Phenol, 2,4-dinonyl-, phosphite | 64033-89-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Phenol, 2,4-dinonyl-, phosphite
• 英文别名: tris[2,4-di(nonyl)phenyl] phosphite
• CAS: 64033-89-2
• 化学式: C₇₂H₁₂₃O₃P
• 分子量: 1067.7
• InChiKey: QLPKPEZOUJMPQC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  33
• 重原子数：
  76
• 可旋转键数：
  54
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.75
• 拓扑面积：
  27.7
• 氢给体数：
  0
• 氢受体数：
  3

文献信息

• THERMOPLASTIC POLYMER COMPOSITION AND PROCESSING STABILISER
  申请人：Kimura Yoshikazu

  公开号：US20130032756A1

  公开（公告）日：2013-02-07

  The present invention provides a thermoplastic polymer composition containing a particular phenol compound or organic phosphoric compound, compound (9) which is compound (9a) represented by C m H 2m O m wherein m is an integer of not less than 3 and not more than 10, and having one aldehyde group or ketone group and m−1 hydroxy groups with at least one hydroxy group having been replaced by an alkoxy group represented by —OR 26 wherein R 26 is a C 1-12 alkyl group, and a thermoplastic polymer, and a processing stabilizer containing a particular phenol compound or organic phosphoric compound, and compound (9). A combined use of a particular phenol compound or organic phosphoric compound and compound (9) can improve processing stability of a thermoplastic polymer composition.

  本发明提供了一种热塑性聚合物组合物，其中包含特定的酚化合物或有机磷化合物、化合物(9)，该化合物(9)表示为CmH2mOm，其中m是不小于3且不大于10的整数，具有一个醛基或酮基和m-1个羟基，其中至少一个羟基已被一个表示为—OR26的烷氧基所取代，其中R26是C1-12烷基，以及一种热塑性聚合物和一种加工稳定剂，该加工稳定剂包含特定的酚化合物或有机磷化合物和化合物(9)。特定的酚化合物或有机磷化合物和化合物(9)的联合使用可以提高热塑性聚合物组合物的加工稳定性。
• Process of (co)polymerization of alpha-olefins in the presence of antioxidants
  申请人：ENICHEM SYNTHESIS S.p.A.

  公开号：EP0254348A2

  公开（公告）日：1988-01-27

  Stabilizers for organic polymers, consisting of one or more phosphorus-containing compounds of the family of alkyl- and/or phenyl-phosphites, alkyl- and/or phenyl-­phosphonites, alkyl- and/or phenyl-diphosphonites, are directly added to the reaction mixture during the (co)polymerization of α-olefins or of mixtures thereof with other unsaturated monomers. The so-obtained polymeric compositions result perfectly stabilized, and show a thermo-oxidative resistance higher than that of the same polymeric compositions to which the same antioxidants have been added by a traditional route.

  有机聚合物稳定剂由烷基和/或苯基亚磷酸酯、烷基和/或苯基亚膦酸盐、烷基和/或苯基二膦酸盐家族中的一种或多种含磷化合物组成，在 α-烯烃或其混合物与其他不饱和单体进行（共）聚合时直接加入反应混合物中。 这样得到的聚合物组合物得到了完美的稳定，其抗热氧化性高于通过传统方法添加相同抗氧化剂的聚合物组合物。
• Crystalline polyolefin composition
  申请人：Chisso Corporation

  公开号：EP0416321A1

  公开（公告）日：1991-03-13

  A crystalline polyolefin composition which provides molded articles having improved stiffness characteristics is disclosed, comprising 100 parts by weight of a crystalline polyolefin, (A) from 0.001 to 1 part by weight of a fluorophosphite compound represented by formula (I): wherein R represents an alkylidene group having from 1 to 4 carbon atoms or a sulfur atom; Ar1 and Ar2, which may be the same or different, each represents an alkylarylene group or a cycloalkylarylene group; and n represents 0 or 1, and (B) from 0.001 to 1 part by weight of at least one compound selected from the group consisting of (1) an aliphatic monocarboxylic acid salt with lithium or sodium, (2) a dithiocarbamic acid salt with lithium, sodium or potassium, (3) a 2-mercaptobenzothiazole salt with lithium, sodium or potassium, (4) a 2-mercaptobenzimidazole salt with lithium, sodium or potassium and (5) a benzotriazole salt with lithium, sodium or potassium. A crystalline polyolefin composition which provides molded articles having improved stiffness charateristics is also disclosed, comprising 100 parts by weight of a crystalline polyolefin, (A) from 0.001 to 1 part by weight of a fluorophosphite compound represented by formula (I) shown above, (B ) from 0.001 to 1 part by weight of at least one compound selected from the group consisting of (1) an aliphatic monocarboxylic acid salt with potassium, strontium or barium, (2) a hydroxy-higher fatty acid salt with potassium, strontium or barium, (3) an aliphatic polycarboxylic acid salt with lithium, sodium, potassium, strontium or barium, (4) a salt of an aliphatic hydroxy acid having form 2 to 6 carbon atoms with lithium, sodium, potassium, magnesium, strontium or barium, (5) an aromatic carboxylic acid salt with lithium, sodium, strontium, barium or aluminum, (6) a glutamic acid salt with lithium, sodium, potassium, strontium or barium, (7) an aliphatic phosphoric acid salt with sodium, potassium, calcium, strontium or barium, (8) a lithium, sodium, potassium or barium salt of a cyclic phosphorus compound represented by formula (II): wherein Ar3 and Ar4, which may be the same or different, each represents an arylene group, an alkylarylene group, a cycloalkylarylene group, an arylarylene group or an aralkylarylene group; M represents lithium, sodium, potassium or barium; and m represents an atomic valence of M, (9) magnesium or aluminum hydroxide, (10) magnesium oxide, (11) magnesium or calcium carbonate and (12) hydrotalcite, and (C) from 0.01 to 1 part by weight of an aliphatic amine.

  本发明公开了一种结晶聚烯烃组合物，该组合物可提供具有改进的刚度特性的模塑制品，该组合物包括按重量计100份的结晶聚烯烃、(A)按重量计0.001至1份的由式(I)代表的亚磷酸氟化合物： 其中 R 代表具有 1 至 4 个碳原子的亚烷基或硫原子；Ar1 和 Ar2 可以相同或不同，各自代表烷基芳基或环烷基芳基；n 代表 0 或 1，以及 (B) 0.(1) 锂或钠的脂肪族一羧酸盐，(2) 锂、钠或钾的二硫代氨基甲酸盐、(3) 锂、钠或钾的 2-巯基苯并噻唑盐， (4) 锂、钠或钾的 2-巯基苯并咪唑盐， (5) 锂、钠或钾的苯并三唑盐。 本发明还公开了一种结晶聚烯烃组合物，该组合物可提供具有改进的刚度特性的模塑制品，其成分包括 100 份（重量）结晶聚烯烃、(A) 0.001 至 1 份（重量）由上文式(I)代表的亚磷酸氟化合物、(B ) 0.(1)钾、锶或钡的脂肪族一羧酸盐；(2)钾、锶或钡的羟基高级脂肪酸盐；(3)锂、钠、钾、锶或钡的脂肪族多羧酸盐；(4)锂、钠、钾、镁、锶或钡的具有 2 至 6 个碳原子的脂肪族羟基酸盐、(5) 锂、钠、锶、钡或铝的芳香族羧酸盐； (6) 锂、钠、钾、锶或钡的谷氨酸盐、(7) 含有钠、钾、钙、锶或钡的脂肪族磷酸盐， (8) 由式（II）代表的环磷化合物的锂、钠、钾或钡盐： 其中 Ar3 和 Ar4 可以相同或不同，各自代表芳基、烷芳基、环烷芳基、芳基芳基或芳基芳基；M 代表锂、钠、钾或钡；m 代表 M 的原子价，(9) 氢氧化镁或铝，(10) 氧化镁，(11) 碳酸镁或碳酸钙和 (12) 水滑石，以及 (C) 0.01至1份重量的脂肪族胺。
• Lens and process of manufacture thereof
  申请人：Teijin Chemicals, Ltd.

  公开号：EP0501195A1

  公开（公告）日：1992-09-02

  There is provided a polycarbonate lens having improved transmittance of light with a wavelength of 400 nm. This lens is made of a polycarbonate derived from 1,1-bis(4-hydroxyphenyl)-1-phenylethane, specific viscosity found from a solution of 0.7 g of said polycarbonate in 100 ml of methylene chloride being 0.176 to 0.295, and transmittance of light with a wavelength of 400 nm passing through a 3 mm thick member molded from said polycarbonate being 80 % or more.

  本发明提供了一种聚碳酸酯镜片，其波长为 400 纳米的光的透射率有所提高。这种镜片由 1,1-双（4-羟基苯基）-1-苯基乙烷衍生的聚碳酸酯制成，从 0.7 克所述聚碳酸酯在 100 毫升二氯甲烷中的溶液中测得的比粘度为 0.176 至 0.295，波长为 400 纳米的光通过由所述聚碳酸酯模制的 3 毫米厚部件的透射率为 80%或以上。
• Thermoplastic resin composition and process for preparing the same
  申请人：MITSUBISHI CHEMICAL CORPORATION

  公开号：EP0601546A2

  公开（公告）日：1994-06-15

  There are disclosed a thermoplastic resin composition comprising (A) 10 to 90 % by weight of a polyphenylene ether, (B) 90 to 10 % by weight of a polyamide, (C) 0.1 to 10 parts by weight of a phosphorous acid ester represented by the formula (I) or (II) mentioned in the specification, based on 100 parts by weight of Components (A) and (B) in total, and (D) 0 to 100 parts by weight of an impact modifier based on 100 parts by weight of Components (A) and (B) in total, and a process for preparing the thermoplastic resin composition comprising preliminarily melting and kneading Components (A), (B) and (C), or Components (A) and (C); adding Component (D), or Components (B) and (D) to the preliminary mixture; and further melting and kneading the mixture.

  公开了一种热塑性树脂组合物，其中包括 (A) 10%至 90%（按重量计）的聚苯醚、 (B) 90-10%(重量)的聚酰胺、 (C) 以组分(A)和组分(B)合计 100 重量份计，0.1 至 10 重量份由本发明所述式 (I)或(II)代表的磷酸酯，和 (D) 以组分(A)和组分(B)的总重量 100 份为基准，抗冲改性剂的重量为 0 至 100 份、 以及制备热塑性树脂组合物的工艺，包括初步熔化和捏合组分(A)、(B)和(C)，或组分(A)和(C)；向初步混合物中加入组分(D)，或组分(B)和(D)；以及进一步熔化和捏合混合物。