pentadecanedinitrile | 41138-35-6

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: pentadecanedinitrile
• 英文别名: Pentadecandinitril
• CAS: 41138-35-6
• 化学式: C₁₅H₂₆N₂
• 分子量: 234.385
• InChiKey: VMMXCORZULBWSO-UHFFFAOYSA-N

物化性质

• 熔点：
  31-31.5 °C
• 沸点：
  393.8±15.0 °C(Predicted)
• 密度：
  0.891±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.5
• 重原子数：
  17
• 可旋转键数：
  12
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.87
• 拓扑面积：
  47.6
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  pentadecanedinitrile 在 乙醚 、 sodium N-methylanilide 作用下， 生成 2-amino-cyclotetradec-1-enecarbonitrile
  参考文献：
  名称：

  Ziegler; Aurnhammer, Justus Liebigs Annalen der Chemie, 1934, vol. 513, p. 43,61

  摘要：

  DOI：
• 作为产物：
  描述：

  1,13-二溴十三烷 、 氰化钾 在 乙醇 作用下， 生成 pentadecanedinitrile
  参考文献：
  名称：

  Chuit; Hausser, Helvetica Chimica Acta, 1929, vol. 12, p. 857

  摘要：

  DOI：

文献信息

• [EN] PHOSPHINYL AMIDINE COMPOUNDS, METAL COMPLEXES, CATALYST SYSTEMS, AND THEIR USE TO OLIGOMERIZE OR POLYMERIZE OLEFINS<br/>[FR] COMPOSÉS DE PHOSPHINYLAMIDINE, COMPLEXES DE MÉTAL, SYSTÈMES DE CATALYSEUR, ET LEUR UTILISATION POUR OLIGOMÉRISER OU POLYMÉRISER DES OLÉFINES
  申请人：CHEVRON PHILLIPS CHEMICAL CO

  公开号：WO2011082192A1

  公开（公告）日：2011-07-07

  N2-phosphinyl amidine compounds, N2-phosphinyl amidinates, N2-phosphinyl amidine metal salt complexes, N2-phosphinyl amidinate metal salt complexes are described. Methods for making N2-phosphinyl amidine compounds, N2-phosphinyl amidinates, N2-phosphinyl amidine metal salt complexes, and N2-phosphinyl amidinate metal salt complexes are also disclosed. Catalyst systems utilizing the N2-phosphinyl amidine metal salt complexes and N2-phosphinyl amidinate metal salt complexes are also disclosed along with the use of the N2-phosphinyl amidine compounds, N2-phosphinyl amidinates, N2-phosphinyl amidine metal salt complexes, and N2-phosphinyl amidinate metal salt complexes for the oligomerization and/or polymerization of olefins.

  描述了N2-膦胺化合物、N2-膦胺酸盐、N2-膦胺金属盐络合物、N2-膦胺酸盐金属盐络合物。还公开了制备N2-膦胺化合物、N2-膦胺酸盐、N2-膦胺金属盐络合物和N2-膦胺酸盐金属盐络合物的方法。还公开了利用N2-膦胺金属盐络合物和N2-膦胺酸盐金属盐络合物的催化剂系统，以及利用N2-膦胺化合物、N2-膦胺酸盐、N2-膦胺金属盐络合物和N2-膦胺酸盐金属盐络合物进行烯烃的寡聚和/或聚合的用途。
• Ionic Liquids for Separation of Olefin-Paraffin Mixtures
  申请人：Dai Sheng

  公开号：US20110015461A1

  公开（公告）日：2011-01-20

  The invention is directed to an ionic liquid comprising (i) a cationic portion containing a complex of a silver (I) ion and one or more neutral ligands selected from organoamides, organoamines, olefins, and organonitriles, and (ii) an anionic portion having the chemical formula wherein m and n are independently 0 or an integer of 1 or above, and p is 0 or 1, provided that when p is 0, the group —N—SO 2 —(CF 2 ) n CF 3 subtended by p is replaced with an oxide atom connected to the shown sulfur atom. The invention is also directed to a method for separating an olefin from an olefin-paraffin mixture by passing the mixture through a layer of the ionic liquid described above.

  该发明涉及一种离子液体，包括（i）含有银（I）离子的阳离子部分，该离子与来自有机酰胺、有机胺、烯烃和有机腈中选择的一个或多个中性配体形成的络合物，以及（ii）具有化学式的阴离子部分，其中m和n独立地为0或大于1的整数，p为0或1，但当p为0时，由p支撑的基团—N—SO2—(CF2)nCF3将被连接到所示硫原子的氧原子替代。该发明还涉及一种从烯烃烷烃混合物中分离烯烃的方法，通过将混合物经过上述离子液体的一层来实现。
• Aminonitrile production
  申请人：E.I. DU PONT DE NEMOURS AND COMPANY

  公开号：EP1415981A1

  公开（公告）日：2004-05-06

  A process for selectively hydrogenating a dinitrile to an aminonitrile is provided. The process comprises contacting a dinitrile with a hydrogen-containing fluid in the presence of a solvent comprising an alcohol or liquid ammonia, at least one metal catalyst, and a carbonyl group-containing additive such as, for example, organic amides, organic esters, salts of carboxylic acids, or urea.

  本发明提供了一种将二腈选择性氢化为氨基腈的工艺。该工艺包括在包含醇或液氨的溶剂、至少一种金属催化剂和含羰基的添加剂（例如有机酰胺、有机酯、羧酸盐或尿素）的存在下，使二腈与含氢流体接触。
• Phosphinyl amidine compounds, metal complexes, catalyst systems, and their use to oligomerize or polymerize olefins
  申请人：Chevron Phillips Chemical Company LP

  公开号：US10144752B2

  公开（公告）日：2018-12-04

  N2-phosphinyl amidine compounds, N2-phosphinyl amidinates, N2-phosphinyl amidine metal salt complexes, N2-phosphinyl amidinate metal salt complexes are described. Methods for making N2-phosphinyl amidine compounds, N2-phosphinyl amidinates, N2-phosphinyl amidine metal salt complexes, and N2-phosphinyl amidinate metal salt complexes are also disclosed. Catalyst systems utilizing the N2-phosphinyl amidine metal salt complexes and N2-phosphinyl amidinate metal salt complexes are also disclosed along with the use of the N2-phosphinyl amidine compounds, N2-phosphinyl amidinates, N2-phosphinyl amidine metal salt complexes, and N2-phosphinyl amidinate metal salt complexes for the oligomerization and/or polymerization of olefins.

  描述了 N2-膦酰基脒化合物、N2-膦酰基脒、N2-膦酰基脒金属盐络合物和 N2-膦酰基脒金属盐络合物。还公开了制造 N2-膦酰基脒化合物、N2-膦酰基脒、N2-膦酰基脒金属盐络合物和 N2-膦酰基脒金属盐络合物的方法。还公开了利用 N2-膦酰基脒金属盐络合物和 N2-膦酰基脒金属盐络合物的催化剂体系，以及 N2-膦酰基脒化合物、N2-膦酰基脒、N2-膦酰基脒金属盐络合物和 N2-膦酰基脒金属盐络合物在烯烃的低聚和/或聚合中的用途。
• 265. Some amidines and amidoximes with trypanocidal activity
  作者：I. D. Lamb、A. C. White

  DOI：10.1039/jr9390001253

  日期：——