3-Methyl-norborn-5-en-2-carbonitril | 28945-39-3

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 3-Methyl-norborn-5-en-2-carbonitril
• 英文别名: 3-methyl-bicyclo[2.2.1]hept-5-ene-2-carbonitrile；3-Methylbicyclo[2.2.1]hept-5-ene-2-carbonitrile
• CAS: 28945-39-3
• 化学式: C₉H₁₁N
• 分子量: 133.193
• InChiKey: RSCIDCVEEKEQCR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.8
• 重原子数：
  10
• 可旋转键数：
  0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  23.8
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  氢氰酸 、 3-Methyl-norborn-5-en-2-carbonitril 在 C₆₀H₆₄O₆P₂ 、 bis(1,5-cyclooctadiene)nickel (0) zinc(II) chloride 作用下， 以 甲苯 、 乙腈 为溶剂， 反应 2.5h， 以85%的产率得到Bicyclo[2.2.1]heptane-2,5-dicarbonitrile, 3-methyl-
  参考文献：
  名称：

  Norbornane based cycloaliphatic compounds containing nitrile groups

  摘要：

  这项发明涉及新颖的去甲杂环戊烷腈衍生物，以及利用氢氰化反应制备它们的相应方法。

  公开号：

  US20050159614A1

文献信息

• Novel catalyst for hydrogenation of polymer and process for hydrogenating polymer with the catalyst
  申请人：JAPAN SYNTHETIC RUBBER CO., LTD.

  公开号：EP0339986A1

  公开（公告）日：1989-11-02

  A hydrogenation catalyst consisting essential­ly of (A) at least one bis(cyclopentadienyl)titanium compound represented by the formula (1): wherein R¹ and R², which may be the same or different, represent halogen atoms, hydrocarbon groups, aryloxy groups, alkoxy groups or carbonyl groups, and (B) at least one lithium compound represented by the formula (2): R³O-Li      (2) wherein R³ represents a hydrocarbon group, or a reaction mixture of an organolithium compound with an alcoholic or phenolic hydroxyl group-containing compound, the (A) component/the (B) component molar ratio being 1/0.5 to 1/20, and optionally (C) at least one reducing organo­metallic compound selected from the group consisting of aluminum compounds, zinc compounds and magnesium com­pounds, the (A) component/the (C) component molar ratio being 1/0.5 to 1/20. The above hydrogenation catalyst is effectively applied to the hydrogenation of a polymer having olefinic double bonds to produce a hydrogenated polymer having a high degree of hydrogenation at a high hydrogenation rate with a high reproducibility.

  一种氢化催化剂，主要包括(A)至少一种由式(1)代表的双(环戊二烯基)钛化合物： 其中 R¹ 和 R² 可以相同或不同，代表卤素原子、烃基、芳氧基、烷氧基或羰基，以及 (B) 至少一种由式 (2) 代表的锂化合物： R³O-Li (2) 其中 R³ 代表烃基，或有机锂化合物与含羟基的醇类或酚类化合物的反应混合物，(A) 组分/(B) 组分的摩尔比为 1/0.5 至 1/20，可选 (C) 至少一种还原性有机金属化合物，选自铝化合物、锌化合物和镁化合物组成的组，(A) 组分/(C) 组分的摩尔比为 1/0.5 至 1/20。将上述氢化催化剂有效地应用于具有烯烃双键的聚合物的氢化，可生产出氢化程度高、氢化速率高、重现性高的氢化聚合物。
• Thermoplastic resin composition
  申请人：JAPAN SYNTHETIC RUBBER CO., LTD.

  公开号：EP0409291A2

  公开（公告）日：1991-01-23

  A thermoplastic resin composition consisting essentially of (A) 5 to 99% by weight of a hydrogenated polymer which is a hydrogenation product of a polymer represented by general formula (I): or a mixture of the norbornene derivative and a monomer copolymerizable therewith to ring-opening polymerization and (B) 95 to 1% by weight of at least one member selected from the group consisting of (B-1) a rubbery polymer and (B-2) a thermoplastic resin. The thermoplastic resin composition has excellent impact resistance and ductility.

  一种热塑性树脂组合物，其主要成分为：(A) 5-99%（按重量计）的氢化聚合物，它是通式(I)所代表的聚合物的氢化产物： 或降冰片烯衍生物与可与之开环聚合的单体的混合物，以及 (B) 95-1%（按重量计）的至少一种选自(B-1)橡胶聚合物和(B-2)热塑性树脂的成员。热塑性树脂组合物具有优异的抗冲击性和延展性。
• Cyanate resin blends and radomes including them
  申请人：Saint-Gobain Performance Plastics Corporation

  公开号：US10329383B2

  公开（公告）日：2019-06-25

  Certain embodiments are directed to cyanate resin blends comprising, for example, a mixture of a cyanate monomer and a cyanate oligomer. The resin blends are effective to provide a dielectric constant of less than 2.7, a glass transition temperature of at least 150° C. and a moisture absorption of less than 1.5%. Radomes using the resin are also described.

  某些实施方案涉及氰酸酯树脂混合物，例如由氰酸酯单体和氰酸酯低聚物混合物组成。这种树脂混合物能有效提供小于 2.7 的介电常数、至少 150 摄氏度的玻璃化转变温度和小于 1.5% 的吸湿性。此外，还介绍了使用该树脂的 Radomes。
• Transparent resin material
  申请人：JAPAN SYNTHETIC RUBBER CO., LTD.

  公开号：EP0317262B1

  公开（公告）日：1996-01-31
• Hydrogenation catalyst composition and process for hydrogenating olefinically unsaturated polymer using the same
  申请人：JAPAN SYNTHETIC RUBBER CO., LTD.

  公开号：EP0434469B1

  公开（公告）日：1995-02-22