Stibanal | 1317-98-2

• 分子结构分类: 无机化合物 - 混合金属/非金属化合物 - 类金属有机物
• 英文名称: Stibanal
• 英文别名: oxoantimony
• CAS: 1317-98-2；12412-52-1
• 化学式: OSb
• 分子量: 137.749
• InChiKey: VTRUBDSFZJNXHI-UHFFFAOYSA-N

物化性质

• 熔点：
  656, in absence of O2℃ [KIR78]
• 沸点：
  1425, partial sublimation [KIR78]
• 密度：
  5.2 [KIR78]

计算性质

• 辛醇/水分配系数(LogP)：
  -0.5
• 重原子数：
  2
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  17.1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  telluryl 、 Stibanal 以 硝酸 为溶剂， 生成 antimony(III) telluride
  参考文献：
  名称：

  Large-Area Sb₂Te₃ Nanowire Arrays

  摘要：

  High-density large-area nanowire arrays of thermoelectric material Sb2Te3 have been successfully prepared using electrochemical deposition into the channels of the porous anodic alumina membrane. The morphologies, structure, and composition of the as-prepared Sb2Te3 nanowires have been characterized using field-emission scanning electron microscopy, transmission electron microscopy, high-resolution transmission electron microscopy, X-ray diffraction, and X-ray photoelectron spectroscopy. Individual Sb2Te3 nanowires are single crystalline and continuous with uniform diameters (similar to50 nm) throughout the entire length. The atomic ratio of Sb to Te is very close to the 2:3 stoichiometry.

  DOI：

  10.1021/jp046100z
• 作为产物：
  描述：

  三氯化锑 在 citric acid 、 potassium citrate 作用下， 以 not given 为溶剂， 生成 Stibanal
  参考文献：
  名称：

  Large-Area Sb₂Te₃ Nanowire Arrays

  摘要：

  High-density large-area nanowire arrays of thermoelectric material Sb2Te3 have been successfully prepared using electrochemical deposition into the channels of the porous anodic alumina membrane. The morphologies, structure, and composition of the as-prepared Sb2Te3 nanowires have been characterized using field-emission scanning electron microscopy, transmission electron microscopy, high-resolution transmission electron microscopy, X-ray diffraction, and X-ray photoelectron spectroscopy. Individual Sb2Te3 nanowires are single crystalline and continuous with uniform diameters (similar to50 nm) throughout the entire length. The atomic ratio of Sb to Te is very close to the 2:3 stoichiometry.

  DOI：

  10.1021/jp046100z
• 作为试剂：
  描述：

  N-(ethyl)-1-methyl-heptylamine 、 antimony trioxide 、 正己烷 、 二硫化碳 在 Stibanal 、 正己烷 作用下， 以 水 为溶剂， 反应 4.0h， 生成 Antimony N-(2-octyl)-N-ethyldithiocarbamate
  参考文献：
  名称：

  Extreme pressure additive for lubricants

  摘要：

  锑N-(2-辛基)-N-乙基二硫代氨基甲酸盐赋予润滑剂极限压力性能。

  公开号：

  US03988249A1

文献信息

• Zinc oxide ceramics and method for producing the same and zinc oxide
  申请人：Matsushita Electric Industrial Co., Ltd.

  公开号：US05739742A1

  公开（公告）日：1998-04-14

  A zinc oxide ceramic and a method for producing the zinc oxide ceramics are provided wherein a zinc oxide varistor for a high voltage which has excellent electric characteristics and great reliability for DC loading and surge can be produced in high yield by performing sintering at a temperature of 750.degree. to 1050.degree. C. At least one of B.sub.2 O.sub.3, Cr.sub.2 O.sub.3, GeO.sub.2, LaO.sub.3, MgO, Nb.sub.2 O.sub.5, Nd.sub.2 O.sub.3, PbO, PrO, Sb.sub.2 O.sub.3, SiO.sub.2, SnO.sub.2, Ta.sub.2 O.sub.5, WO.sub.3 and Y.sub.2 O.sub.3 powders and a Bi.sub.2 O.sub.3 powder are mixed. A mixture thus obtained is heat treated at a temperature of 400.degree. to 700.degree. C. and ground to prepare a synthetic powder. 0.5 to 20 parts by weight of the synthetic powder and 0.1 to 5.0 parts by weight of at least one of CoO, MnO.sub.2 and NiO powders are added and ground for 100 parts by weight of a zinc oxide powder. A binder is added to the ground powder to form a sheet. A silver paste is applied to the surface of the sheet to laminate four sheets. A lamination is integrally sintered at a temperature of 840.degree. C. A zinc oxide varistor of a lamination type comprises an internal silver electrode, an internal silver counter electrode, an effective layer, a noneffective layer, and an external silver electrode.

  提供了一种氧化锌陶瓷和制备氧化锌陶瓷的方法，其中可以在750°C至1050°C的温度下烧结，生产出具有优异电学特性和直流负载和浪涌方面极高可靠性的高压氧化锌压敏电阻器，并且可以高产率生产。混合至少一种B.sub.2 O.sub.3、Cr.sub.2 O.sub.3、GeO.sub.2、LaO.sub.3、MgO、Nb.sub.2 O.sub.5、Nd.sub.2 O.sub.3、PbO、PrO、Sb.sub.2 O.sub.3、SiO.sub.2、SnO.sub.2、Ta.sub.2 O.sub.5、WO.sub.3和Y.sub.2 O.sub.3粉末和Bi.sub.2 O.sub.3粉末，然后将所得混合物在400°C至700°C的温度下热处理并研磨以准备合成粉末。对于100份氧化锌粉末，添加0.5至20份合成粉末和0.1至5.0份CoO、MnO.sub.2和NiO粉末中的至少一种，然后研磨。向研磨后的粉末中添加粘合剂以形成薄片。将银浆涂在薄片表面上以层压四张薄片。在840°C的温度下整体烧结层压体。层压型氧化锌压敏电阻器包括内部银电极、内部银对电极、有效层、无效层和外部银电极。
• Ordered CoSb₃Nanowire Arrays Synthesized by Electrodeposition
  作者：Lijie Chen、Haining Hu、Yangxian Li、Guifeng Chen、Shuyun Yu、Guangheng Wu

  DOI：10.1246/cl.2006.170

  日期：2006.2

  Highly ordered CoSb3 nanowire arrays have been fabricated successfully by direct current electrodeposition from aqueous solution into the pores of a porous anodic aluminum oxide (AAO) template. Extensive characterization of the as-synthesized sample has been performed using X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), selected area electron diffraction (SAED), and energy-dispersive X-ray spectroscopy (EDS). The analysis indicates that the CoSb3 nanowires are single crystals with highly preferential orientation and the atomic ratio of Co to Sb is very close to 1:3.

  通过从水溶液中直接电沉积到多孔阳极氧化铝（AAO）模板的孔隙中，成功制造出了高度有序的 CoSb3 纳米线阵列。利用 X 射线衍射 (XRD)、扫描电子显微镜 (SEM)、透射电子显微镜 (TEM)、选区电子衍射 (SAED) 和能量色散 X 射线光谱 (EDS) 对合成样品进行了广泛的表征。分析表明， 纳米线是高度优先取向的单晶体，Co 与 Sb 的原子比非常接近 1:3。