3-Amino-2,3-diphenylacrylonitrile | 478296-46-7

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二苯乙烯类
• 英文名称: 3-Amino-2,3-diphenylacrylonitrile
• 英文别名: (E)-3-amino-2,3-diphenylprop-2-enenitrile
• CAS: 478296-46-7；41278-43-7
• 化学式: C₁₅H₁₂N₂
• 分子量: 220.274
• InChiKey: KEKPTCUUOVEUNV-PFONDFGASA-N

物化性质

• 沸点：
  430.9±45.0 °C(Predicted)
• 密度：
  1.141±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.8
• 重原子数：
  17
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  49.8
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  苯乙腈 、 苯甲腈 在 potassium tert-butylate 作用下， 以 叔丁醇 为溶剂， 反应 4.0h， 以78%的产率得到3-Amino-2,3-diphenylacrylonitrile
  参考文献：
  名称：

  Ultrasound‐Assisted Synthesis of β‐Enaminonitriles in the Presence of Base

  摘要：

  Application of ultrasound shows significant rate enhancement for the synthesis of beta-enaminonitriles in the presence of base. The role of various homogeneous and heterogeneous bases/solvents was also studied for the reaction, and potassium t-butoxide/t-butyl alcohol combination was found to give the best result at room temperature.

  DOI：

  10.1080/00397910701397144

文献信息

• Method for Producing (Electro) Luminescent, Photoactive or Electrically (Semi) Conducting Polymers
  申请人：Rehahn Matthias

  公开号：US20130065358A1

  公开（公告）日：2013-03-14

  The invention concerns the production of poly(arylene-vinylenes) and related polymers whose polymerization is triggered photochemically. For that purpose, the low molecular starting materials are firstly cooled to temperatures which are so low that in fact their activation into mostly chinoid intermediate stages (the “active” monomer) occurs; the thermally induced polymerization, however, either does not occur or barely takes place at all. The polymerization is instead triggered in a separate step by means of electromagnetic radiation of a suitable wavelength—either using the absorption behavior of the low-molecular starting compounds/the monomers, or mediated by means of photoinitiators and/or sensitizers. By way of example, with this method a display is suitable to be coated with poly(arylene-vinylenes). The monomer is hereby deposited. The polymer is subsequently produced in a photo-induced manner. The remaining monomer is washed out. The process takes place at low temperatures.