酶，可增强杀菌剂的生物效应。
• A process for the production of a granule-shaped composition comprising agricultural chemical compound
  申请人：MEIJI SEIKA KAISHA LTD.

  公开号：EP0255760A1

  公开（公告）日：1988-02-10

  A granule-shaped composition containing an agri­cultural chemical compound and a high proportion of an anionic surface-active agent of selected types in an effective amount to enhance the useful biological activity of said agricultural chemical compound may readily be produced by a process wherein a concentrated aqueous solution or slurry containing said agricultural chemical compound and the anionic surface-active agent at selected ratios, as well as one or more optional additives such as a solid vehicle or water-soluble extender is atomized by means of a spray nozzle of specified outlet orifice diameter and is spray-dried in a spray-drying tower chamber according to a counter-current flow spray-drying method in a specially stipulated manner and under specially selected conditions of operation. The granule-shaped composition so produced has a substantially hollow space within each substantially spherical granule and shows high free-­flowing property, favorable collapsibility or dis­integrability into water, and favorable solubility or dispersibility in water.

  一种颗粒状组合物含有农用化学化合物和高比例的所选类型的阴离子表面活性剂，其有效量可提高所述农用化学化合物的有用生物活性、以及一种或多种可选添加剂（如固体载体或水溶性扩展剂）的浓缩水溶液或浆液，通过指定出口孔径的喷嘴雾化，并按照逆流喷雾干燥法在喷雾干燥塔室中以特别规定的方式和特别选定的操作条件进行喷雾干燥。这样制得的颗粒状组合物在每个基本球形的颗粒内都有一个基本中空的空间，并显示出高度的自由流动性、良好的可塌陷性或水分解性，以及良好的水溶性或分散性。
• Agricultural chemical composition
  申请人：KAO CORPORATION

  公开号：EP0539980A1

  公开（公告）日：1993-05-05

  An agricultural chemical composition which can be safely applied to crops without causing any chemical damage comprising a mixture, which exerts excellent potentiating effects on various agricultural chemicals and has n of from 2 to 50 on the average and x1+y1+z1+x2+y2+z2+x3+y3+z3 of from 0 to 100 on the average, of compounds represented by the following general formula (I) and an agricultural chemical, wherein the weight ratio of the mixture to the agricultural chemical ranges from 0.1 to 20:    wherein R¹, R² and R³ each represent a hydrogen atom or an acyl group having from 2 to 31 carbon atoms, -SO₃Na, -SO₃K, -SO₃H·N(C₂H₄OH)₃ or -SO₃H·NH(C₂H₄OH)₂;    (EO)x1, (EO)x2 and (EO)x3 each represent a polyoxyethylene chain;    (PO)y1, (PO)y2 and (PO)y3 each represent a polyoxypropylene chain;    (BO)z1, (BO)z2 and (BO)z3 each represent a polyoxybutylene chain;    n represents an integer of 1 or more;    x1, y1, z1, x2, y2, z2, x3, y3 and z3 each represent 0 or an integer of 1 or more;    x1+y1+z1, x2+y2+z2 and x3+y3+z3 each represent 0 or an integer of 1 to 200; and    x1+y1+z1+x2+y2+z2+x3+y3+z3 represents 0 or an integer of 1 to 600.

  一种可安全施用于农作物而不会造成任何化学损害的农用化学品组合物，由以下通式 (I) 所代表的化合物和一种农用化学品的混合物组成，该混合物对各种农用化学品具有极佳的增效作用，其 n 平均为 2 至 50，x1+y1+z1+x2+y2+z2+x3+y3+z3 平均为 0 至 100，其中混合物与农用化学品的重量比为 0.1 至 20： 其中 R¹、R² 和 R³ 分别代表氢原子或具有 2 至 31 个碳原子的酰基、-SO₃Na、-SO₃K、-SO₃H-N(C₂H₄OH)₃ 或-SO₃H-NH(C₂H₄OH)₂； (EO)x1、(EO)x2 和 (EO)x3 各代表一条聚氧乙烯链； (PO)y1、(PO)y2 和 (PO)y3 分别代表聚氧丙烯链； (BO)z1、(BO)z2 和 (BO)z3 各自代表聚氧丁烯链； n 代表 1 或 1 以上的整数； x1、y1、z1、x2、y2、z2、x3、y3 和 z3 各代表 0 或 1 或 1 以上的整数； x1+y1+z1、x2+y2+z2 和 x3+y3+z3 各代表 0 或 1 至 200 的整数；以及 x1+y1+z1+x2+y2+z2+x3+y3+z3 表示 0 或 1 至 600 的整数。
• Argricultural chemical composition
  申请人：KAO CORPORATION

  公开号：EP0597488A1

  公开（公告）日：1994-05-18

  An agricultural chemical composition comprising an agricultural chemical and an effective amount for enhancing the effectiveness of the agricultural chemical of an enhancer compound selected from the group consisting of ammonium compounds represented by the following general formulae (I) to (III): wherein A,B,C,D R¹,R⁴,R⁷,R⁸,R⁹,n,Y,Z and X have the meanings given in the description.

  一种农用化学品组合物，包含一种农用化学品和有效量的增强剂化合物，增强剂化合物选 自由以下通式(I)至(III)代表的铵化合物组成的组： 其中 A、B、C、D R¹、R⁴、R⁷、R⁸、R⁹、n、Y、Z 和 X 具有说明中给出的含义。