申请人:Daicel Chemical Industries, Ltd.
公开号:EP2246371A1
公开(公告)日:2010-11-03
Disclosed is a photocurable resin composition for nanoimprint, containing a curable monomer component with or without a binder resin. The composition further contains 0.001 to 5 parts by weight of a compound having a reactive functional group and a hydrophobic functional group in the same molecular skeleton, per 100 parts by weight of the total amount of the curable monomer component and binder resin. Preferably, the reactive functional group is at least one functional group selected from the group consisting of hydroxyl groups, epoxy groups, vinyl ether groups, oxetanyl groups, alkoxysilane groups, and free-radically polymerizable vinyl groups, and the hydrophobic functional group is at least one functional group selected from the group consisting of fluorine-containing groups, alkylsilane groups, alicyclic hydrocarbon groups, and aliphatic hydrocarbon groups having 4 or more carbon atoms.
本发明公开了一种用于纳米压印的光固化树脂组合物,该组合物含有可固化的单体成分和粘合剂树脂或不含粘合剂树脂。按可固化单体组分和粘合剂树脂总量每 100 重量份计,该组合物还含有 0.001 至 5 重量份的化合物,该化合物在同一分子骨架中具有活性官能团和疏水官能团。优选地,活性官能团是至少一种选自羟基、环氧基、乙烯基醚基、氧杂环丁基、烷氧基硅烷基和可自由基聚合乙烯基的官能团,而疏水官能团是至少一种选自含氟基、烷基硅烷基、脂环烃基和具有 4 个或更多碳原子的脂肪烃基的官能团。