6,9-dioxa-tetradecanedinitrile | 854659-59-9

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 6,9-dioxa-tetradecanedinitrile
• 英文别名: 5-[2-(4-Cyanobutoxy)ethoxy]pentanenitrile；5-[2-(4-cyanobutoxy)ethoxy]pentanenitrile
• CAS: 854659-59-9
• 化学式: C₁₂H₂₀N₂O₂
• 分子量: 224.303
• InChiKey: IKQFXWNMLQBXMO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.8
• 重原子数：
  16
• 可旋转键数：
  11
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.83
• 拓扑面积：
  66
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  6,9-dioxa-tetradecanedinitrile 在 乙醚 、 sodium N-methylanilide 作用下， 生成 9-oxo-1,4-dioxa-cyclotridecane-8-carbonitrile
  参考文献：
  名称：

  Rethinking the Analysis of Ethnic Residential Patterns: Segregation, Isolation, or Concentration Thresholds in Auckland, New Zealand?

  摘要：

  Data from the 1996 New Zealand Census on ethnicity in Auckland Urban Area are used to illustrate a new approach to measuring spatial separation. The traditionally employed single‐number indices are found wanting and a method based on thresholds is introduced. This provides more detailed information on the geography of ethnic groups that is consistent with the requirements for testing hypotheses regarding the relationship between social and spatial distance. The results show that (with a few exceptions) Polynesian groups were more encapsulated groups in Auckland than were Asian and European groups, and that most of the European groups—along with the “host society,” the New Zealand Europeans—were not spatially exposed to members of the Polynesian and Asian groups.

  DOI：

  10.1111/j.1538-4632.2002.tb01087.x
• 作为产物：
  描述：

  1,2-bis-(4-bromo-butoxy)-ethane 、 氰化钾 在 乙醇 作用下， 生成 6,9-dioxa-tetradecanedinitrile
  参考文献：
  名称：

  Rethinking the Analysis of Ethnic Residential Patterns: Segregation, Isolation, or Concentration Thresholds in Auckland, New Zealand?

  摘要：

  Data from the 1996 New Zealand Census on ethnicity in Auckland Urban Area are used to illustrate a new approach to measuring spatial separation. The traditionally employed single‐number indices are found wanting and a method based on thresholds is introduced. This provides more detailed information on the geography of ethnic groups that is consistent with the requirements for testing hypotheses regarding the relationship between social and spatial distance. The results show that (with a few exceptions) Polynesian groups were more encapsulated groups in Auckland than were Asian and European groups, and that most of the European groups—along with the “host society,” the New Zealand Europeans—were not spatially exposed to members of the Polynesian and Asian groups.

  DOI：

  10.1111/j.1538-4632.2002.tb01087.x

文献信息

• METHOD FOR PREPARING DINITRILE COMPOUND
  申请人：LG CHEM, LTD.

  公开号：US20140018567A1

  公开（公告）日：2014-01-16

  Disclosed is a method for preparing a dinitrile compound. The method includes reacting an alcohol compound with a nitrile compound having a terminal carbon-carbon unsaturated bond under anhydrous conditions. A potassium alkoxide having 1 to 5 carbon atoms is used as a catalyst in the course of the reaction. According to the method, a high-purity dinitrile compound can be prepared in a simple manner within a short reaction time indicating high productivity.

  揭示了一种制备二腈化合物的方法。该方法包括在无水条件下将一种醇化合物与一种具有末端碳-碳不饱和键的腈化合物发生反应。在反应过程中，使用具有1至5个碳原子的钾烷氧化物作为催化剂。根据该方法，可以在短时间内简单地制备高纯度的二腈化合物，表明具有高生产率。
• METHOD FOR PREPARING A DINITRILE COMPOUND
  申请人：LG Chem, Ltd.

  公开号：EP2687505A1

  公开（公告）日：2014-01-22

  Disclosed is a method for preparing a dinitrile compound. The method includes reacting an alcohol compound with a nitrile compound having a terminal carbon-carbon unsaturated bond under anhydrous conditions. A potassium alkoxide having 1 to 5 carbon atoms is used as a catalyst in the course of the reaction. According to the method, a high-purity dinitrile compound can be prepared in a simple manner within a short reaction time indicating high productivity.

  本发明公开了一种制备二腈化合物的方法。该方法包括在无水条件下，使醇化合物与具有末端碳-碳不饱和键的腈化合物反应。在反应过程中，使用具有 1 至 5 个碳原子的氧化钾作为催化剂。根据该方法，可在较短的反应时间内以简单的方式制备出高纯度的二腈化合物，生产率高。
• US9394242B2
  申请人：——

  公开号：US9394242B2

  公开（公告）日：2016-07-19