cycl<3.3.3>azine | 519-61-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: cycl<3.3.3>azine
• 英文别名: Pyrido[2,1,6-de]quinolizine；13-azatricyclo[7.3.1.05,13]trideca-1(12),2,4,6,8,10-hexaene
• CAS: 519-61-9
• 化学式: C₁₂H₉N
• 分子量: 167.21
• InChiKey: NYGOXVYQBYCRRU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.3
• 重原子数：
  13
• 可旋转键数：
  0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  3.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  cycl<3.3.3>azine 生成 13-azoniatricyclo[7.3.1.05,13]trideca-1,3,5(13),6,8,10-hexaene;bromide
  参考文献：
  名称：

  FARQUHAR D.; GOUGH T. T.; LEAVER D., J. CHEM. SOC. PERKIN TRANS., PART 1 , 1976, NO 3, 341-355

  摘要：

  DOI：
• 作为产物：
  描述：

  1,3-di-tert-butylcycl<3.3.3>azine-1,3-dicarboxylate 以24%的产率得到
  参考文献：
  名称：

  FARQUHAR D.; GOUGH T. T.; LEAVER D., J. CHEM. SOC. PERKIN TRANS., PART 1 , 1976, NO 3, 341-355

  摘要：

  DOI：

文献信息

• KETOPYRROLES AS ORGANIC SEMICONDUCTORS
  申请人：Flores Jean-Charles

  公开号：US20100297405A1

  公开（公告）日：2010-11-25

  Monomeric or polymeric compounds comprising at least one moiety of the formula (Ia) wherein X is CR, where R is H or a substituent as defined in claim 1, or is another ketopyrrole moiety e.g. of the formula (1 b ) or (1 c ) with this moiety and all other symbols are as defined in claim 1, show good solubility in organic solvents and excellent film-forming properties. In addition, high efficiency of energy conversion, excellent field-effect mobility, good on/off current ratios and/or excellent stability can be observed, when the polymers according to the invention are used in semiconductor devices or organic photovoltaic (PV) devices (solar cells).

  单体或聚合物化合物至少包含式(Ia)中的一个基团，其中X为CR，其中R为H或按照权利要求1中定义的取代基，或为另一个酮吡咯基团，例如式(1b)或(1c)，其中此基团和所有其他符号如权利要求1所定义，显示出在有机溶剂中良好的溶解性和优异的成膜性能。此外，当根据本发明的聚合物用于半导体器件或有机光伏（PV）器件（太阳能电池）时，可以观察到高效的能量转换、优异的场效应迁移率、良好的开关电流比和/或优异的稳定性。
• [EN] ORGANIC MOLECULE LIGHT EMITTERS<br/>[FR] ÉMETTEURS DE LUMIÈRE À MOLÉCULES ORGANIQUES
  申请人：GOVERNING COUNCIL UNIV TORONTO

  公开号：WO2022073135A1

  公开（公告）日：2022-04-14

  The present application relates to compounds of Formula I having a negative singlet-triplet gap and a positive oscillator strength. The present application also relates to use of the compounds of Formula (I) in photocatalysis and in OLEDs as emitters and/or dopants.

  本申请涉及具有负单三重态能隙和正振荡强度的I式化合物。本申请还涉及将I式化合物用于光催化和有机发光二极管（OLED）中作为发射剂和/或掺杂剂的用途。
• NEGATIVE DISPERSION RETARDATION PLATE AND ACHROMATIC CIRCULAR POLARIZER
  申请人：Geivandov Arthur

  公开号：US20120113380A1

  公开（公告）日：2012-05-10

  The present invention relates generally to the field of organic chemistry and particularly to the nematic lyotropic liquid crystal solution and negative dispersion retardation plate for application in 3D liquid crystal displays. The negative dispersion retardation plate comprises a substrate, and at least one optically anisotropic retardation layer comprising a multi-component guest-host composition coated onto the substrate.

  本发明一般涉及有机化学领域，特别涉及向列型亲媒性液晶溶液和用于三维液晶显示器应用的负色散延迟板。该负色散延迟板包括基底和至少一个光学各向异性延迟层，该层由多组分客体-宿主组成的复合物涂覆在基底上。
• Diketopyrrolopyrrole polymers as organic semiconductors
  申请人：BASF SE

  公开号：US10424737B2

  公开（公告）日：2019-09-24

  The present invention relates to polymers comprising a repeating unit of the formula (I) and their use as organic semiconductor in organic devices, especially a diode, an organic field effect transistor and/or a solar cell, or a device containing a diode and/or an organic field effect transistor, and/or a solar cell. The polymers according to the invention have excellent solubility in organic solvents and excellent film-forming properties. In addition, high efficiency of energy conversion, excellent field-effect mobility, good on/off current ratios and/or excellent stability can be observed, when the polymers according to the invention are used in semiconductor devices or organic photovoltaic (PV) devices (solar cells).

  本发明涉及含有式（I）重复单元的聚合物及其在有机器件中作为有机半导体的用途，特别是二极管、有机场效应晶体管和/或太阳能电池，或含有二极管和/或有机场效应晶体管和/或太阳能电池的器件。本发明的聚合物在有机溶剂中具有良好的溶解性和优异的成膜性能。此外，当本发明的聚合物用于半导体设备或有机光伏设备（太阳能电池）时，可观察到高能量转换效率、优异的场效应迁移率、良好的开/关电流比和/或优异的稳定性。
• DIKETOPYRROLOPYRROLE POLYMERS AS ORGANIC SEMICONDUCTORS
  申请人：BASF SE

  公开号：US20160049589A1

  公开（公告）日：2016-02-18

  The present invention relates to polymers comprising a repeating unit of the formula (I) and their use as organic semiconductor in organic devices, especially a diode, an organic field effect transistor and/or a solar cell, or a device containing a diode and/or an organic field effect transistor, and/or a solar cell. The polymers according to the invention have excellent solubility in organic solvents and excellent film-forming properties. In addition, high efficiency of energy conversion, excellent field-effect mobility, good on/off current ratios and/or excellent stability can be observed, when the polymers according to the invention are used in semiconductor devices or organic photovoltaic (PV) devices (solar cells).